PUBLICATIONS
| 403 | |
| 402 | “Constructing Saturated Guanidinum Heterocycles by Cycloaddition of N-Amidinyliminium Ions with Indoles” T. K. Allred, M. B. Shaghafi, P.-P. Chen, Q. Tran, K. N. Houk, L. E. Overman Org. Lett. 2021, 23, |
| 401 | “Potent Anticancer Effects of Epidithiodiketopiperazine NT1721 in Cutaneous T Cell Lymphoma” Lin, C. M. Kowolik, J. Xie, S. Yadav, L. E. Overman, D. A. Horne Cancers 2021, 13, 3367. |
| 400 | “Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis” Pitre, S.P.* & Overman, L.E.* Chem. Rev. 2021, ASAP, XXXX—XXXX |
| 399 | “Reducing the age-associated increase in H3K9 trimethylation restores hippocampal BDNF signaling and synaptic plasticity” Tong, C. Butler, N. Berchtold, A. I. Tucker, K. Tseung, L. Overman, C. W. Cotman J. Neurosci. 2021, 36, 3611-3622 |
| 398 |  “Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible-Light Irradiation of EDA Complexes” Pitre, S.P.; Allred, T.K.; Overman, L.E. Org. Lett. 2021, 23, 1103—1106 |
| 397 |  “General Access to Concave-Substituted cis-Dioxabicyclo[3.3.0]octanones: Enantioselective Total Syntheses of Macfarlandin C and Dendrillolide A” Allred, T.K.; Dieskau, A.P.; Zhao, P.; Lackner, G.L.; Overman, L.E. J. Org. Chem. 2020, 85, 15532—15551 |
| 396 |  “Enantioselective Total Synthesis of Macfarlandin C, a Spongian Diterpenoid Harboring a Concave‐Substituted cis‐Dioxabicyclo[3.3.0]octanone Fragment” Allred, T.K.; Dieskau, A.P.; Zhao, P.; Lackner, G.L.; Overman, L.E. Angew. Chem. Int. Ed. 2020, 59, 6268—6272 |
| 395 | “Attenuation of hedgehog/GLI signaling by NT1721 extends survival in pancreatic cancer” M. Kowolik, M. Lin, J. Xie, L. E. Overman, D. A. Horne Journal of Experimental Clinical Cancer Research 2019, 38:431 |
| 394 |  “Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization Cross-Coupling Cascade” A. Weires, Y. Slutskyy, L. E. Overman Angewandte Chemie International Edition 2019, 58, 8561–8565 |
| 393 |  “Tertiary Alcohols as Radical Precursors for the Introduction of Tertiary Substituents into Heteroarenes” Pitre, S. P.; Muuronen, M.; Fishman, D. A.; Overman, L. E. ACS Catal. 2019, 9, 3413—3418. |
| 392 |  “Forging C(sp3)—C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules” Pitre, S. P.; Weires, N. A.; Overman, L. E. J. Am. Chem. Soc. 2019, 141, 2800—2813. |
| 391 |  “Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space” E. Kearney, L. E. Overman, 98 others authors, Rohde, J. M. ACS Central Science 2018, 4, 1727–1741 |
| 390 | “Discussion Addendum for: Preparation of the COP Catalysts: [(S)-COP-OAc]2, [(S)- COP-Cl]2, and (S)-COP-hfacac” S. Cannon, L. E. Overman Organic Syntheses 2018, 95, 500–511 |
| 389 |  “Total Synthesis of (-)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/ Fragmentation Cascade” Tao, D. J.; Slutskyy, Y.; Muuronen, M.; Le, A.; Kohler, P.; Overman, L. E. J. Am. Chem. Soc. 2018, 140, 3091—3102. |
| 388 |  “Discussion Addendum for: Preparation of the COP Catalysts: [(S)-COP-OAc]2, [(S)-COP-Cl]2, and (S)-COP-hfacac” Cannon, J. S..; Overman, L. E. Org. Synth. 2018, 95, 500—510. |
| 387 |  “1,6-Addition of Tertiary Carbon Radicals Generated from Alcohols or Carboxylic Acids by Visible-Light Photoredox Catalysis” Abbas, S. Y.; Zhao, P.; Overman, L. E. Org. Lett. 2018, 20, 868—871. |
| 386 |  “Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C via Convergent Fragment Coupling Using a Tertiary Carbon Radical” Garnsey, M. R.; Slutskyy, Y.; Jamison, C. R.; Zhao, P.; Lee, J.; Rhee, Y. H.; Overman, L. E. J. Org. Chem. 2018, 83, 6958—6976. |
| 385 |  “Fragment Coupling and Formation of Quaternary Carbons by Visible-Light Photoredox Catalyzed Reaction of tert-Alkyl Hemioxalate Salts and Michael Acceptors” Jamison, C. R.; Slutskyy, Y.; Overman, L. E. Org. Synth. 2017, 94, 167—183. |
| 384 |  “Versatile Construction of 6-Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones: Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C” Slutskyy, Y.; Jamison, C. R.; Zhao, P.; Lee, J.; Rhee, Y. H.; Overman, L. E. J. Am. Chem. Soc. 2017, 139, 7192—7195. |
| 383 | “NT1721, a Novel Epidithiodiketopiperazine, Exhi bits Potent in vitro and in vivo Efficacy Against Acute Myeloid Leukemia” Kowolik, C. M.; Lin, M.; Xie, J.; Overman, L. E.; Horne, D. A. Oncotarget, 2016, 7, 86186—86197. |
| 382 |  “Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts” Cannon, J. S.; Overman, L. E. Acc. Chem. Res. 2016, 49, 2220—2231. |
| 381 |  “Analogues of Marine Guanidine Alkaloids are in Vitro Effective against Trypanosoma cruzi and Selectively Eliminate Leishmania (L.) infantum Intracellular Amastigotes” Martins, L. F., Overman, L. E., Tempone, A. G., et al. J. Nat. Prod., 2016, 79, 2202—2210. |
| 380 |  “Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis” Jamison, C. R.; Overman, L. E. Acc. Chem. Res. 2016, 49, 1578—1586. |
| 379 |  “Short Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor” Slutskyy, Y.; Jamison, C. R.; Lackner, G. L.; Müller, D. S.; Dieskau, A. P.; Untiedt, N. L.; Overman. L. E. J. Org. Chem. 2016, 81, 7029—7035. |
| 378 |  “Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins” Slutskyy, Y.; Overman, L. E. Org. Lett. 2016, 18, 2564—2567. |
| 377 |  “Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes” Tao, D. J.; Muuronen, M.; Slutskyy, Y.; Le, A.; Furche, F.; Overman, L. E. Chem. Eur. J. 2016, 22, 8786—8790. |
| 376 |  “H3K9me3 Inhibition Improves Memory, Promotes Spine Formation, and Increases BDNF Levels in the Aged Hippocampus” Snigdha, S.; Prieto, G. A.; Petrosyan, A.; Loertscher, B. M.; Dieskau, A. P.; Overman. L. E.; Cotman, C. W. J. Neurosci. 2016, 36, 3611—3622. |
| 375 |  “Total Synthesis of (—)-Chromodorolide B” Tao, D. J.; Slutskyy, Y.; Overman, L. E. J. Am. Chem. Soc. 2016, 138, 2186—2189. |
| 374 |  “Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms” Buschleb, M.; Dorich, S.; Hanessian, S.; Tao, D.; Schenthal, K. B.; Overman, L. E. Angew. Chem. Int. Ed. 2016, 55, 4156—4186. |
| 373 |  “Ligand-Controlled Diastereoselective 1,3-Dipolar Cycloadditions of Azomethine Ylides and Methacrylonitrile” Walton, M. C.; Yang, Y.-F.; Hong, X.; Houk, K. N.; Overman. L. E. Org. Lett. 2015, 17, 6166—6169. |
| 372 |  “Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis” Pratsch, G.; Overman, L. E. J. Org. Chem. 2015, 80, 11388—11397. |
| 371 |  “Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling” Nawrat, C. C.; Jamison, C. R.; Slutskyy, Y.; MacMillan, D. W. C.; Overman, L. E. J. Am. Chem. Soc. 2015, 137, 11270—11273. |
| 370 |  “Stereocontrolled Enantioselective Total Synthesis of the [2+2] Quadrigemine Alkaloids” Canham, S. M.; Hafensteiner, B. D.; Lebsack, A. D.; May-Dracka, T. L. Nam. S.; Sterns, B. A.; Overman. L. E. Tetrahedron 2015, 71, 6424—6436. |
| 369 |  “Tricyclic Analogues of Epithiodioxopiperazine Alkaloids with Promising in vitro and in vivo Antitumor Activity” Baumann, M.; Dieskau, A. P.; Loertscher, B. M.; Walton, M. C.; Nam, S.; Xie, J.; Horne, D.; Overman. L. E. Chem. Sci. 2015, 6, 4451—4457. |
| 368 |  “Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis” Pratsch, G.; Lackner, G. L.; Overman, L. E. J. Org. Chem. 2015, 80, 6025—6036. |
| 367 |  “Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated from tert-Alkyl N-Phthalimidoyl Oxalates by Visible-Light Photocatalysis” Lackner, G. L.; Quasdorf, K. W.; Pratsch, G.; Overman, L. E. J. Org. Chem. 2015, 80, 6012—6024. |
| 366 |  “Constructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products” Müller, D. S.; Untiedt, N. L.; Dieskau, A. P.; Lackner, G. L.; Overman, L. E. J. Am. Chem. Soc. 2015, 137, 660—663. |
| 365 | “Catalytic enantioselective synthesis of quaternary carbon stereocentres” Quasdorf, K. W.; Overman, L. E. Nature, 2014, 516, 181—191. |
| 364 |  “The insulin secretory action of novel polycyclic guanidines: Discovery through open innovation phenotypic screening, and exploration of structure–activity relationships” Shaghafi, M. B.; Barrett, D. G.; Willard, F. S.; Overman, L. E. Bioorganic & Medicinal Chemistry Letters 2014, 24, 1031—1036. |
| 363 |  “Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates” Gregory L. Lackner, Kyle W. Quasdorf, Larry E. Overman. Journal of the American Chemical Society 2013, 135, 15342—15345. |
| 362 |  “Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Rings: Coupled Dynamic Kinetic Epimerization and Chirality Transfer” Zachary D. Aron, Tatsuya Ito, Tricia L. May, Larry E. Overman, and Jocelyn Wang. Journal of Organic Chemistry 2013, 78, 9929—9948. |
| 361 |  “Enantioselective Total Synthesis of Plectosphaeroic Acids B and C” Salman Y. Jabri and Larry E. Overman. Journal of Organic Chemistry 2013, 78, 8766—8788. |
| 360 |  “Enantioselective Total Synthesis of Plectosphaeroic Acid B” Salman Y. Jabri and Larry E. Overman. Journal of the American Chemical Society 2013, 135, 4231—4234. |
| 359 |  “General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors: Enantioselective Total Syntheses of (+)-and (−)-Gliocladine C, (+)-Leptosin D, (+)-T988C, (+)-Bionectin A, and (+)-Gliocladin A” John E. DeLorbe, David Horne, Richard Jove, Steven M. Mennen, Sangkil Nam, Fang-Li Zhang, and Larry E. Overman. Journal of the American Chemical Society 2013, 135, 4117—4128. |
| 358 |  “Origins of Stereoselectivities of Dihydroxylations of cis-Bicyclo[3.3.0]octenes” Hao Wang, Philipp Kohler, Larry. E. Overman, and K. N. Houk. Journal of the Americal Chemical Society 2012, 134, 16054—16058. |
| 357 |  “A Concise Synthesis of (—)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition” Martin J. Schnermann, Larry E. Overman. Angewandte Chemie International Edition 2012, 51, 9576—9580. |
| 356 |  “Forming Tertiary Organolithium and Organocuprates from Nitrile Precursors and their Bimolecular Reactions with Carbon Electrophiles to Form Quaternary Carbon Stereocenters” Martin J. Schnermann, Nicholas L. Untiedt, Gonzalo Jimenez-Oses, Kendall N. Houk, Larry E. Overman. Angewandte Chemie International Edition 2012, 51, 9581—9586. |
| 355 |  “Total Synthesis of (+)-Sieboldine A: Evolution of A Pinacol-Terminated Cyclization” Stephen M. Canham, David J. France, Larry E. Overman. Journal of Organic Chemistry 2013, 78, 9—34. |
| 354 |  “Palladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles” Jeffrey S. Cannon, Angela C. Olson, Larry E. Overman, Nicole S. Solomon Journal of Organic Chemistry, 2012, 77, 1961–1973. |
| 353 |  “Palladacyclic Imidazoline-Naphthalene Complexes: Synthesis and Catalytic Performance in Pd(II)-Catalyzed Enantioselective Reactions of Allylic Trichloroacetimidates” Jeffrey S. Cannon, James H. Frederich, and Larry E. Overman Journal of Organic Chemistry, 2012, 77, 1939–1951. |
| 352 | “Is There No End to the Total Syntheses of Strychnine? Lessons to be Learned for Strategy and Tactics in Total Synthesis” Jeffrey S. Cannon and Larry E. Overman Angewandte Chemie, International Edition 2012, 51, Early View. |
