{"id":2034,"date":"2021-11-11T18:09:46","date_gmt":"2021-11-11T18:09:46","guid":{"rendered":"https:\/\/sites.ps.uci.edu\/overman\/?page_id=2034"},"modified":"2022-01-25T00:26:15","modified_gmt":"2022-01-25T00:26:15","slug":"publications-2","status":"publish","type":"page","link":"https:\/\/sites.ps.uci.edu\/overman\/publications-2\/","title":{"rendered":"Publications"},"content":{"rendered":"\n<pre class=\"wp-block-preformatted\">402. \t\"Constructing Saturated Guanidinum Heterocycles by Cycloaddition of N-Amidinyliminium Ions with Indoles\"\n\tT. K. Allred, M. B. Shaghafi, P.-P. Chen, Q. Tran, K. N. Houk, L. E. Overman\n\tOrganic Letters 2021, 23, .  https:\/\/doi.org\/10.1021\/acs.orglett.1c02832\n\n401.\t\"Potent Anticancer Effects of Epidithiodiketopiperazine NT1721 in Cutaneous T Cell Lymphoma\"\n\tM. Lin, C. M. Kowolik, J. Xie, S. Yadav, L. E. Overman, D. A. Horne\n\tCancers, 2021, 13, 3367. https:\/\/doi.org\/10.3390\/cancers13133367 \n\n400. \t\"Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis\"\n\tS. P. Pitre, L. E. Overman\n\tChem. Rev. 2021, 121,  https:\/\/doi.org\/10.1021\/acs.chemrev.1c00247\n\n399.\t\"Reducing the age-associated increase in H3K9 trimethylation restores hippocampal BDNF signaling and synaptic plasticity\"\nL. Tong, C. Butler, N. Berchtold, A. I. Tucker, K. Tseung, L. Overman, C. W. Cotman\n J. Neurosci. 2021, 23, 3611\u20133622\n\n398.\t\"Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible Light Irradiation of EDA Complexes\"\n\tS. P. Pitre, T. K. Allred, L. E. Overman\n\tOrganic Letters 2021, 23, 1103\u20131106\n\n397.\t\"General Access to Concave-Substituted cis-Dioxabicyclo[3.3.0]octanones: Enantioselective Total Syntheses of Macfarlandin C and Dendrillolide A\"\n\tT. K. Allred, A. P. Dieskau, P. Zhao, G. L. Lackner, L. E. Overman\n\tJournal of Organic Chemistry 2020, 85, 15532\u201315551\n\n396.\t\"Enantioselective Total Synthesis of Macfarlandin C, a Spongian Diterpenoid Harboring a Concave-Substituted cis-Dioxabicyclo[3.3.0]octanone Fragment\"\n\tT. K. Allred, A. P. Dieskau, P. Zhao, G. L. Lackner, L. E. Overman\n\tAngewandte Chemie International Edition 2020, 59, 6268\u20136272\n\t\n395. \t\"Attenuation of hedgehog\/GLI signaling by NT1721 extends survival in pancreatic cancer\" \n\tC. M. Kowolik, M. Lin, J. Xie, L. E. Overman, D. A. Horne \n\tJournal of Experimental Clinical Cancer Research 2019, 38:431 (https:\/\/doi.org\/10.1186\/s13046-019-1445-z) \n \n\n394. \t\"Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization Cross-Coupling Cascade\"\n\tN. A. Weires, Y. Slutskyy, L. E. Overman\n\tAngewandte Chemie International Edition 2019, 58, 8561\u20138565\n\n393.\t\"Tertiary Alcohols as Radical Precursors for the Introduction of Tertiary Substituents into Heteroarenes\"\n\tS. P. Pitre, M. Muuronen, D. A. Fishman, L. E. Overman\n\tACS Catalysis 2019, 9, 3413\u20133418\n\n\n392.\t\"Forging C(sp3)\u2013C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules\"\n\tS. P. Pitre, N. A. Weires, L. E. Overman\n\tJournal of the American Chemical Society 2019, 141, 2800\u20132813\n\n391.\t\"Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space\" \n\tS. E. Kearney, L. E. Overman, 98 others authors, Rohde, J. M.\n\tACS Central Science 2018, 4, 1727\u20131741\n\n390.\t\"Discussion Addendum for: Preparation of the COP Catalysts: [(S)-COP-OAc]2, [(S)- COP-Cl]2, and (S)-COP-hfacac\"\n\tJ. S. Cannon, L. E. Overman\n\tOrganic Syntheses 2018, 95, 500\u2013511; DOI: 10.15227\/orgsyn.095.0500\n\n389. \t\u201cTotal Synthesis of (\uf02d)-Chromodorolide B by a Computationally-Guided Radical Addition\/Cyclization\/Fragmentation Cascade\u201d\nD. J. Tao, Y. Slutskyy, M. Muuronen, A. Le, P. Kohler, L. E. Overman \nJournal of the American Chemical Society 2018, 140, 3091\u20133102\n\n388.    \u201c1,6-Addition of Tertiary Carbon Radicals Generated From Alcohols or Carboxylic Acids by Visible-Light Photoredox Catalysis\u201d\n\tS. Y. Abbas, P. Zhao, L. E. Overman\n\tOrganic Letters 2018, 20, 868\u2013871\n\n387.     \u201cShort Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide via Convergent Fragment Coupling Using a Tertiary Carbon Radical\u201d\n\tM. R. Garnsey, Y. Slutskyy, C. R. Jamison, P. Zhao, J. Lee, Y. H. Rhee, L. E. Overman\n\tJournal of Organic Chemistry 2018, 83, 6958\u20136976 \n\n386.