| 351 |  “Enantioselective Total Synthesis of Aplyviolene” Larry E. Overman and Martin J. Schnermann Journal of the American Chemical Society 2011, 133, 16425–16427 |
| 350 |  “Divergent Synthesis and Chemical Reactivity of Bicyclic Lactone Fragments of Complex Rearranged Spongian Diterpenes” Martin J. Schnermann, Christopher M. Beaudry, Nathan E. Genung, Stephen M. Canham, Nicholas L. Untiedt, Breanne D. W. Karanikolas, Christine Sütterlin and Larry E. Overman Journal of the American Chemical Society 2011, 133, 17494–17503 |
| 349 |  “Identification of an Unexpected 2-Oxonia[3,3]sigmatropic Rearrangement/Aldol Pathway in the Formation of Oxacyclic Rings. Total Synthesis of (+)-Aspergillin PZ” Stephen M. Canham, Larry E. Overman and Paul S. Tanis Tetrahedron 2011, 67, 9837–9843 |
| 348 |  “Enantioselective Total Synthesis of (+)-Gliocladin C and (+)-Gliocladine C. A Convergent Construction of Cyclotryptamine-Fused Polyoxopiperazines and a General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors” J. E. DeLorbe, S. Y. Jabri, S. M. Mennen, L. E. Overman and F-L Zhang Journal of the American Chemical Society 2011, 133, 6549–6552 |
| 347 |  “Total Synthesis of (+)-Condylocarpine (+)-Isocondylocarpine, and (+)-Tubotaiwine” C. L. Martin, S. Nakamura, R. Otte and L. E. Overman Organic Letters 2011, 13, 138–141: PMCID: PMC3014433 |
| 346 |  “Total Synthesis of (+)-Nankakurines A and B and (±)-5-epi-Nankakurine A” R. A. Altman, B. L. Nilsson, L. E. Overman, J. Read de Alaniz, J. M. Rohde and V. Taupin Journal of Organic Chemistry 2010, 75, 7519–7534: PMCID: PMC3038189 |
| 345 |  “Mechanism of the Cobalt Oxazoline Palladacycle (COP)-Catalyzed Asymmetric Synthesis of Allylic Esters” J. S. Cannon, S. F. Kirsch, L. E. Overman and H. F. Sneddon Journal of the American Chemical Society 2010, 132, 15192–15203: PMCID: PMC 2967776 |
| 344 |  “Catalytic Asymmetric Synthesis of Chiral Allylic Esters” J. S. Cannon, S. F. Kirsch and L. E. Overman Journal of the American Chemical Society 2010, 132, 15185–15191: PMCID: PMC 2966826 |
| 343 |  “Terminating Catalytic Asymmetric Heck Cyclizations by Stereoselective Intramolecular Capture of h3-Allylpalladium Intermediates: Total Synthesis of (–)-Spirotryprostatin B and Three Stereoisomers” L. E. Overman and M. D. Rosen Tetrahedron 2010, 66, 6514–6525: PMCID: PMC 2921616 |
| 342 |  “Total Synthesis of (+)-Sieboldine A” S. M. Canham, D. J. France and L. E. Overman Journal of the American Chemical Society 2010, 132, 7876–7877: PMCID: PMC 2885033 |
| 341 |  “Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Ring Systems: Dynamic Kinetic Resolution Using Aza-Cope Rearrangements” T. Ito, L. E. Overman and J. Wang, Journal of the American Chemical Society 2010, 132, 3272–3273: PMCID: PMC2858009 |
| 340 | “Golgi Modifying Properties of Macfarlandin E and the Synthesis and Evaluation of Its 2,7-Dioxabicyclo[3.2.1]octan-3-one Core” M. J. Schnermann, C. M. Beaudry, A. V. Egorova, R. S. Polishchuk, C. Suetterlin and L. E. Overman Proceedings of the National Academy of Science (USA), 2010, 107, 6158–6163: PMCID: PMC 2851978 |
| 339 |  “Total Synthesis of (±)- and (–)-Actinophyllic Acid” C. L. Martin, L. E. Overman and J. A. Rohde Journal of the American Chemical Society 2010, 132, 4894–4906: PMCID: PMC 2851836 |
| 338 |  “Origin of Stereocontrol in the Construction of the 12-Oxatricyclo[6.3.1.02,7]dodecane Ring System by Prins–Pinacol Reactions” L. E. Overman and P. A. Tanis Journal of Organic Chemistry 2010, 75, 455–463: PMID: 20000652 |
| 337 |  “The Aza-Cope-Mannich Reaction” L. E. Overman, P. G. Humphreys and G. S. Welmaker Organic Reactions 2011, 75, pp 747–820 |
| 336 | “Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols” A. C. Olson, L. E. Overman, H. F. Sneddon and J. W. Ziller Advanced Synthesis & Catalysis 2009, 351, 3186–3192 |
| 335 |  “Asymmetric Construction of Rings A–D of Daphnicyclidin Type Alkaloids” T. B. Dunn, J. M. Ellis, C. C. Kofink, J. R. Manning and L. E. Overman Organic Letters 2009, 11, 5658–5661 |
| 334 |  “A Unified Strategy for Enantioselective Total Synthesis of Cladiellin and Briarellen Diterpenes: Total Synthesis of Briarellins E and F, and the Putative Structure of Alcyonin and Revision of Its Structure Assignment” O. Corminboeuf, L. E. Overman and L. D. Pennington Journal of Organic Chemistry 2009, 74, 5458–5470: PMCID: PMC 2744073 |
| 333 |  “Molecular Rearrangements in the Construction of Complex Molecules” L. E. Overman Tetrahedron 2009, 65, 6432–6446: PMCID: PMC 2967776 |
| 332 |  “Absolute Configuration of Actinophyllic Acid as Determined through Chiroptical Data” T. Taniguchi, C. L. Martin, K. Monde, K. Nakanishi, N. Berova and L. E. Overman Journal of Natural Products 2009, 72, 430–432: PMCID: PMC 2902975 |
| 331 |  “A Versatile Synthesis of Unsymmetrical 3,3′-Bioxindoles: Stereoselective Mukaiyama Aldol Reactions of 2-Siloxyindoles with Isatins” J. M. Ellis, L. E. Overman, H. R. Tanner and J. Wang Journal of Organic Chemistry 2008, 73, 9151–9154: PMCID: PMC 2634855 |
| 330 |  “Enantioselective Total Syntheses of Nankakurines A and B: Confirmation of Structure and Establishment of Absolute Configuration” Journal of the American Chemical Society 2008, 130, 11297–11299 B. L. Nilsson, L. E. Overman, J. Read de Alaniz and J. M. Rohde |
| 329 |  “Total Synthesis of (–)-Actinophyllic Acid” C. L. Martin, L. E. Overman and J. M. Rohde Journal of the American Chemical Society 2008, 130, 7568–7569: PMCID: PMC 2654095 |
| 328 |  “Catalytic Asymmetric Synthesis of Allylic Thiol Derivatives” L. E. Overman, S. W. Roberts and H. Sneddon Organic Letters 2008, 10, 1485–1488 |
| 327 |  “Total Synthesis of the Strychnos Alkaloid (+)–Minfiensine: Tandem Enantioselective Intramolecular Heck-Iminium Ion Cyclization” A. B. Dounay, P. G. Humphreys, L. E. Overman and A. D. Wrobleski Journal of the American Chemical Society 2008, 130, 5368–5377: PMCID: PMC 2995331 |
| 326 |  “Construction of Epidithiodioxopiperazines by Directed Oxidation of Hydroxyproline-Derived Dioxopiperazines” L. E. Overman and T. Sato Organic Letters 2007, 9, 5267–5270 |
| 325 |  “On the Structure of Palau’amine: Evidence for the Revised Relative Configuration from Chemical Synthesis” Journal of the American Chemical Society 2007, 129, 12896–12900: PMCID: PMC 2593883 B. A. Lanman, L. E. Overman, R. Paulini and N. S. White |
| 324 |  “Synthesis of All Low-Energy Stereoisomers of the Tris(pyrrolidinoindoline) Alkaloid Hodgkinsine and Preliminary Assessment of Their Antinociceptive Activity” Journal of Organic Chemistry 2007, 72, 7909–7914 J. J. Kodanko, S. Hiebert, E. A. Peterson, L. Sung, L. E. Overman, V. de Moura Linck, G. C. Goerck, T. A. Amador, M. B. Leal and E. Elisabetsky |
| 323 |  “Total Synthesis of (–)-Sarain A” Journal of the American Chemical Society 2007, 129, 11987–12002 M. H. Becker, P. Chua, R. Downham, C. J. Douglas, N. K. Garg, S. Hiebert, S. Jaroch, R. T. Matsuoka, J. A. Middleton, F. W. Ng and L. E. Overman |
| 322 | “The Asymmetric Intramolecular Mizoroki-Heck Reaction in Natural Product Synthesis” The Mizoroki-Heck Reaction; M. Oestreich, Ed.; Wiley–VCH, West Sussex, UK, 2009, Chapter 16, pp 533–568 A. B. Dounay and L. E. Overman |
| 321 |  “Total Synthesis of (+)-Asperazine” Tetrahedron 2007, 63, 8499–8513 S. P. Govek and L. E. Overman |
| 320 | “Total Synthesis of Complex Cyclotryptamine Alkaloids: Stereocontrolled Construction of Quarternary Carbon Stereocenters” Angewandte Chemie, International Edition 2007, 46, 5488–5508 A. Steven and L. E. Overman |
| 319 |  “Kinetic and Computational Analysis of the Palladium(II)-Catalyzed Asymmetric Allylic Trichloroacetimidate Rearrangement. Development of a Model for Enantioselectivity” Journal of the American Chemical Society 2007, 129, 5031–5044 M. P. Watson, L. E. Overman and R. G. Bergman |
| 318 |  “Catalytic Asymmetric Synthesis of Allylic Aryl Ethers” Organic Letters 2007, 9, 911–913 S. F. Kirsch, L. E. Overman and N. White |
| 317 |  “Enantioselective Total Synthesis of (+)-Gliocladin C” Organic Letters 2007, 9, 339–341: PMCID: PMC 2526118 L. E. Overman and Y. Shin |
| 316 | “Preparation of the COP Catalysts: [(S)-COP-OAc]2, [(S)-COP-Cl]2, and (S)-COP-hfacac” Organic Syntheses 2007, 84, 148–155 C. E. Anderson, S. F. Kirsch, L. E. Overman, C. J. Richards and M. P. Watson |
| 315 | “Preparation of (h5-(S)-2-(4-Methylethyl)-Oxazolinylcyclopentadienyl)-(h4-Tetraphenylcylcobutadiene)Cobalt” Organic Syntheses 2007, 84, 139–147 C. E. Anderson, L. E. Overman, C. J. Richards, M. P. Watson and N. White |
| 314 | |
| 313 |  “Stereocontrolled Synthesis of Functionalized cis-Cyclopentapyrazolidines by 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines” Journal of Organic Chemistry 2006, 71, 9144–9152: PMCID: PMC 2516743 J. Gergely, J. B. Morgan and L. E. Overman |
| 312 |  “Enantioselective Total Synthesis of Guanacastepene N Using an Uncommon 7-Endo Heck Cyclization as a Pivotal Step” Journal of the American Chemical Society 2006, 128, 13095–13101 S. Iimura, L. E. Overman, R. Paulini and A. Zakarian |
| 311 |  “Concise Synthesis of Guanidine-Containing Heterocycles Using the Biginelli Reaction” Journal of Organic Chemistry 2006, 71, 7706–7714: PMCID: PMC 2535792 B. L. Nilsson and L. E. Overman |
| 310 |  “The Total Synthesis of (–)-Sarain A” Angewandte Chemie, International Edition 2006, 45, 2912–2915 N. K. Garg, S. Hiebert and L. E. Overman |
| 309 |  “Diastereoselection in the Formation of Contiguous Quaternary Carbon Stereocenters by the Intramolecular Heck Reaction” Journal of Organic Chemistry 2006, 71, 2600–2608: PMCID: PMC 2535793 L. E. Overman and D. A. Watson |
| 308 |  “Diastereoselection in the Formation of Spirocyclic Oxindoles by the Intramolecular Heck Reaction” Journal of Organic Chemistry 2006, 71, 2587–2599: PMCID: PMC 2585599 L. E. Overman and D. A. Watson |
| 307 |  “Scope and Facial Selectivity of the Prins–Pinacol Synthesis of Attached Rings” Journal of Organic Chemistry 2006, 71, 1581–1587 L. E. Overman and E. J. Velthuisen |
| 306 |  “Enantioselective Total Synthesis of the Proposed Structure of Batzelladine F and Definition of Its Structure” Journal of the American Chemical Society 2006, 128, 2604–2608: PMCID: PMC 2535800 F. Cohen and L. E. Overman |
| 305 |  “Evolution of a Strategy for the Synthesis of Structurally Complex Batzelladine Alkaloids. Enantioselective Total Synthesis of the Proposed Structure of Batzelladine F and Structural Revision” Journal of the American Chemical Society 2006, 128, 2594–2603: PMCID: PMC 2535801 F. Cohen and L. E. Overman |
| 304 | |
| 303 |  “Use of the Intramolecular Heck Reaction for Forming Congested Quaternary Carbon Stereocenters: Stereocontrolled Total Synthesis of (±)-Gelsemine” Journal of the American Chemical Society 2005, 127, 18054–18065: PMCID: PMC 2597289 A. Madin, C. J. O’Donnell, T. Oh, D. W. Old, L. E. Overman and M. J. Sharp |
| 302 |  “Aza-Cope Rearrangement–Mannich Cyclizations for the Formation of Complex Tricyclic Amines: Stereocontrolled Total Synthesis of (±)-Gelsemine” Journal of the American Chemical Society 2005, 127, 18046–18053: PMCID: PMC 2570375 W. G. Earley, E. J. Jacobsen, A. Madin, G. P. Meier, C. J. O’Donnell, T. Oh, D. W. Old, L. E. Overman and M. J. Sharp |
| 301 |  “Total Synthesis of (–)-Crambidine and Definition of the Relative Configuration of its Unique Tetracyclic Guanidinium Core” Journal of the American Chemical Society 2005, 127, 15652–15658 L. E. Overman and Y. H. Rhee |
| 300 |  “Sequential Catalytic Asymmetric Heck–Iminium Ion Cyclization: Enantioselective Total Synthesis of the Strychnos Alkaloid Minfiensine” Journal of the American Chemical Society 2005, 127, 10186–10187 A. B. Dounay, L. E. Overman and A. D. Wrobleski |
| 299 |  “Asymmetric Construction of Quaternary Carbon Stereocenters: High Stereoselection in Mukaiyama Aldol Reactions of 2-Siloxyindoles with Chiral Aldehydes” Organic Letters 2005, 7, 2795–2797 S. Adhikari, S. Caille, M. Hanbauer, V. X. Ngo and L. E. Overman |
| 298 | “Asymmetric Rearrangement of Allylic Trichloroacetimidates: Preparation of (S)-2,2,2-Trichloro-N-(1-propylallyl)acetamide” Organic Syntheses 2005, 82, 134–139 C. E. Anderson, L. E. Overman and M. P. Watson |
| 297 |  “Catalytic Asymmetric Intramolecular Aminopalladation: Improved Palladium(II) Catalysts” Journal of Organic Chemistry 2005, 70, 2859–2861 S. F. Kirsch and L. E. Overman |
| 296 |  “Catalytic Asymmetric Synthesis of Chiral Allylic Esters” Journal of the American Chemical Society 2005, 127, 2866–2867 S. F. Kirsch and L. E. Overman |
| 295 |  “Toward an Enantioselective Total Synthesis of Sarain A: Construction of an Advanced Intermediate and Rearrangement of the Sarain A Core Under Mild Conditions” Organic Letters 2005, 7, 933–936 C. J. Douglas, S. Hiebert and L. E. Overman |
| 294 |  “Stereocontrolled Synthesis of Angularly-Substituted 1-Azabicyclic Rings by Cationic 2-Aza-Cope Rearrangements” Organic Letters 2005, 7, 913–916 Z. D. Aron and L. E. Overman |
| 293 |  “Total Synthesis and Properties of the Crambescidin Core Zwitterionic Acid and Crambescidin 359” Journal of the American Chemical Society 2005, 127, 3380–3390 Z. D. Aron and L. E. Overman |
| 292 |  “Synthesis of tert-Leucine-Derived Cobalt Oxazoline Palladacycles. Reversal of Palladation Diastereoselectivity and Application to the Asymmetric Rearrangement of N-Aryl Trifluoroacetimidates” Organometallics 2005, 24, 77–81 R. S. Prasad, C. E. Anderson, C. J. Richards and L. E. Overman |
| 291 |  “The Allylic Trihaloacetimidate Rearrangement” Organic Reactions 2005, 66, 1–107 N. E. Carpenter and L. E. Overman |
| 290 |  “Catalytic Asymmetric Synthesis of Chiral Allylic Amines. Evaluation of Ferrocenyloxazoline Palladacycle Catalysts and Imidate Motifs” Journal of Organic Chemistry 2005, 70, 648–657 C. E. Anderson, Y. Donde, C. J. Douglas and L. E. Overman |
| 289 |  “Enantioselective Synthesis of Six-Membered Palladacycles Having Metal-Bound Stereogenic Carbons: Isolation and Reactivity of Palladacycles Containing Readily Accessible b-Hydrogens” Journal of the American Chemical Society 2004, 126, 16820–16833 B. J. Burke and L. E. Overman |
| 288 |  “Stereocontrolled Construction of Either Stereoisomer of 12-Oxatricyclo[6.3.1.02,7]-dodecanes Using Prins-Pinacol Reactions” Organic Letters 2004, 6, 3853–3856 L. E. Overman and E. J. Velthuisen |
| 287 |  “Monomeric Cobalt Oxazoline Palladacycles (COP). Useful Catalysts for Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates” Journal of Organic Chemistry 2004, 69, 8101–8104 S. F. Kirsch, L. E. Overman and M. P. Watson |
| 286 | “Guanidine Alkaloid Analogs as Inhibitors of HIV-1 Nef Interactions with p53, Actin, and p56lck” Proceedings of the National Academy of Science USA 2004, 101, 14079–14084: PMCID: PMC 521092 A. Olszewski, K. Sato, Z. D. Aron, F. Cohen, A. Harris, B. R. McDougall, W. E. Robinson, Jr., L. E. Overman and G. A. Weiss |
| 285 |  “Asymmetric Synthesis of Pyrrolidinoindolines. Application for the Practical Total Synthesis of (–)-Phenserine” Journal of the American Chemical Society 2004, 126, 14043–14053 A. Huang, J. J. Kodanko and L. E. Overman |
| 284 |  “Studies Towards the Total Synthesis of Palau’amine. Formation of 4,5-Dihydropyrrole-2-carboxylate Intermediates by Alkene–Enamide Ring-Closing Metathesis” Tetrahedron 2004, 60, 9559–9568 J. D. Katz and L. E. Overman |
| 283 | “Inhibition of HIV-1 Envelope-Mediated Fusion by Synthetic Batzelladine Analogs” Journal of Natural Products 2004, 67, 1319–1324 C. A. Bewley, S. Ray, F. Cohen, S. K. Collins and L. E. Overman |
| 282 |  “Synthesis and Anticancer Activity of Side Chain Analogs of the Crambescidin Alkaloids” Bioorganic & Medicinal Chemistry Letters 2004, 14, 3445–3449 Z. D. Aron, H. Pietraszkiewicz, L. E. Overman, F. Valeriote and C. Cuevas |
| 281 | “Contiguous Stereogenic Quaternary Carbons: A Daunting Challenge in Natural Products Synthesis” Proceedings of the National Academy of Science USA 2004, 101, 11943–11948: PMCID: PMC 514413 E. A. Peterson and L. E. Overman |
| 280 |  “Enantioselective Total Synthesis of (–)-Dehydrobatzelladine C” Organic Letters 2004, 6, 1253–1255 S. K. Collins, A. I. McDonald, L. E. Overman and Y. H. Rhee |
| 279 | “Scope and Limitations of the Thionium Ion-Initiated Prins–Pinacol Synthesis of Carbocycles” Synlett 2004, 1387–1393 B. J. Burke, A. D. Lebsack and L. E. Overman |
| 278 | “Catalytic Asymmetric Synthesis of All-Carbon Quaternary Stereocenters” Proceedings of the National Academy of Sciences USA 2004, 101, 5363–5367: PMCID: PMC 397386 C. J. Douglas and L. E. Overman |
| 277 |  “Total Syntheses of (±)-Didehydrostemofoline (Asparagamine A) and (±)-Isodidehydrostemofoline” Journal of the American Chemical Society 2003, 125, 15284–15285 M. Brüggemann, A. I. McDonald, L. E. Overman, M. D. Rosen, L. Schwink and J. P. Scott |
| 276 |  “The Tethered Biginelli Condensation in Natural Product Synthesis” Chemical Communications 2004, 253–265 Z. D. Aron and L. E. Overman |
| 275 |  “Assembling Polycyclic Bisguanidine Motifs Resembling Batzelladine Alkaloids by Double Tethered Biginelli Condensations” Organic Letters 2003, 5, 4485–4488 F. Cohen, S, K. Collins and L. E. Overman |
| 274 |  “Palladium” Chemical & Engineering News 2003, September 8, p 116 L. E. Overman |
| 273 |  “Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity” Journal of the American Chemical Society 2003, 125, 12412–12413 C. E. Anderson and L. E. Overman |
| 272 |  “Strategic Use of Pinacol-Terminated Prins Cyclizations in Target-Oriented Total Synthesis” Journal of Organic Chemistry 2003, 68, 7143–7157 L. E. Overman and L. D. Pennington |
| 271 |  “Enantioselective Synthesis of (–)-Idiospermuline” Tetrahedron 2003, 59, 6905–6919 L. E. Overman and E. A. Peterson |
| 270 |  “Catalytic Asymmetric Rearrangement of Allylic N-Aryl Trifluoroacetimidates. A Useful Method for Transforming Prochiral Allylic Alcohols to Chiral Allylic Amines” Organic Letters 2003, 5, 1809–1812 L. E. Overman, C. E. Owen, M. M. Pavan, C. J. Richards |
| 269 |  “Enantioselective Total Synthesis of Briarellins E and F. The First Total Syntheses of Briarellin Diterpenes” Journal of the American Chemical Society 2003, 125, 6650–6652 O. Corminboeuf, L. E. Overman and L. D. Pennington |
| 268 | “Enantioselective Total Syntheses of the Cyclotryptamine Alkaloids Hodgkinsine and Hodgkinsine B” Angewandte Chemie, International Edition 2003, 42, 2528–2531 J. J. Kodanko and L. E. Overman |
| 267 | “Enantioselective Total Synthesis of the Cyclotryptamine Alkaloid Idiospermuline” Angewandte Chemie, International Edition 2003, 42, 2525–2528 L. E. Overman and E. A. Peterson |
| 266 |  “Total Synthesis of the Reputed Structure of Alcyonin and Reassignment of its Structure” Organic Letters 2003, 5, 1543–1546 O. Corminboeuf, L. E. Overman and L. D. Pennington |
| 265 |  “Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions” Journal of the American Chemical Society 2003, 125, 6261–6271 A. B. Dounay, K. Hatanaka, J. J. Kodanko, M. Oestreich, L. E. Overman, L. A. Pfeifer and M. M. Weiss |
| 264 | “The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis” Chemical Reviews 2003, 103, 2945–2963 L. E. Overman and A. Dounay |
| 263 |  “Stereocontrolled Synthesis of Triazacyclopenta[cd]pentalenes by Intramolecular 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines” Journal of Organic Chemistry 2002, 67, 7880–7883 G. Bélanger, F-T. Hong, L. E. Overman, B. N. Rogers, J. T. Tellew and W. C. Trenkle |
| 262 |  “Diastereoselective Lithiation of (h6-Arene)dicarbonyltriphenylphosphane Chromium(0) Oxazoline Complexes—Direct Preparation of Enantiopure Complexes Having Planar Chiral Fragments of Either Configuration” Angewandte Chemie, International Edition 2002, 41, 3884–3887 L. E. Overman, C. E. Owen and G. G. Zipp |
| 261 |  “New Cationic Olefin Cyclization–Pinacol Reactions. Ring-Expanding Cyclopentane Annulations that Directly Install Useful Functionality in the Cyclopentane Ring” Journal of Organic Chemistry 2002, 67, 6421–6429 L. E. Overman and J. P. Wolfe |
| 260 |  “Enantioselective Total Synthesis of Quadrigemine C and Psycholeine” Journal of the American Chemical Society 2002, 124, 9008–9009 A. D. Lebsack, J. T. Link, L. E. Overman and B. A. Stearns |
| 259 |  “Stereoselective Synthesis of Carbocyclic Ring Systems by Pinacol-Terminated Prins Cyclizations” Tetrahedron 2002, 58, 6473–6483 T. C. Gahman and L. E. Overman |
| 258 |  “Preparation of a-Sulfenyl Enones by Thermal Fragmentation of b-Sulfenyl Enol Triflates” Organic Letters 2002, 4, 929–931 J. Hynes, Jr., T. Nasser, L. E. Overman and D. A. Watson |
| 257 |  “Construction of Substituted Cyclohexanones by Reductive Cyclization of 7-Oxo-2,8-alkadienyl Esters” Organic Letters 2002, 4, 79–82 T. M. Kamenecka, L. E. Overman and S. K. L. Sakata |
| 256 |  “Catalytic Asymmetric Intramolecular Aminopalladation: Enantioselective Synthesis of Vinyl-Substituted 2-Oxazolidinones, 2-Imidazolidinones and 2-Pyrrolidinones” Journal of the American Chemical Society 2002, 124, 12–13 L. E. Overman and T. P. Remarchuk |
| 255 | “Enantioselective Total Synthesis of Batzelladine F: Structural Revision and Stereochemical Definition” Journal of the American Chemical Society 2001, 123, 10782–10783 F. Cohen and L. E. Overman |
| 254 | “Enantioselective Total Syntheses of Ditryptophenaline and ent-WIN 64821” Journal of the American Chemical Society 2001, 123, 9465–9467 L. E. Overman and D. V. Paone |
| 253 | “Total Synthesis of Asperazine” Journal of the American Chemical Society 2001, 123, 9468–9469: PMCID: PMC 1987397 S. P. Govek and L. E. Overman |