\t\u201cVisible-Light Photocatalysis in the Synthesis of Natural Products\u201d\n\tG. L. Lackner, K. W. Quasdorf, L. E. Overman\n\tIn Visible Light Photocatalysis in Chemistry, C. Stephenson and D. W. C. MacMillan, \tEds., Wiley-VCH, Weinheim, Germany, 2018, Chapter 9, pp 283\u2013297.\n\n385. \t\u201cFragment Coupling and Formation of Quaternary Carbons by Visible-Light Photoredox \tCatalyzed Reaction of tert-Alkyl Hemioxalate Salts and Michael Acceptors\u201d\n\tC. R. Jamison, Y. Slutskyy, L. E. Overman\n\tOrganic Syntheses 2017, 94, 167\u2013183 \n\n384. \t\u201cVersatile Construction of 6-Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones. Short \tEnantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C\u201d\n\tY. Slutskyy, C. R. Jamison, P. Zhao, J. Lee, Y. H. Rhee, L. E. Overman\n\tJournal of the American Chemical Society 2017, 139, 7192\u20137195\n\n383. \t\"NT1721, a novel epidithiodiketopiperazine, exhibits potent in vitro and in vivo efficacy \tagainst acute myeloid leukemia\" \n\tC. M. Kowolik, M. Lin, J. Xie, L. E. Overman and D. A. Horne \n\tOncotarget 2016, 7, 86186\u201386197\n\n382.\t\"Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts\" \n\tJ. S. Cannon and L. E. Overman\n\tAccounts of Chemical Research 2016, 49, 2220\u20132231 \t\n\n381. \t\u201cAnalogues of Marine Guanidine Alkaloids Are in Vitro Effective against Trypanosoma cruzi and Selectively Eliminate Leishmania (L.) infantum Intracellular Amastigotes\u201d \n\tL. F. Martins, J. T. Mesquita, E. G. Pinto, T. A. Costa-Silva,S. E. T. Borborema, A. J. G. Junior, B. J. Neves, C. H. Andrade,Z. A. Shuhaib, E. L. Bennett, G. P. Black, P. M. Harper, D. M. Evans, H. S. Fituri, J. P. Leyland, C. Martin, T. D. Roberts, A. J. Thornhill, S. A. Vale, A. Howard-Jones,  D. A. Thomas, H. L. Williams, L. E. Overman, R. G. S. Berlinck, P. J. Murphy, and A. G. Tempone\n \tJ. Nat. Prod. 2016, 79, 2202\u20132210\n\n380. \t\"Fragment Coupling With Tertiary Radicals Generated By Visible-Light Photocatalysis\"\n\tC. R. Jamison and L. E. Overman\n\tAccounts of Chemical Research 2016, 49, 1578\u20131586\n\n379. \t\u201cGeneration of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins\u201d\n\tY. Slutskyy and L. E. Overman*\n\tOrganic Letters 2016, 18, 2564\u20132567\n\n378.\t\u201cShort Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor\u201d\n\tY. Slutskyy, C. R. Jamison, G. L. Lackner, D. S. M\u00fcller, A. P. Dieskau, N. L. Unteidt, and L. E. Overman\n\tJournal of Organic Chemistry 2016, 81, 7029\u20137035. \n377. \t\u201cDiastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes\u201d\n\tD. J. Tao, M. Muuronen, Y. Slutskyy, A. Le, F. Furche, and L. E. Overman\n\tChemistry \u2013 A European Journal 2016, 22, 8786\u20138790\n\n376. \t\u201cH3K9me3 Inhibition Improves Memory, Promotes Spine Formation and Increases BDNF Levels in the Aged Hippocampus\u201d\n\tS.  Snigdha, G. A. Prieto, A. Petrosyan, B. M. Loertscher, A. P. Dieskau, L. E. Overman, \n\tand C. Cotman\n\tJournal of Neuroscience 2016, 36, 3611\u20133622. PMCID: PMC4804016\n\n375.\t\u201cTotal Synthesis of (\u2013)-Chromodorolide B\u201d\n\tD. J. Tao, Y. Slutzkyy, and L. E. Overman\t\n\tJournal of the American Chemical Society 2016, 138, 2186\u20132189. PMCID:PMC \t4864965\n\n374.\t\"Ligand-Controlled Diastereoselective 1,3-Dipolar Cycloadditions of Azomethine Ylides \tWith Methacrylonitrile\" \t\n\tM. C. Walton, Y.-F. Yang, X. Hong, K. N. Houk, and L. E. Overman\n\tOrganic Letters 2015, 17, 6166\u20136169\n373.\t\"Synthetic Strategies Toward Natural Products Containing Contiguous Stereogenic Quaternary Carbons\" \n\tM. B\u00fcschleb, S. Dorich, S.Hanessian, D. Tao, K. B. Schenthal, and L. E. Overman\nAngewandte Chemie International Edition 2016, 55, 4156\u20134186. PMCID:PMC 26836448\n372. \t\"Synthesis of 2,5-Diaryl-1,5-Dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis\"\n\tG. Pratsch and L. E. Overman\n\tJournal of Organic Chemistry 2015, 80, 11388\u201311397. PMCID: PMC4697828\n371.\t\u201cOxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling\u201d \nC. C. Nawrat, C. R. Jamison, Y. Slutskyy, D. W. C. MacMillan, and L. E. Overman \nJournal of the American Chemical Society 2015, 137, 11270\u201311273. PMCID: \tPMC4632490\n370.