| 252 | “A General Strategy for the Synthesis of Cladiellin Diterpenes. Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (a.k.a. Deacetoxyalcyonin Acetate), Cladiell-11-ene-3,6,7-triol, Sclerophytin A and the Initially Purported Structure of Sclerophytin A” Journal of the American Chemical Society 2001, 123, 9033–9044 D. W. C. MacMillan, L. E. Overman and L. D. Pennington |
| 251 | “Enantioselective Total Synthesis of Shahamin K” Journal of the American Chemical Society 2001, 123, 4851–4852 A. D. Lebsack, L. E. Overman and R. J. Valentegovich |
| 250 |  “A New Asymmetric Synthesis of trans-Hydroisoquinolones” Organic Letters 2001, 3, 1229–1232 A. Kamatani and L. E. Overman |
| 249 |  “Stereoselection in the Prins-Pinacol Synthesis of Acyltetrahydrofurans” Organic Letters 2001, 3, 1225–1228 F. Cohen, D. W. C. MacMillan, L. E. Overman and A. Romero |
| 248 |  “Synthesis of Polycyclic Guanidines by Cyclocondensation Reactions of N-Amidinyliminium Ions” Journal of Organic Chemistry 2001, 66, 3167–3175 L. E. Overman and J. P. Wolfe |
| 247 | “Use of Sequential Intramolecular Heck Cyclizations for Preparing Bicyclo[3.2.1]octane Fragments of Tetracyclic Stemodane and Stemarane Diterpenes” Synlett 2001, 1009–1012 S. J. O’Connor, L. E. Overman and P. V. Rucker |
| 246 |  “Thwarting ß-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction” Angewandte Chemie, International Edition 2001, 40, 1439–1442 M. Oestreich, P. R. Dennison, J. J. Kodanko and L. E. Overman |
| 245 |  “Enantioselective Synthesis of Authentic Schlerophytin A, Sclerophytin B, and Cladiell-11-ene-3,6,7-triol” Organic Letters 2001, 3, 135–137 F. Gallou, D. W. C. MacMillan, L. E. Overman, L. A. Paquette, L. D. Pennington and J. Yang |
| 244 | “Catalytic Asymmetric Synthesis of Quaternary Carbon Centers by Intramolecular Heck Reaction: Synthetic Developments and Mechanistic Studies” Journal of Synthetic Organic Chemistry, JAPAN 2000, 58, 718–727 A. Ashimori and L. E. Overman |
| 243 | “Total Synthesis of (–)-Spirotryprostatin B and Three Stereoisomers” Angewandte Chemie, International Edition 2000, 39, 4596–4599 L. E. Overman and M. D. Rosen |
| 242 | “Synthesis of 3-Acyltetrahydrofurans from Formaldehyde Acetals of Allylic Diols” Tetrahedron Letters 2000, 41, 9431–9435 C. M. Gasparski, P. M. Herrinton, L. E. Overman and J. P. Wolfe |
| 241 |  “Investigation of a Dialkylation Approach for Enantioselective Construction of Vicinal Quaternary Stereocenters” Organic Letters 2000, 2, 3241–3244 S. B. Hoyt and L. E. Overman |
| 240 |  “Total Synthesis of the Supposed Structure of Sclerophytin A and an Improved Route to (–)-7-Deacetoxyalcyonin Acetate” Organic Letters 2000, 2, 2683–2686 L. E. Overman and L. D. Pennington |
| 239 | “A New Method for Stereocontrolled Synthesis of Substituted Tetrahydrothiophenes” Journal of the American Chemical Society 2000, 122, 8672–8676 A. M. Ponce and L. E. Overman |
| 238 | “Enantioselective Total Syntheses of 13,14,15-Isocrambescidin 800 and 13,14,15-Isocrambescidin 657” Journal of the American Chemical Society 2000, 122, 4904–4914 D. S. Coffey, L. E. Overman and F. Stappenbeck |
| 237 | “A Practical Entry to the Crambescidin Family of Guanidine Alkaloids. Enantioselective Total Syntheses of Ptilomycalin A, Crambescidin 657 and its Methyl Ester (Neofolitispate 2) and Crambescidin 800” Journal of the American Chemical Society 2000, 122, 4893–4903 D. S. Coffey, A. I. McDonald, L. E. Overman, M. H. Rabinowitz and P. A. Renhowe |
| 236 |  “Stereoselection in the Prins–Pinacol Synthesis of 2,2-Disbustituted 4-Acyltetrahydrofurans. Enantioselective Synthesis of (–)-Citreoviral” Organic Letters 2000, 2, 223–226 N. Hanaki, J. T. Link, D. W. C. MacMillan, L. E. Overman, W. G. Trankle and J. A. Wurster |
| 235 | |
| 234 |  “Asymmetric Total Synthesis of Batzelladine D” Organic Letters 1999, 1, 2169–2172 F. Cohen, L. E. Overman and S. K. L. Sakata |
| 233 | “A New Strategy for Synthesis of Attached Rings” Canadian Journal of Chemistry 2000, 78, 732–738 L. E. Overman and L. D. Pennington |
| 232 | “Enantioselective Total Synthesis of the Kinesin Motor Protein Inhibitor Adociasulfate 1” Journal of the American Chemical Society 1999, 121, 12206–12207 M. Bogenstätter, A. Limberg, L. E. Overman and A. L. Tomasi |
| 231 | “Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and Meso-Chimonanthine” Angewandte Chemie, International Edition 2000, 39, 213–215 L. E. Overman, J. F. Larrow, B. A. Stearns and J. M. Vance |
| 230 | “Preparation of (3S)-N-N-1,7-Bis-tert-butoxycarbonyl-3-hydroxyspermidine in High Enantiomeric Purity” Journal of Organic Chemistry 1999, 64, 8741–8742 D. S. Coffey, A. I. McDonald and L. E. Overman |
| 229 | “A Suzuki Coupling Method for Directly Introducing a Protected b-Aminoethyl Group into Arenes and Alkenes. Convenient Synthesis of Phenethyl and Homoallylic Amines” Journal of Organic Chemistry 1999, 64, 8743–8744 A. Kamatani and L. E. Overman |
| 228 | “Direct Stereo- and Enantiocontrolled Synthesis of Vicinal Stereogenic Quaternary Carbon Centers. Total Synthesis of meso– and (–)-Chimonanthine and (+)-Calycanthine” Journal of the American Chemical Society 1999, 121, 7702–7703 L. E. Overman, D. V. Paone and B. A. Stearns |
| 227 | “Total Synthesis of (±)-Gelsemine” Angewandte Chemie, International Edition 1999, 38, 2934–2936 A. Madin, C. J. O’Donnell, T. Oh, D.W. Old, L. E. Overman and M. J. Sharp |
| 226 | “Enantioselective Total Synthesis of 13,14,15-Isocrambescidin 800” Journal of the American Chemical Society 1999, 121, 6944–6945 D. Coffey, A. I. McDonald, L. E. Overman and F. Stappenbeck |
| 225 | “Enantiodivergent Total Synthesis of (+)- and (–)-Scopadulcic Acid A” Journal of the American Chemical Society 1999, 121, 5467–5480 M. E. Fox, C. Li, J. P. Marino, Jr. and L. E. Overman |
| 224 | “High Enantioselection in the Rearrangement of Allylic Imidates with Ferrocenyl Oxazoline Catalysts” Journal of the American Chemical Society 1999, 121, 2933–2934. Y. Donde and L. E. Overman |
| 223 | “Palladium Catalyzed Enantioselective Rearrangement of Allylic Imidates to Allylic Amides” Journal of Organometallic Chemistry 1999, 576/1-2, 290–299 T. K. Hollis and L. E. Overman |
| 222 | “Asymmetric Intramolecular Heck Reactions” Catalytic Asymmetric Synthesis, Second Edition; I. Ojima, Ed., Wiley: New York; 2000, Chapter 8G, pp 675–697 Y. Donde and L. E. Overman |
| 221 |  “Studies Towards a Total Synthesis of Sarains A–C. Stereospecific Condensation of a,b-Unsaturated Esters With the Phenyl Oxazoline Derivative of Threonine” Tetrahedron Letters 1999, 40, 1273–1276 S. Jaroch, R. T. Matsuoka and L. E. Overman |
| 220 | “Stereocontrolled Synthesis of Trisubstituted Tetrahydropyrans” Journal of the American Chemical Society 1999, 121, 1092–1093 M. J. Cloninger and L. E. Overman |
| 219 |  “Tuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis or trans 1-Oxo- and 1-Iminohexahydropyrrolo-[1,2-c]pyrimidines” Journal of Organic Chemistry 1999, 64, 1520–1528 A. I. McDonald and L. E. Overman |
| 218 |  “Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B” Journal of Organic Chemistry 1999, 64, 1512–1519 A. S. Franklin, S. K. Ly, G. H. Mackin, L. E. Overman and A. J. Shaka |
| 217 | “Total Synthesis of (+)-Aloperine. Use of a Nitrogen-Bound Silicon Tether in an Intramolecular Diels–Alder Reaction” Journal of the American Chemical Society 1999, 121, 700–709 A. D. Brosius, L. E. Overman and L. Schwink |
| 216 |  “Asymmetric Construction of the Diazatricyclic Core of the Marine Alkaloids Sarains A-C” Journal of Organic Chemistry 1998, 63, 8096–8097 R. Downham, F. W. Ng and L. E Overman |
| 215 | “Planar-Chiral Cyclopalladated Ferrocenyl Amines and Imines as Enantioselective Catalysts for Allylic Imidate Rearrangements” Tetrahedron: Asymmetry 1998, 9, 3213–3222 F. Cohen and L.E. Overman |
| 214 | “Forming Cyclics with the Intramolecular Heck Reaction” CHEMTECH 1998, 28(8), August, 19–26 J. T. Link and L. E. Overman |
| 213 | “Stereoselectivities of Nucleophilic Additions to Cycloheptanones. Experimental and Theoretical Studies and General Purpose Force Field for the Prediction of Nucleophilic Addition Stereoselectivities” Journal of Organic Chemistry 1998, 63, 3196–3203 K. Ando, K. R. Condroski, K. N. Houk, Y.-D. Wu, S. K. Ly and L. E. Overman |
| 212 |  “Catalytic Asymmetric Synthesis of Either Enantiomer of the Calabar Alkaloids Physostigmine and Physovenine” Journal of the American Chemical Society 1998, 120, 6500–6503 T. Matsuura, L. E. Overman and D. J. Poon |
| 211 | “Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of (Z)-a,b-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Intermediates” Journal of the American Chemical Society 1998, 120, 6488–6499 A. Ashimori, B. Bachand, M. A. Calter, S. P. Govek, L. E. Overman and D. J. Poon |
| 210 | “Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Investigations of Intramolecular Heck Reactions of (E)-a,b-Unsaturated 2-Haloanilides and Analogs to Form Enantioenriched Spirocyclic Products” Journal of the American Chemical Society 1998, 120, 6477–6487 A. Ashimori, B. Bachand, L. E. Overman and D. J. Poon |
| 209 |  “Intramolecular Heck Cyclization of a-Sulfenyl Enol Triflates. Asymmetric Synthesis of a Pentacyclic Cardenolide Precursor Having Functionality at C-11” Tetrahedron Letters 1998, 39, 4647–4650 J. Hynes, Jr., L. E. Overman, T. Nasser and P. V. Rucker |
| 208 |  “Enantioselective Synthesis of Cardenolide Precursors Using an Intramolecular Heck Reaction” Tetrahedron Letters 1998, 39, 4643–4646 L. E. Overman and P. V. Rucker |
| 207 | “Enantioselective Total Synthesis of Hispidospermidin” Journal of the American Chemical Society 1998, 120, 4039–4040 L. E. Overman and A. Tomasi |
| 206 | “Synthesis of a Phenolic Analog of Aphidicolin. Diminished Stereoselection in Intramolecular 6-Exo Heck Reactions of Substrates Having a Hydrocarbon Tether” Synlett 1997, 1469–1471 M. M. Abelman, N. Kado, L. E. Overman and A. K. Sarkar |
| 205 | “Halide-Terminated N-Acyliminium Ion–Alkyne Cyclizations: A New Construction of Carbacephem Antibiotics” Journal of Organic Chemistry 1997, 62, 9210–9216 E. Metais, L. E. Overman, M. I. Rodriguez and B. A. Stearns |
| 204 |  “Pyridinomorphinans: Asymmetric Synthesis of Either Enantiomer and Opioid Receptor Binding Selectivity” Tetrahedron Letters 1997, 38, 8439–8442 C. Y. Hong, L. E. Overman and A. Romero |
| 203 |  “An Unexpected Product Arising from Metal Alkylidene Mediated Ring-Closing Diene Metathesis” Tetrahedron Letters 1997, 38, 8635–8638 D. Joe and L. E. Overman |
| 202 |  “Cyclopalladated Ferrocenyl Amines as Enantioselective Catalysts for the Rearrangement of Allylic Imidates to Allylic Amides” Tetrahedron Letters 1997, 38, 8837–8840 T. K. Hollis and L. E. Overman |
| 201 | “Total Synthesis of (±)-Scopadulcic Acid B” Journal of the American Chemical Society 1997, 119, 12031–12040 L. E. Overman, D. J. Ricca and V. D. Tran |
| 200 | “Stereocontrolled Synthesis of the Tetracyclic Core of the Bisguanidine Alkaloids Palau’amine and Styloguanidine” Journal of the American Chemical Society 1997, 119, 7159–7160 L. E. Overman, B. Rogers, J. Tellew and W. C. Trenkle |
| 199 | “Ring-Enlarging Cyclohexane Annulations” Journal of Organic Chemistry 1997, 62, 6379–6387 S. Ando, K. P. Minor and L. E. Overman |
| 198 | “Prins-Pinacol Spiroannulations” Tetrahedron 1997, 53, 8927–8940 K. P. Minor and L. E. Overman |
| 197 | 197. “Controlling Stereoselection in Aza-Cope–Mannich Reactions” Israel Journal of Chemistry 1997, 37, 23–30 L. E. Overman and W. C. Trenkle |
| 196 | “Total Synthesis of (+)-Isolaurepinnacin. Use of Acetal–Alkene Cyclizations to Prepare Highly Functionalized Seven-Membered Cyclic Ethers” Journal of the American Chemical Society 1997, 119, 2446–2452 D. Berger, L. E. Overman and P. A. Renhowe |
| 195 | “Allylic Transposition of Alcohol and Amine Functionality by Thermal- or Palladium(II)- Catalyzed Rearrangements of Allylic N-Benzoylbenzimidates” Journal of Organic Chemistry 1997, 62, 2288–2291 L. E. Overman and G. G. Zipp |
| 194 | “First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allyl Amides” Journal of Organic Chemistry 1997, 62, 1449–1456 M. Calter, T. K. Hollis, L. E. Overman, J. Ziller and G. G. Zipp |
| 193 | “Intramolecular Heck Reactions in Natural Products Chemistry” Metal-catalyzed Cross-coupling Reactions, Diederich, F.; Stang, P. J., Eds.; VCH: Weinheim; 1998, Chapter 6, pp 231–269 J. T. Link and L. E. Overman |
| 192 | “Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration” Journal of Organic Chemistry 1997, 62, 440–441 A. D. Brosius and L. E. Overman |
| 191 | “Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights” Angewandte Chemie, International Edition in English 1997, 36, 518–521 L. E. Overman and D. J. Poon |
| 190 | “Synthesis of 2-Azatricyclo[5.2.1.0]decanes and 2,5-Diazatricyclo[5.2.1]decanes by Intramolecular Azomethine Ylide Cycloadditions” Journal of Organic Chemistry 1996, 61, 8338–8340 L. E. Overman and J. T. Tellew |
| 189 | “A Strategy for Total Synthesis of Complex Cardenolides” Journal of Organic Chemistry 1996, 61, 6760–6761 W. Deng, M. S. Jensen, L. E. Overman, P. V. Rucker and J.-P. Vionnet |
| 188 | “Design and In Vitro Pharmacology of a Selective g-Aminobutryic AcidC Receptor Antagonist” Molecular Pharmacology 1996, 50, 1024–1030 R. M. Woodward, D. Ragozzino, Y. Murata, F. Eusebi, L. E. Overman and R. Miledi |
| 187 | “The First Selective Antagonist of the GABAc Receptor” Bioorganic & Medicinal Chemistry Letters 1996, 6, 2073–2076 Y. Murata, R. M. Woodward, R. Miledi and L. E. Overman |
| 186 | “Stereocontrolled Total Syntheses of meso-Chimonanthine and meso-Calycanthine via a Novel Samarium Mediated Reductive Dialkylation” Journal of the American Chemical Society 1996, 118, 8166–8167 J. T. Link and L. E. Overman |
| 185 | “Enantioselective Total Synthesis of (+)-Allopumiliotoxins 267A, 323B and 339A. Application of Iodide-Promoted Iminium Ion–Alkyne Cyclizations for Forming Allopumiliotoxin A Alkaloids” Journal of the American Chemical Society 1996, 118, 9073–9082 C. Caderas, R. Lett, L. E. Overman, M. H. Rabinowitz, L. A. Robinson, M. J. Sharp and J. Zablocki |
| 184 | “Efficient Total Syntheses of Pumiliotoxins A and B. Applications of Iodide-Promoted Iminium Ion–Alkyne Cyclizations in Alkaloid Construction” Journal of the American Chemical Society 1996, 118, 9062–9072 N. Lin, L. E. Overman, M. H. Rabinowitz, L. A. Robinson, M. J. Sharp and J. Zablocki |
| 183 | “Aprotic Chloride and Bromide-Promoted Alkyne-Iminium Ion Cyclizations” Heterocycles 1996, 42, 549–553 Y. Murata and L. E. Overman |
| 182 | “Total Syntheses of Pumiliotoxin A and Allopumiliotoxin Alkaloids. Interplay of Pharmacologically Active Natural Products and New Synthetic Methods and Strategies” Chemical Reviews 1996, 96, 505–522 A. Franklin and L. E. Overman |
| 181 | “New Reactions for Forming Heterocycles and Their Use in Natural Products Synthesis” Aldrichimica Acta 1995, 28, 107–120 L. E. Overman |
| 180 | “Silyl Ethers of Cycloheptene – Novel Proton Pump Inhibitors Obtained During the Total Synthesis of the Scopadulcic Acids” Bioorganic & Medicinal Chemistry Letters 1995, 5, 2943–2946 T. Hayashi, T. Sugimoto, N. Takewaki, N. Takeguchi, V. Tran, S. O’Connor, P. Rucker and L. E. Overman |
| 179 | “Enantioselective Total Synthesis of (–)-7-Deacetoxyalcyonin Acetate. The First Synthesis of a Eunicellin Diterpene” Journal of the American Chemical Society 1995, 117, 10391–10392 D. W. C. MacMillan and L. E. Overman |
| 178 | “Mannich Biscyclizations. Total Synthesis of (–)-Ajmalicine” Journal of the American Chemical Society 1995, 117, 9139–9150 M. Lögers, L. E. Overman and G. Welmaker |
| 177 | “Total Synthesis of (+)-Laurencin. Use of Acetal–Vinylsulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers” Journal of the American Chemical Society 1995, 117, 5958–5966 M. Bratz, W. H. Bullock, L. E. Overman and T. Takemoto |
| 176 | “The Enantiomer of Strychnine is a Weak Antagonist of the Inhibitory Glycine Receptor” Bioorganic & Medicinal Chemistry Letters 1995, 5, 749–752 S. D. Knight, R. Miledi, Q.-T. Nguyen, L. E. Overman and G. Pairaudeau |
| 175 | “Asymmetric Total Syntheses of (–)- and (+)-Strychnine and the Wieland–Gumlich Aldehyde” Journal of the American Chemical Society 1995, 117, 5776–5788 S. D. Knight, L. E. Overman and G. Pairaudeau |
| 174 | “Enantioselective Total Synthesis of (–)-Ptilomycalin A” Journal of the American Chemical Society 1995, 117, 2657–2658 L. E. Overman, M. H. Rabinowitz and P. A. Renhowe |
| 173 | “Enantioselective Total Synthesis of Either Enantiomer of the Antifungal Antibiotic Preussin (L-657,398) from (S)-Phenylalanine” Journal of the American Chemical Society 1994, 116, 11241–11250 W. Deng and L. E. Overman |
| 172 | “Preparation of Spirocyclic Polyethers by Intramolecular Heck Reactions” Heterocycles 1994, 39, 497–501 S. D. Knight and L. E. Overman |
| 171 | “Regioselective Opening of Terminal Epoxides with 2-(Trialkylsilyl)allyl Organometallic Reagents” Journal of Organic Chemistry 1994, 59, 4138–4142 L. E. Overman and P. A. Renhowe |
| 170 | “An Enantioselective Approach to the Synthesis of Manzamine A” Tetrahedron Letters 1994, 35, 4279–4282 T. M. Kamenecka and L. E. Overman |
| 169 | “Preparation of Opium Alkaloids by Palladium Catalyzed Bis-Cyclizations. Formal Total Synthesis of Morphine” Tetrahedron Letters 1994, 35, 3453–3456 C. Y. Hong and L. E. Overman |
| 168 | “A Convenient Method for the Preparation of 3-Substituted Glutarate Diesters” Journal of Organic Chemistry 1994, 59, 1946 G. Leotta, III, L. E. Overman and G. S. Welmaker |
| 167 | “Application of Intramolecular Heck Reactions for Forming Congested Quaternary Carbon Centers in Complex Molecule Total Synthesis” Pure and Applied Chemistry 1994, 66, 1423–1430 L. E. Overman |
| 166 | “Application of Intramolecular Heck Reactions to the Preparation of Steroid and Terpene Intermediates Having cis A-B Ring Fusions. Model Studies for the Total Synthesis of Complex Cardenolides” Tetrahedron (Symposium in Print “Palladium in Organic Synthesis”) 1994, 50, 347–358 S. Laschat, F. Narjes and L. E. Overman |
| 165 | “Asymmetric Synthesis of Either Enantiomer of Opium Alkaloids and Morphinans. Total Synthesis of (–)- and (+)-Dihydrocodeinone and (–)- and (+)-Morphine” Journal of the American Chemical Society 1993, 115, 11028–11029 C. Y. Hong, N. Kado and L. E. Overman |
| 164 | “Simple Method for Controlling Stereoselection in Mannich Cyclization Reactions of Aldehydes” Journal of Organic Chemistry 1993, 58, 6947–6948 D. A. Heerding, C. Y. Hong, N. Kado, G. C. Look and L. E. Overman |
| 163 | “Enantioselective Total Synthesis of (–)-Strychnine” Journal of the American Chemical Society 1993, 115, 9293–9294 S. D. Knight, L. E. Overman and G. Pairaudeau |
| 162 | “Total Synthesis of (±)-Scopadulcic Acid A. An Illustration of the Utility of Palladium Catalyzed Polyene Cyclizations” Journal of Organic Chemistry 1993, 58, 5304–5306 D. J. Kucera, S. J. O’Connor and L. E. Overman |
| 161 | “Catalytic Asymmetric Synthesis of Either Enantiomer of Physostigmine. Formation of Quaternary Carbon Centers with High Enantioselection by Intramolecular Heck Reactions of (Z)-2-Butenanilides” Journal of Organic Chemistry 1993, 58, 6949–6951 A. Ashimori, T. Matsuura, L. E. Overman and D. J. Poon |
| 160 | “Charge as a Key Component in the Design of New Cyclization Reactions” Abstract, 33rd National Organic Symposium 1993, 96–116 L. E. Overman |
| 159 | “Enantioselective Total Synthesis of (–)-Isolaurepinnacin” Journal of the American Chemical Society 1993, 115, 9305–9306 D. Berger, L. E. Overman and P. A. Renhowe |
| 158 | “First Total Synthesis of Scopadulcic Acid B. An Illustration of the Utility of Palladium- Catalyzed Polyene Cyclizations” Organometallic Reagents in Organic Synthesis, Academic Press: New York, 1994, pp 117–128 L. E. Overman, M. M. Abelman, D. J. Ricca and V. D. Tran |
| 157 | “Preparation of Enantioenriched Tetrahydropyridines by Iminium Ion–Vinylsilane Cyclizations” Tetrahedron Letters 1993, 34, 5243–5246 P. Castro, L. E. Overman, X. Zhang and P. S. Mariano |
| 156 | “Introduction of the 2-Phenylthioethyl, 2-Phenylsulfinylethyl, and 2,2-Di(phenylthio)ethyl Substituents into Cyclic Ketones” Journal of Organic Chemistry 1993, 58, 6476–6479 J. Montgomery and L. E. Overman |
| 155 | “Studies Towards the Total Synthesis of (+)-Ptilomycalin A. Use of a Tethered Biginelli Condensation for the Preparation of an Advanced Tricyclic Intermediate” Journal of Organic Chemistry 1993, 58, 3235–3237 L. E. Overman and M. H. Rabinowitz |
| 154 | “Total Synthesis of Amaryllidaceae Alkaloids of the 5,11-Methanomorphanthride Type. Efficient Total Syntheses of (–)-Pancracine and (±)-Pancracine” Journal of Organic Chemistry 1993, 58, 4662–4672 L. E. Overman and J. Shim |
| 153 | “First Total Synthesis of Lycopodium Alkaloids of the Magellenane Group. Enantioselective Total Syntheses of (–)-Magellanine and (+)-Magellaninone” Journal of the American Chemical Society 1993, 115, 2992–2993 G. C. Hirst, T. O. Johnson and L. E. Overman |
| 152 | “The Aza-Cope-Mannich Approach to Strychnos Alkaloids. Short Stereocontrolled Total Syntheses of (±)-Dehydrotubifoline and (±)-Akuammicine” Journal of the American Chemical Society 1993, 115, 3966–3976 S. R. Angle, J. M. Fevig, S. D. Knight, R. M. Marquis, Jr. and L. E. Overman |
| 151 | “General Approach to Halogenated Tetrahydrofuran Natural Products from Red Algae of the Genus Laurencia. The Total Synthesis of (±)-Kumausallene and (±)-epi-Kumausallene” Journal of Organic Chemistry 1993, 58, 2468–2477 T. A. Grese, K. D. Hutchinson and L. E. Overman |