\t\u201cTricyclic Analogues of Epidithiodioxopiperazine Alkaloids with Promising In Vitro and In Vivo Antitumor Activity\u201d \nM. Baumann, A. P. Dieskau, B. M. Loertscher, M. C. Walton, S. Nam, J. Xie, D. Horne, and L. E. Overman \nChemical Science, 2015, 6, 4451\u20134457. PMCID: PMC4540405\n\n369.\t\u201cConstructing Quaternary Carbons from (N-Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis\u201d \nG. Pratsch, G. L. Lackner and L. E. Overman\nJournal of Organic Chemistry, 2015, 80, 6025\u20136036. PMCID: PMC4699447\n\n368.\t\u201cFragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis\u201d\nG. L. Lackner, Kyle W. Quasdorf, G. Pratsch and L. E. Overman \nJournal of Organic Chemistry, 2015, 80, 6012\u20136024. PMCID: PMC4697963\n\n367.\t\u201cStereocontrolled enantioselective total synthesis of the [2+2] quadrigemine alkaloids\u201d\nS. M. Canham, B. D. Hafensteiner, A. D. Lebsack, T. L. May-Dracka, S. Nam, B. A. Stearns, and L. E. Overman \nTetrahedron 2015, 71, 6424\u20136436. PMCID: PMC4526107\n\n366.\t\u201cConstructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products\u201d\nD. S. M\u00fcller, N. L. Untiedt, A. P. Dieskau, G. L. Lackner and L. E. Overman\nJournal of the American Chemical Society 2015, 137, 660\u2013663\n365.\t\"Catalytic Enantioselective Synthesis of Quaternary Carbon Stereocenters\"\nK. W. Quasdorf and L. E. Overman\nNature 2014, 516, 181\u2013194. PMCID: PMC4697831\n\n364.\t\"The Insulin Secretory Action of Novel Polycyclic Guanidines: Discovery through Open Innovation Phenotypic Screening, and Exploration of Structure-Activity Relationships\"\n M. B. Shaghafi, D. G. Barrett, F. S. Willard and L. E. Overman\nBioorganic &amp; Medicinal Chemistry Letters 2014, 24, 1031\u20131036.  \n\n363.\t\"Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates\"\nG. L. Lackner, K. W. Quasdorf and L. E. Overman\nJournal of the American Chemical Society 2013, 135, 15342\u201315345. PMCID: PMC3856227\n\n362.\t\"Enantioselective Synthesis of Angularly Substituted 1-Azabicylic Rings: Coupled Dynamic Kinetic Epimerization and Chirality Transfer\"\nZ. D. Aron, T. Ito, T. L. May, L. E. Overman and J. Wang\nJournal of Organic Chemistry 2013, 78, 9929\u20139948. PMCID: PMC3843940 \n\n361. \t\"Enantioselective Total Synthesis of Plectosphaeroic Acids B and C\"\nS. Y. Jabri and L. E. Overman \nJournal of Organic Chemistry 2013, 78, 8766\u20138788. PMCID: PMC3819034 \n\n360. \t\"Enantioselective Total Synthesis of Plectosphaeroic Acid B\"\nS. Y. Jabri and L. E. Overman \nJournal of the American Chemical Society 2013, 135, 4231\u20134234 PMCID: PMC3611964\n\n359. \t\"A General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors. Enantioselective Total Syntheses of (+)- and (\u2013)-Gliocladine C, (+)-Leptosin D, (+)-T988C, (+)-Bionectin A and (+)-Gliocladin A\"\nJ. E. DeLorbe, D. Horne, R. Jove, S. M. Mennen, S. Nam, F-L. Zhang and L. E. Overman\nJournal of the American Chemical Society 2013, 135, 4117\u20134128. PMCID: PMC3640572\n\n358. \t\"Origins of Stereoselectivities of Dihydroxylations of cis-Bicyclo[3.3.0]octenes\"\nH. Wang, P. Kohler, L. E. Overman and K. Houk\nJournal of the American Chemical Society 2012, 134, 16054\u201316058. PMCID: PMC3460691\n\n357.\t\u201cA Concise Synthesis of (\u2013)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition\u201d\nM. J. Schnermann and L. E. Overman\nAngewandte Chemie International Edition 2012, 51, 9576\u20139580. PMCID: PMC3517069\n\n356.\t\u201cForming Tertiary Organolithium and Organocuprates from Nitrile Precursors and their Bimolecular Reactions with Carbon Electrophiles to Form Quaternary Carbon Stereocenters\u201d\nM. J. Schnermann, N. L. Untiedt, G. Jim\u00e9nez-Os\u00e9s, K. N. Houk and L. E. Overman\nAngewandte Chemie International Edition 2012, 51, 9581\u20139586. PMCID: PMC3517041\n\n355.\t\u201cTotal Synthesis of (+)-Sieboldine A: Evolution of A Pinacol-Terminated Cyclization Strategy\u201d\nS. M. Canham, D. J. France and L. E. Overman\nJournal of Organic Chemistry 2013, 78, 9\u201334\n\n354.