| 150 | “Total Synthesis of the Amaryllidaceae Alkaloid (±)-Epielwesine. The Importance of Vinylsilane Stereochemistry in Iminium Ion–Vinylsilane Cyclizations” Heterocycles 1993, 35, 205–225 R. M. Burk and L. E. Overman |
| 149 | “First Total Synthesis of Scopadulcic Acid B” Journal of the American Chemical Society 1993, 115, 2042–2044 L. E. Overman, D. J. Ricca and V. D. Tran |
| 148 | “Preparation of Unsaturated Seven and Eight Membered Nitrogen Heterocycles by Iodide-Promoted Alkyne–Iminium Ion Cyclizations” Synlett 1992, 995–996 I. M. Rodriguez-Campos and L. E. Overman |
| 147 | “Preparation of Seven-Membered Cyclic Ethers Containing Halogenated Side Chains by Acetal-Alkene Cyclizations” Synlett 1992, 811–812 D. Berger and L. E. Overman |
| 146 | “Palladium-Catalyzed Polyene Cyclizations” Pure and Applied Chemistry 1992, 64, 1813–1819 L. E. Overman, M. M. Abelman, D. J. Kucera, D. J. Ricca and V. D. Tran |
| 145 | “Controlling Stereoselection in Intramolecular Heck Reactions by Tailoring the Palladium Catalyst” Tetrahedron Letters 1992, 33, 4859–4862 A. Madin and L. E. Overman |
| 144 | “Iodide-Promoted Aldiminium Ion–Alkyne Cyclizations. A Convenient Synthesis of Substituted Tetrahydropyridines and 3-Alkyldenepiperidines” Tetrahedron Letters 1992, 33, 4103–4106 L. E. Overman and A. K. Sarkar |
| 143 | “Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Palladium Catalyzed Formation of Either Enantiomer of Spirooxindoles and Related Spirocyclics Using a Single Enantiomer of a Chiral Diphosphine Ligand” Journal of Organic Chemistry 1992, 57, 4571–4572 A. Ashimori and L. E. Overman |
| 142 | “Charge as a Key Component in Reaction Design. The Invention of Cationic Cyclization Reactions of Importance in Synthesis” Accounts of Chemical Research 1992, 25, 352–359 L. E. Overman |
| 141 | “Reaction of Na2Fe(CO)4 with an Unsaturated Aziridinium Ion. Unprecedented Rearrangement of an Alkyltetracarbonylferrate Intermediate” Journal of Organic Chemistry 1992, 57, 1035–1038 L. E. Overman and M. J. Sharp |
| 140 | “Synthesis of 3-Acyl-3-Alkyloxindoles” Tetrahedron Letters 1991, 32, 6993–6996 C. J. Flann, L. E. Overman and A. Sarkar |
| 139 | “First Total Synthesis of (+)-Allopumiliotoxin 339A. A Practical Entry to Dendrobatid Alkaloids of the Allopumiliotoxin Class” Journal of the American Chemical Society 1992, 114, 368–369 L. E. Overman, L. A. Robinson and J. Zablocki |
| 138 | “Ring-Enlarging Cyclopentene Annulations” Tetrahedron Letters 1991, 32, 7361–7364 T. Johnson and L. E. Overman |
| 137 | “First Total Synthesis of Amaryllidaceae Alkaloids of the 5,11-Methanomorphanthridine Type. An Efficient Total Synthesis of (±)-Pancracine” Journal of Organic Chemistry 1991, 56, 5005–5007 L. E. Overman and J. Shim |
| 136 | “New Approach to Strychnos Alkaloids. Stereocontrolled Total Synthesis of (±)-Dehydrotubifoline” Journal of the American Chemical Society 1991, 113, 5085–5086 J. M. Fevig, R. M. Marquis, Jr. and L. E. Overman |
| 135 | “The First Enantioselective Total Syntheses of the Allopumiliotoxin A Alkaloids 267A and 339B” Journal of Organic Chemistry 1992, 57, 1179–1190 S. W. Goldstein, L. E. Overman, and M. H. Rabinowitz |
| 134 | “3(S)-((tert-Butyldiphenylsilyl)oxy)-2-butanone (2-Butanone, (S)-3-[[1,1-dimethylethyl)diphenylsilyl]]oxy]” Organic Syntheses 1992, 71, 56–62; Collective Volume IX, p 139–142 L. E. Overman and G. M. Rishton |
| 133 | “Stereocontrolled Preparation of 3-Acyltetrahydrofurans from Acid-Promoted Rearrangements of Allylic Ketals: (2S,3S)-3-Acetyl-8-carboethoxy-2,3-dimethyl-1-oxa-8-azaspiro[4.5]decane” Organic Syntheses 1992, 71, 63–71; Collective Volume IX, pp 4–9 L. E. Overman and G. M. Rishton |
| 132 | “General Approach to Halogenated Tetrahydrofuran Natural Products from Red Algae of the Genus Laurencia. Total Synthesis of (±)-trans-Kumausyne and Demonstration of an Asymmetric Synthesis Strategy” Journal of the American Chemical Society 1991, 113, 5378–5384 M. J. Brown, T. Harrison and L. E. Overman |
| 131 | “Stereocontrolled Preparation of Tetrahydrofurans from Acid-Promoted Rearrangements of Allylic Acetals” Journal of the American Chemical Society 1991, 113, 5354–5365 M. H. Hopkins, L. E. Overman and G. M. Rishton |
| 130 | “Acid-Promoted Reaction of Cyclic Allylic Diols with Carbonyl Compounds. Stereoselective Ring-Enlarging Tetrahydrofuran Annulations” Journal of the American Chemical Society 1991, 113, 5365–5378 M. J. Brown, T. Harrison, P. M. Herrinton, M. H. Hopkins, K. D. Hutchinson, P. Mishra and L. E. Overman |
| 129 | “Use of Aza-Cope Rearrangement–Mannich Cyclization Reactions to Achieve a General Entry to Melodinus and Aspidosperma Alkaloids. Stereocontrolled Total Syntheses of (±)-Deoxoapodine, (±)-Meloscine, and (±)-Epimeloscine and a Formal Synthesis of 1-Acetylaspidoalbidine” Journal of the American Chemical Society 1991, 113, 2598–2610 L. E. Overman, G. M. Robertson and A. J. Robichaud |
| 128 | “Preparation of 3-Amino-4-(hydroxymethyl)azetidin-2-ones from the Reaction of Glycine Enolates with Imines of a Glycoaldehyde” Journal of Organic Chemistry 1991, 56, 1933–1936 M. J. Brown and L. E. Overman |
| 127 | “Construction of Quaternary Carbon Centers by Palladium-Catalyzed Intramolecular Alkene Insertions. Total Synthesis of the Amaryllidaceae Alkaloids (±)-Tazettine and (±)-6a-Epipretazettine” Journal of the American Chemical Society 1990, 112, 6959–6964 M. M. Abelman, L. E. Overman and V. D. Tran |
| 126 | “Formation of D4-Oxocenes from Lewis Acid-Promoted Cyclization of 5-Hexenyl Acetals. Evidence for a Concerted Ene Cyclization Mechanism” Journal of the American Chemical Society 1990, 112, 4399–4403 T . A. Blumenkopf, G. C. Look and L. E. Overman |
| 125 | “Preparation of Eight-Membered Cyclic Ethers by Lewis Acid Promoted Acetal–Alkene Cyclizations” Journal of the American Chemical Society 1990, 112, 4386–4399 T. A. Blumenkopf, M. Bratz, A. Castañeda, G. C. Look, L. E. Overman, D. Rodriguez and A. S. Thompson |
| 124 | “Mechanism of the Palladium Dichloride Catalyzed Cope Rearrangement of Acyclic Dienes. A Substituent Effect Study” Journal of the American Chemical Society 1990, 112, 3945–3949 L. E. Overman and A. F. Renaldo |
| 123 | “Palladium-Catalyzed Polyene Cyclizations of Trienyl Triflates” Journal of Organic Chemistry 1989, 54, 5846–5848 N. E. Carpenter, D. J. Kucera and L. E. Overman |
| 122 | “Pumiliotoxin Alkaloids: A New Class of Sodium Channel Agents” Biochemical Pharmacology 1990, 40, 315–326 J. W. Daly, F. Gusovsky, E. T. McNeal, S. Secunda, M. Bell, C. R. Creveling, Y. Nishizawa, L. E. Overman, M. J. Sharp and D. P. Rossignol |
| 121 | “Intramolecular (N-Acyloxy)iminium Ion-Alkyne Cycloadditions. A New Route to Bicyclic a-Amino Ketones” Journal of Organic Chemistry 1990, 55, 1447–1459 M. J. Fisher and L. E. Overman |
| 120 | “Intramolecular Mannich and Related Reactions” Comprehensive Organic Synthesis 1991, 2, 1007–1046 L. E. Overman and D. J. Ricca |
| 119 | “(E)-1-Benzyl-3-(1-iodoethylidene)piperidine. Nucleophile-Promoted Alkyne Iminium Ion Cyclizations” Organic Syntheses 1991, 70, 111–119; Collective Volume IX, pp 46–51 H. J. Arnold, L. E. Overman, M. J. Sharp and M. C. Witschel |
| 118 | “Total Synthesis of (±)-Meloscine and (±)-Epimeloscine” Journal of Organic Chemistry 1989, 54, 1236–1238 L. E. Overman, G. M. Robertson and A. J. Robichaud |
| 117 | “Stereocontrolled Construction of Carbocyclic Rings by Sequential Cationic Cyclization–Pinacol Rearrangements” Journal of the American Chemical Society 1989, 111, 1514–1515 G. C. Hirst, P. N. Howard and L. E. Overman |
| 116 | “Cationic Cyclization Reactions Terminated by Pinacol Rearrangements” Selectivities in Lewis Acid-Promoted Reactions, NATO ASSI Series, Kluwer Academic: Dordrecht, Netherlands, Vol. 289; D. Schinzer, Ed.; 1989, pp 1–20 L. E. Overman |
| 115 | “Preparation of Seven-Membered Ring Cyclic Ethers and 3-Alkylidene-Tetrahydropyrans from the Cyclization of Oxonium Cations Derived from Unsubstituted and Silicon-Containing 4-Alken-1-ols” Journal of Organic Chemistry 1989, 54, 5695–5707 A. Castañeda, D. J. Kucera and L. E. Overman |
| 114 | “Preparation of Functionalized Hydroindol-3-ols via Tandem Aza-Cope Rearrangement–Mannich Cyclizations. Formal Total Synthesis of (+)-6a-Epipretazettine and Related Alkaloids” Tetrahedron Letters 1989, 30, 647–650 L. E. Overman and H. Wild |
| 113 | “Synthesis of Allopumiliotoxin A Alkaloids via Iminium Ion–Vinylsilane Cyclizations” Tetrahedron Letters 1988, 29, 6541–6544 R. M. Lett, L. E. Overman and J. Zablocki |
| 112 | “Complementary Use of Iminium Ion and Acyl Iminium Ion Cyclization Initiators for Asymmetric Synthesis of Both Enantiomers of Hydroxylated Indolizidines” Journal of Organic Chemistry 1989, 54, 2591–2596 M.-P. Heitz and L. E. Overman |
| 111 | “Total Syntheses of (+)-Geissoschizine, (±)-Geissoschizine, and (±)-(Z)-Isositsirikine. Stereocontrolled Synthesis of Exocyclic Double Bonds by Stereospecific Iminium Ion–Vinylsilane Cyclizations” Journal of the American Chemical Society 1989, 111, 300–308 L. E. Overman and A. J. Robichaud |
| 110 | “Synthesis Studies Directed Towards Gelsemine. Preparation of an Advanced Pentacyclic Intermediate” Tetrahedron Letters 1988, 29, 3785–3788 W. G. Earley, T. Oh and L. E. Overman |
| 109 | “Synthesis Studies Directed Towards Gelsemine. A New Synthesis of Highly Functionalized cis-Hydroisoquinolines” Tetrahedron Letters 1988, 29, 3781–3784 W. G. Earley, E. J. Jacobsen, G. P. Meier, T. Oh and L. E. Overman |
| 108 | “Studies on the Total Synthesis of Gelsemine” Proceedings of the First Princess Chulabhorn Science Congress 1987. International Congress on Natural Products 1990, 3, 381–390 W. G. Earley, E. J. Jacobsen, T. Oh and L. E. Overman |
| 107 | “Synthesis of Substituted Tetrahydropyridines by Cyclizations of Silicon-Containing Iminium Ions” Tetrahedron (Symposium in Print) 1988, 44, 3919–3930 G. W. Daub, D. A. Heerding and L. E. Overman |
| 106 | “Palladium-Catalyzed Polyene Cyclizations of Dienyl Aryl Iodides” Journal of the American Chemical Society 1988, 110, 2328–2329 M. M. Abelman and L. E. Overman |
| 105 | “Enantioselective Total Synthesis of the Pumiliotoxin A Alkaloids via Reductive Iminium Ion–Alkyne Cyclizations. Total Synthesis of (+)-Pumiliotoxin A” Tetrahedron Letters 1988, 29, 901–904 L. E. Overman and M. J. Sharp |
| 104 | “Synthesis and Diels-Alder Reactions of 5-Alkenyl-1,3-Oxathiole-3-Oxides. A New Class of Diheterosubstituted 1,3-Dienes” Journal of Organic Chemistry 1988, 53, 2630–2634 M. J. Fisher and L. E. Overman |
| 103 | “Nucleophile-Promoted Electrophilic Cyclization Reactions of Alkynes” Journal of the American Chemical Society 1988, 110, 612–614, 5934 L. E. Overman and M. J. Sharp |
| 102 | “Total Synthesis of (–)-Laurenyne. The Use of Acetal-Initiated Cyclizations to Prepare Functionalized Eight-Membered Cyclic Ethers” Journal of the American Chemical Society 1988, 110, 2248–2256 L. E. Overman and A. S. Thompson |