\t\u201cPalladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles\u201d\nJ. S. Cannon, A. C. Olson, L. E. Overman and N. S. Solomon\nJournal of Organic Chemistry 2012, 77, 1961\u20131973. PMCID: PMC3296363\n\n353.\t\u201cPalladacyclic Imidazoline-Naphthalene Complexes: Synthesis and Catalytic Performance in Pd(II)-Catalyzed Enantioselective Reactions of Allylic Trichloroacetimidates\u201d \nJ. S. Cannon, J. H. Frederich and L. E. Overman\nJournal of Organic Chemistry 2012, 77, 1939\u20131951. PMCID: PMC3288570\n\n352.\t\u201cIs There No End to the Total Syntheses of Strychnine? Lessons Learned for Strategy and Tactics in Total Synthesis\u201d \nJ. S. Cannon and L. E. Overman\nAngewandte Chemie International Edition 2012, 51, 4288\u20134311\n\n351.\t\u201cEnantioselective Total Synthesis of Aplyviolene\u201d \nL. E. Overman and M. J. Schnermann\nJournal of the American Chemical Society 2011, 133, 16425\u201316427. PMCID: PMC3205941 \n\n350.\t\u201cDivergent Synthesis and Chemical Reactivity of Bicyclic Lactone Fragments of Complex Rearranged Spongian Diterpenes\u201d \nM. J. Schnermann, C. M. Beaudry, N. E. Genung, S. M. Canham, N. L. Untiedt, B. D. W. Karanikolas, C. S\u00fctterlin and L. E. Overman\nJournal of the American Chemical Society 2011, 133, 17494\u201317503. PMCID: PMC3202687\n\n349.\t\u201cIdentification of an Unexpected 2-Oxonia[3,3]sigmatropic Rearrangement\/Aldol Pathway in the Formation of Oxacyclic Rings. Total Synthesis of (+)-Aspergillin PZ\u201d S. M. Canham, L. E. Overman and P. S. Tanis\nTetrahedron 2011, 67, 9837\u20139843. PMCID: PMC3327308\n\n348.\t\u201cEnantioselective Total Synthesis of (+)-Gliocladin C and (+)-Gliocladine C. A Convergent Construction of Cyclotryptamine-Fused Polyoxopiperazines and a General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors\u201d\nJ. E. DeLorbe, S. Y. Jabri, S. M. Mennen, L. E. Overman and F-L. Zhang\nJournal of the American Chemical Society 2011, 133, 6549\u20136552. PMCID: PMC3090078\n\n347.\t\u201cTotal Synthesis of (+)-Condylocarpine (+)-Isocondylocarpine, and (+)-Tubotaiwine\u201d\nC. L. Martin, S. Nakamura, R. Otte and L. E. Overman\nOrganic Letters 2011, 13, 138\u2013141. PMCID: PMC3014433\n\n346.\t\u201cTotal Synthesis of (+)-Nankakurines A and B and (\u00b1)-5-epi-Nankakurine A\u201d\nR. A. Altman, B. L. Nilsson, L. E. Overman, J. Read de Alaniz, J. M. Rohde and V. Taupin\nJournal of Organic Chemistry 2010, 75, 7519\u20137534. PMCID: PMC3038189\n\n345.\t\u201cMechanism of the Cobalt Oxazoline Palladacycle (COP)-Catalyzed Asymmetric Synthesis of Allylic Esters\u201d \nJ. S. Cannon, S. F. Kirsch, L. E. Overman and H. F. Sneddon\nJournal of the American Chemical Society 2010, 132, 15192\u201315203. PMCID: PMC 2967776\n\n344.\t\u201cCatalytic Asymmetric Synthesis of Chiral Allylic Esters\u201d \nJ. S. Cannon, S. F. Kirsch and L. E. Overman\nJournal of the American Chemical Society 2010, 132, 15185\u201315191. PMCID: PMC 2966826\n\n343.\t\u201cTerminating Catalytic Asymmetric Heck Cyclizations by Stereoselective Intramolecular Capture of \uf0683-Allylpalladium Intermediates: Total Synthesis of (\u2013)-Spirotryprostatin B and Three Stereoisomers\u201d \nL. E. Overman and M. D. Rosen\nTetrahedron 2010, 66, 6514\u20136525. PMCID: PMC 2921616\n\n342.\t\u201cTotal Synthesis of (+)-Sieboldine A\u201d\nS. M. Canham, D. J. France and L. E. Overman \nJournal of the American Chemical Society 2010, 132, 7876\u20137877. PMCID: PMC 2885033\n\n341.\t\u201cEnantioselective Synthesis of Angularly Substituted 1-Azabicyclic Ring Systems: Dynamic Kinetic Resolution Using Aza-Cope Rearrangements\u201d\nT. Ito, L. E. Overman and J. Wang,\nJournal of the American Chemical Society 2010, 132, 3272\u20133273. PMCID: PMC2858009\n\n340.\t\u201cGolgi Modifying Properties of Macfarlandin E and the Synthesis and Evaluation of Its 2,7-Dioxabicyclo[3.2.1]octan-3-one Core\u201d\nM. J. Schnermann, C. M. Beaudry, A. V. Egorova, R. S. Polishchuk, C. Suetterlin and L. E. Overman \nProceedings of the National Academy of Science (USA), 2010, 107, 6158\u20136163. PMCID: PMC 2851978\n\n339.\t\u201cTotal Synthesis of (\uf0b1)- and (\u2013)-Actinophyllic Acid\u201d\nC. L. Martin, L. E. Overman and J. A. Rohde\nJournal of the American Chemical Society 2010, 132, 4894\u20134906. PMCID: PMC 2851836\n\n338.\t\u201cOrigin of Stereocontrol in the Construction of the 12-Oxatricyclo[6.3.1.02,7]dodecane Ring System by Prins\u2013Pinacol Reactions\u201d\nL. E. Overman and P. A. Tanis\nJournal of Organic Chemistry 2010, 75, 455\u2013463. PMCID: PMC3077117\n\n337.\t\u201cThe Aza-Cope-Mannich Reaction\u201d\nL. E. Overman, P.  G. Humphreys and G. S. Welmaker \nOrganic Reactions 2011, 75, pp 747\u2013820\n\n336.\t\u201cCatalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols\u201d\nA. C. Olson, L. E. Overman, H. F. Sneddon and J. W. Ziller\nAdvanced Synthesis &amp; Catalysis 2009, 351, 3186\u20133192 \n\n335.\t\u201cAsymmetric Construction of Rings A\u2013D of Daphnicyclidin Type Alkaloids\u201d\nT. B. Dunn, J. M. Ellis, C. C. Kofink, J. R. Manning and L. E. Overman\nOrganic Letters 2009, 11, 5658\u20135661. PMCID: PMC2996462\n\n\n334.\t\u201cA Unified Strategy for Enantioselective Total Synthesis of Cladiellin and Briarellen Diterpenes: Total Synthesis of Briarellins E and F, and the Putative Structure of Alcyonin and Revision of Its Structure Assignment\u201d\nO. Corminboeuf, L. E. Overman and L. D. Pennington \nJournal of Organic Chemistry 2009, 74, 5458\u20135470. PMCID: PMC 2744073\n\n333.\t\u201cMolecular Rearrangements in the Construction of Complex Molecules\u201d\nL. E. Overman\nTetrahedron 2009, 65, 6432\u20136446. PMCID: PMC 2967776\n\n332. \t\u201cAbsolute Configuration of Actinophyllic Acid as Determined through Chiroptical Data\u201d\nT. Taniguchi, C. L. Martin, K. Monde, K. Nakanishi, N. Berova and L. E. Overman\nJournal of Natural Products 2009, 72, 430\u2013432. PMCID: PMC 2902975\n\n331. \t\u201cA Versatile Synthesis of Unsymmetrical 3,3'-Bioxindoles: Stereoselective Mukaiyama Aldol Reactions of 2-Siloxyindoles with Isatins\u201d\nJ. M. Ellis, L. E. Overman, H. R. Tanner and J. Wang\nJournal of Organic Chemistry 2008, 73, 9151\u20139154. PMCID: PMC 2634855\n\n330.\t\u201cEnantioselective Total Syntheses of Nankakurines A and B: Confirmation of Structure and Establishment of Absolute Configuration\u201d\nJournal of the American Chemical Society 2008, 130, 11297\u201311299. PMCID: PMC3074941\nB. L. Nilsson, L. E. Overman, J. Read de Alaniz and J. M. Rohde\n\n329.\t\u201cTotal Synthesis of (\u2013)-Actinophyllic Acid\u201d\nC. L. Martin, L. E. Overman and J. M. Rohde\nJournal of the American Chemical Society 2008, 130, 7568\u20137569. PMCID: PMC 2654095\n\n328.\t\u201cCatalytic Asymmetric Synthesis of Allylic Thiol Derivatives\u201d\nL. E. Overman, S. W. Roberts and H. Sneddon Organic Letters 2008, 10, 1485\u20131488\n\n\n327.\t\u201cTotal Synthesis of the Strychnos Alkaloid (+)\u2013Minfiensine: Tandem Enantioselective Intramolecular Heck-Iminium Ion Cyclization\u201d\nA. B. Dounay, P. G. Humphreys, L. E. Overman and A. D. Wrobleski\nJournal of the American Chemical Society 2008, 130, 5368\u20135377. PMCID: PMC 2995331\n\n326.\t\u201cConstruction of Epidithiodioxopiperazines by Directed Oxidation of Hydroxyproline-Derived Dioxopiperazines\u201d\nL. E. Overman and T. Sato Organic Letters 2007, 9, 5267\u20135270\n\n325.\t\u201cOn the Structure of Palau\u2019amine: Evidence for the Revised Relative Configuration from Chemical Synthesis\u201d\nJournal of the American Chemical Society 2007, 129, 12896\u201312900. PMCID: PMC 2593883\nB. A. Lanman, L. E. Overman, R. Paulini and N. S. White\n\n324.\t\u201cSynthesis of All Low-Energy Stereoisomers of the Tris(pyrrolidinoindoline) Alkaloid Hodgkinsine and Preliminary Assessment of Their Antinociceptive Activity\u201d\nJournal of Organic Chemistry 2007, 72, 7909\u20137914\nJ. J. Kodanko, S. Hiebert, E. A. Peterson, L. Sung, L. E. Overman, V. de Moura Linck, G. C. Goerck, T. A. Amador, M. B. Leal and E. Elisabetsky\n\n323.\t\u201cTotal Synthesis of (\u2013)-Sarain A\u201d\nJournal of the American Chemical Society 2007, 129, 11987\u201312002\nM. H. Becker, P. Chua, R. Downham, C. J. Douglas, N. K. Garg, S. Hiebert, S. Jaroch, R. T. Matsuoka, J. A. Middleton, F. W. Ng and L. E. Overman\n\n322.\t\u201cThe Asymmetric Intramolecular Mizoroki-Heck Reaction in Natural Product Synthesis\u201d The Mizoroki-Heck Reaction; M. Oestreich, Ed.; Wiley\u2013VCH, West Sussex, UK, 2009, Chapter 16, pp 533\u2013568\nA. B. Dounay and L. E. Overman\n\n321.