| 101 | “Face Selectivity in Diels–Alder Reactions of Chiral Dienes Containing Allylic Substituents” Journal of the American Chemical Society 1988, 110, 4625–4633 M. J. Fisher, W. J. Hehre, S. D. Kahn and L. E. Overman |
| 100 | “Scope and Mechanism of Tandem Cationic Aza-Cope Rearrangement–Mannich Cyclization Reactions” Journal of the American Chemical Society 1988, 110, 4329–4336 E. J. Jacobsen, J. Levin and L. E. Overman |
| 99 | “Enantioselective Total Synthesis of Streptazolin. The Tandem Use Iminium Ion–Vinylsilane Cyclizations and Intramolecular Acylations” Journal of the American Chemical Society 1987, 109, 6115–6119 C. J. Flann and L. E. Overman |
| 98 | “Medium Effects and the Nature of the Rate-Determining Step in Mannich-Type Cyclizations” Journal of the American Chemical Society 1987, 109, 6107–6114 S. J. McCann and L. E. Overman |
| 97 | “Intramolecular Alkene Arylations for Rapid Assembly of Polycyclic Systems Containing Quaternary Centers. A New Synthesis of Spirooxindoles and Other Fused and Bridged Ring Systems” Journal of Organic Chemistry 1987, 52, 4130–4133 M. M. Abelman, T. Oh and L. E. Overman |
| 96 | “Ring-Enlarging Furan Annulations” Journal of Organic Chemistry 1987, 52, 3711–3712 P. M. Herrinton, M. H. Hopkins, P. Mishra, M. J. Brown and L. E. Overman |
| 95 | “A Naturally Occurring Erythro Diastereomer of Pumiliotoxin B” Tetrahedron 1988, 44, 6795–6800 H. M. Garraffo, M. W. Edwards, T. F. Spande, J. W. Daly, L. E. Overman, C. Severini and V. Erspamer |
| 94 | “Stereocontrolled Preparation of Tetrahydrofurans by Acid-Catalyzed Rearrangement of Allylic Acetals” Journal of the American Chemical Society 1987, 109, 4748–4749 M. H. Hopkins and L. E. Overman |
| 93 | “Pumiliotoxin Alkaloids: Relationship of Cardiotonic Activity to Sodium Channel Activity and Phosphatidylinositol Turnover” Journal of Medicinal Chemistry 1988, 31, 477–480 J. W. Daly, E. McNeal, F. Gusovsky, F. Ito and L. E. Overman |
| 92 | “Transition State Geometry of [3,3]-Sigmatropic Rearrangements of Iminium Ions” Journal of Organic Chemistry 1988, 53, 685–690 R. J. Doedens, G. P. Meier and L. E. Overman |
| 91 | “Cationic Cyclization Reactions of Vinylsilanes in Heterocyclic Synthesis” Chemica Scripta 1987, 27, 543–544 L. E. Overman |
| 90 | “Iminium Ion and Acyliminium Ion Initiated Cyclization Reactions of Vinylsilanes. Regiocontrolled Synthesis of Tetrahydropyridines and Related Heterocycles” Journal of the American Chemical Society 1987, 109, 6097–6107 C. Flann, T. C. Malone and L. E. Overman |
| 89 | “tert-Butyldiphenylsilylamines: Useful Protecting Groups for Primary Amines” Tetrahedron Letters 1986, 27, 4301–4304 L. E. Overman, M. E. Okazaki and P. Mishra |
| 88 | “Efficient Preparations of 8- and 9-Membered Cyclic Ethers” Journal of the American Chemical Society 1986, 108, 3516–3517 L. E. Overman, T. A. Blumenkopf, A. Castañeda and A. S. Thompson |
| 87 | “Regioselective Synthesis of Tetrahydropyridines. Synthesis of 1-(4-Methoxyphenyl)-1,2,5,6-tetrahydropyridine” Organic Syntheses 1989, 68, 188–197; Collective Volume VIII, pp 358–362 L. E. Overman, C. J. Flann and T. C. Malone |
| 86 | “Vinylsilane- and Alkynylsilane-Terminated Cyclization Reactions” Chemical Reviews 1986, 86, 857–873 T. A. Blumenkopf and L. E. Overman |
| 85 | “Heterocyclization Reactions Employing Vinylsilane Terminators” Lectures in Heterocyclic Chemistry 1985, 8, 59–67 L. E. Overman |
| 84 | “Acetal-Initiated Cyclizations of Vinylsilanes. A General Synthesis of Allylically Unsaturated Oxacyclics” Journal of the American Chemical Society 1986, 108, 1303–1304 L. E. Overman, A. Castañeda and T. A. Blumenkopf |
| 83 | “Modeling Chemical Reactivity 1. Regioselectivity of Diels–Alder Cycloadditions of Electron-Rich Dienes with Electron-Deficient Dienophiles” Journal of the American Chemical Society 1986, 108, 7381–7396 S. D. Kahn, C. F. Pau, L. E. Overman and W. J. Hehre |
| 82 | “Enantioselective Total Synthesis of (+)-Pumiliotoxin A” Journal of Organic Chemistry 1985, 50, 3669–3670 L. E. Overman and N.-H. Lin |
| 81 | “The Synthesis of Indolizidines by Intramolecular Ene Cyclizations. Preparation of (E)-Alkylidene Analogs of Pumiliotoxin A” Tetrahedron Letters 1985, 26, 4167–4170 L. E. Overman and D. Lesuisse |
| 80 | “(Z)-4-(Trimethylsilyl)-3-buten-1-ol” Organic Syntheses 1989, 68, 182–187; Collective Volume VIII, pp 609–612 L. E. Overman, M. J. Brown and S. F. McCann |
| 79 | “Stereocontrolled Synthesis of Substituted cis-Cyclopenta[b]pyrrolidines” Journal of Organic Chemistry 1985, 50, 2403–2405 L. E. Overman, M. Okazaki and E. J. Jacobsen |
| 78 | “Synthesis Applications of Cationic Aza-Cope Rearrangements. Stereocontrolled Synthesis of Hexahydro-1H-pyrrolo[2,3-d]carbazoles” Journal of Organic Chemistry 1985, 50, 4021–4028 L. E. Overman and S. R. Angle |
| 77 | “A Convenient Synthesis of D1-Pyrrolines and D1-Piperideines” Tetrahedron Letters 1984, 25, 5737–5738 L. E. Overman and R. M. Burk |
| 76 | “The Importance of Vinylsilane Stereochemistry and s-p Stabilization in Iminium Ion–Vinylsilane Cyclizations. A Short Total Synthesis of the Amaryllidaceae Alkaloid (±)-Epielwesine” Tetrahedron Letters 1984, 25, 5739–5742 L. E. Overman and R. M. Burk |
| 75 | “A Convenient Method for Obtaining trans-2-Aminocyclohexanol and trans-2-Aminocyclopentanol in Enantiomerically Pure Form” Journal of Organic Chemistry 1985, 50, 4154–4155 L. E. Overman and S. Sugai |
| 74 | “Total Synthesis of (–)-Crinine. Use of Tandem Cationic Aza-Cope Rearrangement/ Mannich Cyclizations for the Synthesis of Enantiomerically Pure Amaryllidaceae Alkaloid” Helvetica Chimica Acta 1985, 68, 745–749 L. E. Overman and S. Sugai |
| 73 | “A Convenient Synthesis of 4-Unsubstituted b-Lactams” Journal of the American Chemical Society 1985, 107, 1698–1701 L. E. Overman and T. Osawa |
| 72 | “Enantioselective Total Synthesis of Allopumiliotoxin A Alkaloids 267A and 339B” Journal of the American Chemical Society 1984, 106, 5360–5361 L. E. Overman and S. W. Goldstein |
| 71 | “A Convenient Synthesis of Unsymmetrical Secondary Amines. In Situ Formation of Unstable Formaldehyde Imines” Tetrahedron Letters 1984, 25, 1635–1638 L. E. Overman and R. M. Burk |
| 70 | “A New Class of Cardiotonic Agents: Structure-Activity Correlations for Natural and Synthetic Analogs of the Alkaloid Pumiliotoxin B” Journal of Medicinal Chemistry 1985, 28, 482–486 J. W. Daly, E. T. McNeal, L. E. Overman and D. H. Ellison |
| 69 | “Mercury(II) and Palladium(II)-Catalyzed [3,3]-Sigmatropic Rearrangements” Angewandte Chemie, International Edition in English 1984, 23, 579–586 L. E. Overman |
| 68 | “New Synthetic Route to Perhydrohistrionicotoxin Using (3Z)-4-Butyl-3-Trichloroacetamido-1,3-Butadiene” Heterocycles 1984, 22, 485–488 T. Ibuka, H. Minakata, M. Hashimoto, L. E. Overman and R. L. Freerks |
| 67 | “Recent Advances in the Total Synthesis of Pentacyclic Aspidosperma Alkaloids” Alkaloids: Chemical and Biological Perspectives” S. W. Pelletier, Ed., Volume 3, 1985, pp 275–307 L. E. Overman and M. Sworin |
| 66 | “Iminium Ion and Acyliminium Ion Initiated Cyclizations of Vinylsilanes. Regiocontrolled Construction of Unsaturated Azacyclics” Journal of the American Chemical Society 1983, 105, 6993–6994 L. E. Overman, T. C. Malone and G. P. Meier |
| 65 | “Enantioselective Total Syntheses of Pumiliotoxin B and Pumiliotoxin 251D. A General Entry to the Pumiliotoxin A Alkaloids via Stereospecific Iminium Ion-Vinylsilane Cyclizations” Journal of the American Chemical Society 1984, 106, 4192–4201 L. E. Overman, K. L. Bell and F. Ito |
| 64 | “Palladium Dichloride Catalyzed Cope Rearrangements of Functionalized Acyclic 1,5-Dienes” Tetrahedron Letters 1983, 24, 3757–3760 L. E. Overman and A. F. Renaldo |
| 63 | “Synthesis Applications of Cationic Aza-Cope Rearrangements. Stereoselective Synthesis of cis– and trans-3a-Aryl-4-oxodecahydrocyclohepta[b]pyrroles” Journal of Organic Chemistry 1983, 48, 3393–3400 L. E. Overman, E. J. Jacobsen and R. J. Doedens |
| 62 | “Applications of Cationic Aza-Cope Rearrangements for Alkaloid Synthesis. Stereoselective Preparation of cis-3a-Arylhydroindoles and a New Short Route to Amaryllidaceae Alkaloids” Journal of the American Chemical Society 1983, 105, 6629–6637 L. E. Overman, L. T. Mendelson and E. J. Jacobsen |
| 61 | “Carbon–Carbon Bond Formation Under Mild Conditions via Tandem Cationic Aza-Cope–Mannich Reactions. A Convenient Synthesis of Polysubstituted Pyrrolidines” Journal of the American Chemical Society 1983, 105, 6622–6629 L. E. Overman, M. Kakimoto, M. Okazaki and G. P. Meier |
| 60 | “Palladium Dichloride Promoted Cyclizations of 1,5-Dienes. A New Method for Forming Cyclohexenes” Tetrahedron Letters 1983, 24, 2235–2238 L. E. Overman and A. F. Renaldo |
| 59 | “Importance of Allylic Interactions and Stereoelectronic Effects in Dictating the Steric Course of the Reaction of Iminium Ions with Nucleophiles. An Efficient Total Synthesis of (+)-Gephyrotoxin” Journal of the American Chemical Society 1983, 105, 5373–5379 L. E. Overman, D. Lesuisse and M. Hashimoto |
| 58 | “Preparation and Diels-Alder Reactions of 1,3-Dienes Containing Both Sulfur and Nitrogen Substituents. Complete Orientational Control by the Acylamino Group” Journal of the American Chemical Society 1983, 105, 6335–6337 L. E. Overman, C. B. Petty, T. Ban and G. T. Huang |
| 57 | “Carbonyl Participation in the Reaction of N-Acyl-2-isopropenylpyrrolidines with Halogen Electrophiles. Stereocontrolled Preparation of Enantiomerically Pure Synthons for the Synthesis of Pumiliotoxin A Alkaloids” Tetrahedron Letters 1982, 23, 4887–4890 L. E. Overman and R. J. McCready |
| 56 | “A New Approach for the Total Synthesis of Pentacyclic Aspidosperma Alkaloids. Total Synthesis of dl-16-Methoxytabersonine” Journal of Organic Chemistry 1983, 48, 2685–2690 L. E. Overman, M. Sworin and R. M. Burk |
| 55 | “Highly Stereocontrolled Reduction of a’-Alkoxyenones to Give Either the Threo or Erythro Allylic 1,2-Diol. Assignment of the Threo Configuration to the C-15, C-16 Diol of Pumiliotoxin B” Tetrahedron Letters 1982, 23, 2355–2358 L. E. Overman and R. J. McCready |
| 54 | “The Cyanomethyl Group for Nitrogen Protection and Iminium Ion Generation in Ring-Enlarging Pyrrolidine Annulations. A Short Synthesis of the Amaryllidaceae Alkaloid dl-Crinine” Tetrahedron Letters 1982, 23, 2741–2744 L. E. Overman and E. J. Jacobsen |
| 53 | “Synthesis Applications of Aza-Cope Rearrangements. Stereocontrolled Synthesis of Cyclohepta[b]pyrroldines” Tetrahedron Letters 1982, 23, 2737–2740 L. E. Overman and E. J. Jacobsen |
| 52 | “Synthesis Applications of Aza-Cope Rearrangements. Stereoselective Synthesis of trans-2-Alkyl-cis-3a-aryloctahydroindolones” Tetrahedron Letters 1982, 23, 2733–2736 L. E. Overman, L. T. Mendelson and L. A. Flippin |