\t\u201cTotal Synthesis of (+)-Asperazine\u201d\nTetrahedron 2007, 63, 8499\u20138513\nS. P. Govek and L. E. Overman\n\n320.\t\u201cTotal Synthesis of Complex Cyclotryptamine Alkaloids: Stereocontrolled Construction of Quarternary Carbon Stereocenters\u201d\nAngewandte Chemie, International Edition 2007, 46, 5488\u20135508\nA. Steven and L. E. Overman\n\n319.\t\u201cKinetic and Computational Analysis of the Palladium(II)-Catalyzed Asymmetric Allylic Trichloroacetimidate Rearrangement. Development of a Model for Enantioselectivity\u201d\nJournal of the American Chemical Society 2007, 129, 5031\u20135044\nM. P. Watson, L. E. Overman and R. G. Bergman\n\n318.\t\u201cCatalytic Asymmetric Synthesis of Allylic Aryl Ethers\u201d\nOrganic Letters 2007, 9, 911\u2013913\nS. F. Kirsch, L. E. Overman and N. White \n\n317.\t\u201cEnantioselective Total Synthesis of (+)-Gliocladin C\u201d\nOrganic Letters 2007, 9, 339\u2013341: PMCID: PMC 2526118\nL. E. Overman and Y. Shin\n\n316.\t\u201cPreparation of the COP Catalysts: [(S)-COP-OAc]2, [(S)-COP-Cl]2, and (S)-COP-hfacac\u201d\nOrganic Syntheses 2007, 84, 148\u2013155\nC. E. Anderson, S. F. Kirsch, L. E. Overman, C. J. Richards and M. P. Watson\n\n315. \t\u201cPreparation of (\uf0685-(S)-2-(4-Methylethyl)-Oxazolinylcyclopentadienyl)-(\uf0684-Tetraphenylcylcobutadiene)Cobalt\u201d\nOrganic Syntheses 2007, 84, 139\u2013147\nC. E. Anderson, L. E. Overman, C. J. Richards, M. P. Watson and N. White\n\n314. \t\u201cEvaluation of Strategies for the Synthesis of the Guanidine Hemiaminal Portion of Palau\u2019amine\u201d \nHeterocycles 2006, 70, 557\u2013570: PMCID: PMC 2600862\nB. A. Lanman and L. E. Overman\n\n313. \t\u201cEnantioselective Total Synthesis of Guanacastepene N Using an Uncommon 7-Endo Heck Cyclization as a Pivotal Step\u201d \nJournal of the American Chemical Society 2006, 128, 13095\u201313101\nS. Iimura, L. E. Overman, R. Paulini and A. Zakarian\n\n312. \t\u201cStereocontrolled Synthesis of Functionalized cis-Cyclopentapyrazolidines by 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines\u201d \nJournal of Organic Chemistry 2006, 71, 9144\u20139152: PMCID: PMC 2516743\nJ. Gergely, J. B. Morgan and L. E. Overman\n\n311. \t\u201cConcise Synthesis of Guanidine-Containing Heterocycles Using the Biginelli Reaction\u201d \nJournal of Organic Chemistry 2006, 71, 7706\u20137714: PMCID: PMC 2535792\nB. L. Nilsson and L. E. Overman\n\n310. \t\u201cThe Total Synthesis of (\u2013)-Sarain A\u201d\nAngewandte Chemie, International Edition 2006, 45, 2912\u20132915\nN. K. Garg, S. Hiebert and L. E. Overman\n\n309. \t\u201cDiastereoselection in the Formation of Contiguous Quaternary Carbon Stereocenters by the Intramolecular Heck Reaction\u201d \nJournal of Organic Chemistry 2006, 71, 2600\u20132608: PMCID: PMC 2535793\nL. E. Overman and D. A. Watson\n\n308. \t\u201cDiastereoselection in the Formation of Spirocyclic Oxindoles by the Intramolecular Heck Reaction\u201d \nJournal of Organic Chemistry 2006, 71, 2587\u20132599: PMCID: PMC 2585599\nL. E. Overman and D. A. Watson\n\n307. \t\u201cScope and Facial Selectivity of the Prins\u2013Pinacol Synthesis of Attached Rings\u201d\nJournal of Organic Chemistry 2006, 71, 1581\u20131587\nL. E. Overman and E. J. Velthuisen\n\n306. \t\u201cEnantioselective Total Synthesis of the Proposed Structure of Batzelladine F and Definition of Its Structure\u201d\nJournal of the American Chemical Society 2006, 128, 2604\u20132608: PMCID: PMC 2535800\nF. Cohen and L. E. Overman \n\n305.\t\u201cEvolution of a Strategy for the Synthesis of Structurally Complex Batzelladine Alkaloids. Enantioselective Total Synthesis of the Proposed Structure of Batzelladine F and Structural Revision\u201d\nJournal of the American Chemical Society 2006, 128, 2594\u20132603: PMCID: PMC 2535801\nF. Cohen and L. E. Overman \n\n304. \t\u201cSynthesis of Dihydroquinolinones Angularly Fused to Tetrahydrobenzazepinone Rings\u201d\nHeterocycles 2006, 67, 585\u2013588\nL. E. Overman and E. A. Peterson\n\n303.