| 51 | “Stereocontrolled Synthesis of Exocyclic Trisubstituted Double Bonds by Stereospecific Iminium Ion–Vinylsilane Cyclizations. A Short Synthetic Route to Indoloquinolizidine Alkaloids” Journal of Organic Chemistry 1982, 47, 5297–5300 L. E. Overman and T. C. Malone |
| 50 | “Chair Topology of the Palladium Dichloride-Catalyzed Cope Rearrangement of Acyclic 1,5-Dienes” Journal of the American Chemical Society 1982, 104, 7225–7231 L. E. Overman and E. J. Jacobsen |
| 49 | “Synthesis Applications of Aza-Cope Rearrangements. A Stereoselective Synthesis of cis-3a-Aryloctahydroindolones and a New Short Entry to Amaryllidaceae Alkaloids” Journal of the American Chemical Society 1981, 103, 5579–5581 L. E. Overman and L. T. Mendelson |
| 48 | “Synthesis Applications of Aza-Cope Rearrangements. A Stereoselective Synthesis of 9a-Arylhydrolilolidines and a New Approach to the Synthesis of Aspidosperma Alkaloids” Tetrahedron (Symposium in Print) 1981, 37, 4041–4045 L. E. Overman and M. Sworin |
| 47 | “A Short Total Synthesis of (+)-Perhydrogephyrotoxin” Journal of Organic Chemistry 1981, 46, 2833–2835 L. E. Overman and R. L. Freerks |
| 46 | “Enantiospecific Total Synthesis of Dendrobatid Toxin 251D. A Short Chiral Entry to the Cardiac-Active Pumiliotoxin A Alkaloids via Stereospecific Iminium Ion–Vinylsilane Cyclizations” Journal of the American Chemical Society 1981, 103, 1851–1853 L. E. Overman and K. L. Bell |
| 45 | “Facile Aminolysis of Epoxides with Diethylaluminum Amides” Tetrahedron Letters 1981, 22, 195–199 L. E. Overman and L. A. Flippin |
| 44 | “Preparation of Substituted 2-Pyridones by Thermal Rearrangement of Propargylic Pseudoureas. Improvements in the 2-Pyridone Yields by Variations of the Pseudourea NR2 Substituent” Journal of Organic Chemistry 1981, 46, 811–813 L. E. Overman and J. P. Roos |
| 43 | “A New Method for Stereoselective Piperidine Annulation. Directing the 2-Azonia-[3,3]-Sigmatropic Rearrangement by Irreversible Hydrolysis” Journal of Organic Chemistry 1980, 45, 5229–5230 L. E. Overman and T. Yokomatsu |
| 42 | “Diels–Alder Reactions of 1-N-Acylamino-1,3-dienes” Journal of the American Chemical Society 1981, 103, 2816–2822 L. E. Overman, R. L. Freerks, C. B. Petty, L. A. Clizbe, R. K. Ono, G. F. Taylor and P. J . Jessup |
| 41 | “Thermal Rearrangements of Propargylic Trichloroacetimidates. Synthesis of Trichloroacetamido-1,3-and 1,2-dienes” Journal of the American Chemical Society 1981, 103, 2807–2816 L. E. Overman, L. A. Clizbe, R. L. Freerks and C. K. Marlowe |
| 40 | “Pumiliotoxin-C and Synthetic Analogs: A New Class of Nicotinic Antagonists” Molecular Pharmacology 1982, 22, 565–573 Y. Nimitkitpaisan, J. W. Daly, P. J. Jessup, L. E. Overman, J. E. Warnick and E. X. Albuquerque |
| 39 | “Allylic and Propargylic Imidic Esters in Organic Synthesis” Accounts of Chemical Research 1980, 13, 218–224 L. E. Overman |
| 38 | “Stereoselective Total Synthesis of (+)-Perhydrogephyrotoxin. Synthetic Applications of Directed 2-Azonia-[3,3]-Sigmatropic Rearrangements” Journal of the American Chemical Society 1980, 102, 1454–1456 L. E. Overman and C. Fukaya |
| 37 | “Palladium(II)Chloride-Catalyzed Cope Rearrangements of Acyclic 1,5-Dienes” Journal of the American Chemical Society 1980, 102, 865–867 L. E. Overman and F. M. Knoll |
| 36 | “Directed 2-Azonia-[3,3]-Sigmatropic Rearrangements. A Convenient Preparation of Substituted 1-Azaspiro[4,5]decanes” Tetrahedron Letters 1979, 42, 4041–4044 L. E. Overman, M. Kakimoto and M. Okawara |
| 35 | “Synthetic Applications of N-Acylamino-1,3-dienes. Control of Endo Stereoselectivity by the Acyl Substituent. A Stereospecific Synthesis of the Analgesic Tilidine” Journal of Organic Chemistry 1979, 44, 4183–4185 L. E. Overman, C. B. Petty and R. J. Doedens |
| 34 | “Preparation of Substituted 2-Pyridones by Thermal Rearrangement of Propargylic Pyrrolidine Pseudoureas” Journal of the American Chemical Society 1980, 102, 747–754 L. E. Overman, S. Tsuboi, J. P. Roos and G. F. Taylor |
| 33 | “4-Methylene-1,5-Dihydrooxazoles: Isolation, Properties and Use for the Preparation of Substituted Oxazoles” Journal of Organic Chemistry 1979, 44, 2323–2325 L. E. Overman, S. Tsuboi and S. Angle |
| 32 | “The Preparation of Trichloroacetamido-1,2-dienes” Tetrahedron Letters 1979, 20, 599–603 L. E. Overman, C. M. Marlowe and L. A. Clizbe |
| 31 | “Palladium(II)-Catalyzed Rearrangement of Allylic Acetates” Tetrahedron Letters 1979, 20, 321–324 L. E. Overman and F. M. Knoll |
| 30 | “Carbon–Carbon Bond Formation via Directed 2-Azonia-[3,3]-Sigmatropic Rearrangements. A New Pyrrolidine Synthesis” Journal of the American Chemical Society 1979, 101, 1310–1313 L. E. Overman and M. Kakimoto |
| 29 | “Preparation of Rearranged Allylic Isocyanates from the Reaction of Allylic Alkoxides with Cyanogen Chloride” Journal of Organic Chemistry 1978, 43, 4564–4567 L. E. Overman and M. Kakimoto |
| 28 | “Synthetic Applications of N-Acylamino-1,3-dienes. An Efficient Stereospecific Total Synthesis of dl-Pumiliotoxin C and a General Entry to cis-Decahydroquinoline Alkaloids” Journal of the American Chemical Society 1978, 100, 5179–5185 L. E. Overman and P. J. Jessup |
| 27 | “How Important is Secondary Orbital Overlap in Determining the Regioselectivity of Diels–Alder Reactions?” Tetrahedron Letters 1978, 19, 1313–1316 I. Fleming, J. P. Michael, L. E. Overman and G. F. Taylor |
| 26 | “trans-1-N-Acylamino-1,3-dienes: Preparation from Dienoic Acids” Journal of Organic Chemistry 1978, 43, 2164–2167 L. E. Overman, G. F. Taylor, C. B. Petty and P. J. Jessup |
| 25 | “Mild Procedures for Interconverting Allylic Oxygen Functionality. Cyclization-Induced [3,3]-Sigmatropic Rearrangement of Allylic Carbamates” Journal of the American Chemical Society 1978, 100, 4822–4834 L. E. Overman, C. B. Campbell and F. M. Knoll |
| 24 | “1-N-Acylamino-1,3-dienes from 2,4-Pentadienoic Acids by the Curtius Rearrangement: Benzyl trans-1,3-Butadiene-1-carbamate” Organic Syntheses 1979, 59, 1–9; Collective Volume VI, pp 95–101 P. J. Jessup, C. B. Petty, J. Roos and L. E. Overman |
| 23 | “The Diels–Alder Reaction Between trans-1-N-Acylamino-1,3-dienes and Methyl Acrylate. A Correlation Between Diene Photoelectron Ionization Potentials and Reactivity, Stereoselectivity and Regioselectivity” Journal of the American Chemical Society 1978, 100, 3182–3189 L. E. Overman, G. F. Taylor, K. N. Houk and L. S. Domelsmith |
| 22 | “A Short Stereospecific Total Synthesis of dl-Pumiliotoxin C” Tetrahedron Letters 1977, 18, 1253–1256 L. E. Overman and P. J. Jessup |
| 21 | “A New Synthesis of 2-Pyridones. Solution Thermolysis of Propargylic Pseudoureas” Journal of the American Chemical Society 1977, 99, 2813–2815 L. E. Overman and S. Tsuboi |
| 20 | “Gas Phase Acidities of the 2-Butenes. Regarding the Use of Organometallics as Models for Free Carbanions” Journal of the American Chemical Society 1977, 99, 1976–1977 J. E. Bartmess, W. J. Hehre, R. T. McIver, Jr. and L. E. Overman |
| 19 | “Mercury(II)-Catalyzed 3,3-Sigmatropic Rearrangements of Allylic N,N-Dimethylcarbamates: A Mild Method for Allylic Equilibrations and Contrathermodynamic Allylic Isomer Enrichments” Journal of Organic Chemistry 1976, 41, 3338–3340 L. E. Overman and C. B. Campbell |
| 18 | “N-Acyl-1-amino-1,3-dienes: 1-Amino-1,3-diene Synthetic Equivalents for the Diels-Alder Reaction” Tetrahedron Letters 1976, 17, 3089–3092 L. E. Overman, G. F. Taylor and P. J. Jessup |
| 17 | “The Preparation of Ureas by the Thermolysis of Allylic Pseudoureas” Tetrahedron Letters 1976, 17, 1145–1148 S. Tsuboi, P. Stromquist and L. E. Overman |
| 16 | “Synthesis of Trichloroacetamido-1,3-dienes. Useful Aminobutadiene Equivalents for the Diels–Alder Reaction” Journal of the American Chemical Society 1976, 98, 2352–2355 L. E. Overman and L. A. Clizbe |
| 15 | “A General Method for the Synthesis of Amines by the Rearrangement of Allylic Trichloroacetimidates. 1,3-Transposition of Alcohol and Amine Functions” Journal of the American Chemical Society 1976, 98, 2901–2910 L. E. Overman |
| 14 | “Nucleophilic Cleavage of the Sulfur–Sulfur Bond by Phosphorus Nucleophiles. IV. Kinetic Study of the Reduction of Alkyl Disulfides with Triphenylphosphine and Water” Journal of the American Chemical Society 1976, 98, 771–775 L. E. Overman and E. M. O’Connor |
| 13 | “Allylically Transposed Amines from Allylic Alcohols: 3,7-Dimethyl-1,6-Octadien-3-Amine” Organic Syntheses 1978, 58, 4–11: Collective Volume VI, pp 507–511 L. A. Clizbe and L. E. Overman |
| 12 | “Nucleophilic Cleavage of the Sulfur–Sulfur Bond by Phosphorus Nucleophiles III. Kinetic Study of the Reduction of a Series of Ethyl Aryl Disulfides with Triphenylphosphine and Water” Journal of Organic Chemistry 1975, 40, 2779–2781 L. E. Overman and S. T. Petty |
| 11 | “Synthesis of 1-Azaspiro[5.5]undec-7-en-2-one” Tetrahedron Letters 1975, 16, 1149–1152 L. E. Overman |
| 10 | “Nucleophilic Cleavage of the Sulfur-Sulfur Bond by Phosphorous Nucleophiles. Kinetic Study of the Reduction of Aryl Disulfides with Triphenylphosphine and Water” Journal of the American Chemical Society 1974, 96, 6081–6089 L. E. Overman, D. Matzinger, E. M. O’Connor and J. D. Overman |
| 9 | “Hemiacetal-Mediated Reactions. Directed Synthesis of Diols and Acetals” Journal of Organic Chemistry 1974, 39, 1474–1481 L. E. Overman and C. B. Campbell |
| 8 | “Thermal- and Mercuric Ion-Catalyzed [3,3]-Sigmatropic Rearrangements of Allylic Trichloroacetimidates. The 1,3-Transposition of Alcohol and Amine Functions” Journal of the American Chemical Society 1974, 96, 597–599 L. E. Overman |
| 7 | “The Reduction of Aryl Disulfides with Triphenylphosphine and Water” Synthesis 1974, 59–60 L. E. Overman, J. Smoot and J. D. Overman |
| 6 | “Intramolecular Delivery of a Water Equivalent in the Oxymercuration Reaction. Conversion of an Allylic Alcohol Into a cis-Vicinal Diol” Journal of the Chemical Society, Chemical Communications 1972, 1196–1198 L. E. Overman |
| 5 | “Dehydrogenase Enzyme Models. Approximation of an Alcohol and a Pyridinium Ring” Journal of Organic Chemistry 1972, 37, 4214–4218 L. E. Overman |
| 4 | “Solvolytic Rearrangements Accompanied by Multiple Alkyl Shifts” Journal of the American Chemical Society 1971, 93, 2247–2253 H. W. Whitlock, Jr. and L. E. Overman |
| 3 | “An ‘Artificial Enzyme’ Combining a Metal Catalytic Group and Hydrophobic Binding Cavity” Journal of the American Chemical Society 1970, 91, 1075–1077 R. Breslow and L. E. Overman |
| 2 | “The Chemical Behavior of o-Bis(phenylethynyl)benzene Toward Some Electrophilic and Nucleophilic Reagents” Journal of Organic Chemistry 1969, 34, 879–886 H. W. Whitlock, Jr., P. V. Sandvick, L. E. Overman and P. B. Reichardt |
| 1 | “Angular Methylation” Journal of Organic Chemistry 1969, 34, 1962–1963 H. W. Whitlock, Jr. and L. E. Overman |