\t\u201cUse of the Intramolecular Heck Reaction for Forming Congested Quaternary Carbon Stereocenters: Stereocontrolled Total Synthesis of (\u00b1)-Gelsemine\u201d\nJournal of the American Chemical Society 2005, 127, 18054\u201318065: PMCID: PMC 2597289\nA. Madin, C. J. O\u2019Donnell, T. Oh, D. W. Old, L. E. Overman and M. J. Sharp\n\n302.\t\u201cAza-Cope Rearrangement\u2013Mannich Cyclizations for the Formation of Complex Tricyclic Amines: Stereocontrolled Total Synthesis of (\u00b1)-Gelsemine\u201d\nJournal of the American Chemical Society 2005, 127, 18046\u201318053: PMCID: PMC 2570375\nW. G. Earley, E. J. Jacobsen, A. Madin, G. P. Meier, C. J. O\u2019Donnell, T. Oh, D. W. Old, L. E. Overman and M. J. Sharp\n\n301.\t\u201cTotal Synthesis of (\u2013)-Crambidine and Definition of the Relative Configuration of its Unique Tetracyclic Guanidinium Core\u201d\nJournal of the American Chemical Society 2005, 127, 15652\u201315658\nL. E. Overman and Y. H. Rhee\n\n300.\t\u201cSequential Catalytic Asymmetric Heck\u2013Iminium Ion Cyclization: Enantioselective Total Synthesis of the Strychnos Alkaloid Minfiensine\u201d\nJournal of the American Chemical Society 2005, 127, 10186\u201310187\nA. B. Dounay, L. E. Overman and A. D. Wrobleski\n\n299. \t\u201cAsymmetric Construction of Quaternary Carbon Stereocenters: High Stereoselection in Mukaiyama Aldol Reactions of 2-Siloxyindoles with Chiral Aldehydes\u201d\nOrganic Letters 2005, 7, 2795\u20132797\nS. Adhikari, S. Caille, M. Hanbauer, V. X. Ngo and L. E. Overman\n\n298. \t\u201cAsymmetric Rearrangement of Allylic Trichloroacetimidates: Preparation of (S)-2,2,2-Trichloro-N-(1-propylallyl)acetamide\u201d\nOrganic Syntheses 2005, 82, 134\u2013139\nC. E. Anderson, L. E. Overman and M. P. Watson\n\n297.\t\u201cCatalytic Asymmetric Intramolecular Aminopalladation: Improved Palladium(II) Catalysts\u201d\nJournal of Organic Chemistry 2005, 70, 2859\u20132861\nS. F. Kirsch and L. E. Overman\n\n296.\t\u201cCatalytic Asymmetric Synthesis of Chiral Allylic Esters\u201d\nJournal of the American Chemical Society 2005, 127, 2866\u20132867\nS. F. Kirsch and L. E. Overman\n\n295.\t\u201cToward an Enantioselective Total Synthesis of Sarain A: Construction of an Advanced Intermediate and Rearrangement of the Sarain A Core Under Mild Conditions\u201d\nOrganic Letters 2005, 7, 933\u2013936\nC. J. Douglas, S. Hiebert and L. E. Overman\n\n294.\t\u201cStereocontrolled Synthesis of Angularly-Substituted 1-Azabicyclic Rings by Cationic 2-Aza-Cope Rearrangements\u201d\nOrganic Letters 2005, 7, 913\u2013916\nZ. D. Aron and L. E. Overman\n\n293.\t\u201cTotal Synthesis and Properties of the Crambescidin Core Zwitterionic Acid and Crambescidin 359\u201d\nJournal of the American Chemical Society 2005, 127, 3380\u20133390\nZ. D. Aron and L. E. Overman\n\n292.\t\u201cSynthesis of tert-Leucine-Derived Cobalt Oxazoline Palladacycles. Reversal of Palladation Diastereoselectivity and Application to the Asymmetric Rearrangement of N-Aryl Trifluoroacetimidates\u201d\nOrganometallics 2005, 24, 77\u201381\nR. S. Prasad, C. E. Anderson, C. J. Richards and L. E. Overman\n\n291.\t\u201cThe Allylic Trihaloacetimidate Rearrangement\u201d\nOrganic Reactions 2005, 66, 1\u2013107\nN. E. Carpenter and L. E. Overman\n\n290. \t\u201cCatalytic Asymmetric Synthesis of Chiral Allylic Amines. Evaluation of Ferrocenyloxazoline Palladacycle Catalysts and Imidate Motifs\u201d\nJournal of Organic Chemistry 2005, 70, 648\u2013657\nC. E. Anderson, Y. Donde, C. J. Douglas and L. E. Overman\n\n289. \t\u201cEnantioselective Synthesis of Six-Membered Palladacycles Having Metal-Bound Stereogenic Carbons: Isolation and Reactivity of Palladacycles Containing Readily Accessible \uf062-Hydrogens\u201d\nJournal of the American Chemical Society 2004, 126, 16820\u201316833\nB. J. Burke and L. E. Overman\n\n288. \t\u201cStereocontrolled Construction of Either Stereoisomer of 12-Oxatricyclo[6.3.1.02,7]-dodecanes Using Prins-Pinacol Reactions\u201d\nOrganic Letters 2004, 6, 3853\u20133856\nL. E. Overman and E. J. Velthuisen\n\n287. \t\u201cMonomeric Cobalt Oxazoline Palladacycles (COP). Useful Catalysts for Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates\u201d\nJournal of Organic Chemistry 2004, 69, 8101\u20138104\nS. F. Kirsch, L. E. Overman and M. P. Watson\n\n286. \t\u201cGuanidine Alkaloid Analogs as Inhibitors of HIV-1 Nef Interactions with p53, Actin, and p56lck\u201d\nProceedings of the National Academy of Science USA 2004, 101, 14079\u201314084: PMCID: PMC 521092\nA. Olszewski, K. Sato, Z. D. Aron, F. Cohen, A. Harris, B. R. McDougall, W. E. Robinson, Jr., L. E. Overman and G. A. Weiss\n\n285. \t\u201cAsymmetric Synthesis of Pyrrolidinoindolines. Application for the Practical Total Synthesis of (\u2013)-Phenserine\u201d\nJournal of the American Chemical Society 2004, 126, 14043\u201314053\nA. Huang, J. J. Kodanko and L. E. Overman\n\n284. \t\u201cStudies Towards the Total Synthesis of Palau\u2019amine. Formation of 4,5-Dihydropyrrole-2-carboxylate Intermediates by Alkene\u2013Enamide Ring-Closing Metathesis\u201d\nTetrahedron 2004, 60, 9559\u20139568\nJ. D. Katz and L. E. Overman\n\n283. \t\u201cInhibition of HIV-1 Envelope-Mediated Fusion by Synthetic Batzelladine Analogs\u201d\nJournal of Natural Products 2004, 67, 1319\u20131324\nC. A. Bewley, S. Ray, F. Cohen, S. K. Collins and L. E. Overman\n\n282. \t\u201cSynthesis and Anticancer Activity of Side Chain Analogs of the Crambescidin Alkaloids\u201d\nBioorganic &amp; Medicinal Chemistry Letters 2004, 14, 3445\u20133449\nZ. D. Aron, H. Pietraszkiewicz, L. E. Overman, F. Valeriote and C. Cuevas\n\n281. \t\u201cContiguous Stereogenic Quaternary Carbons: A Daunting Challenge in Natural Products Synthesis\u201d\nProceedings of the National Academy of Science USA 2004, 101, 11943\u201311948: PMCID: PMC 514413\nE. A. Peterson and L. E. Overman\n\n280. \t\u201cEnantioselective Total Synthesis of (\u2013)-Dehydrobatzelladine C\u201d\nOrganic Letters 2004, 6, 1253\u20131255\nS. K. Collins, A. I. McDonald, L. E. Overman and Y. H. Rhee\n\n279. \t\u201cScope and Limitations of the Thionium Ion-Initiated Prins\u2013Pinacol Synthesis of Carbocycles\u201d\nSynlett 2004, 1387\u20131393\nB. J. Burke, A. D. Lebsack and L. E. Overman\n\n278. \t\u201cCatalytic Asymmetric Synthesis of All-Carbon Quaternary Stereocenters\u201d\nProceedings of the National Academy of Sciences USA 2004, 101, 5363\u20135367: PMCID: PMC 397386\nC. J. Douglas and L. E. Overman\n\n277. \t\u201cTotal Syntheses of (\u00b1)-Didehydrostemofoline (Asparagamine A) and (\u00b1)-Isodidehydrostemofoline\u201d\nJournal of the American Chemical Society 2003, 125, 15284\u201315285\nM. Br\u00fcggemann, A. I. McDonald, L. E. Overman, M. D. Rosen, L. Schwink and J. P. Scott\n\n276. \t\u201cThe Tethered Biginelli Condensation in Natural Product Synthesis\u201d\nChemical Communications 2004, 253\u2013265\nZ. D. Aron and L. E. Overman\n\n275.\t\u201cAssembling Polycyclic Bisguanidine Motifs Resembling Batzelladine Alkaloids by Double Tethered Biginelli Condensations\u201d\nOrganic Letters 2003, 5, 4485\u20134488\nF. Cohen, S, K. Collins and L. E. Overman\n\n274.\t\u201cPalladium\u201d\nChemical &amp; Engineering News 2003, September 8, p 116 \nL. E. Overman\n\n273.\t\u201cCatalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity\u201d\nJournal of the American Chemical Society 2003, 125, 12412\u201312413\nC. E. Anderson and L. E. Overman\n\n272.\t\u201cStrategic Use of Pinacol-Terminated Prins Cyclizations in Target-Oriented Total Synthesis\u201d\nJournal of Organic Chemistry 2003, 68, 7143\u20137157\nL. E. Overman and L. D. Pennington\n\n271.\t\u201cEnantioselective Synthesis of (\u2013)-Idiospermuline\u201d\nTetrahedron 2003, 59, 6905\u20136919\nL. E. Overman and E. A. Peterson\n\n270.\t\u201cCatalytic Asymmetric Rearrangement of Allylic N-Aryl Trifluoroacetimidates. A Useful Method for Transforming Prochiral Allylic Alcohols to Chiral Allylic Amines\u201d\nOrganic Letters 2003, 5, 1809\u20131812\nL. E. Overman, C. E.  Owen, M. M. Pavan, C. J. Richards\n\n269.\t\u201cEnantioselective Total Synthesis of Briarellins E and F. The First Total Syntheses of Briarellin Diterpenes\u201d\nJournal of the American Chemical Society 2003, 125, 6650\u20136652\nO. Corminboeuf, L. E. Overman and L. D. Pennington\n\n268.\t\u201cEnantioselective Total Syntheses of the Cyclotryptamine Alkaloids Hodgkinsine and Hodgkinsine B\u201d\nAngewandte Chemie, International Edition 2003, 42, 2528\u20132531\nJ. J. Kodanko and L. E. Overman\n\n267.\t\u201cEnantioselective Total Synthesis of the Cyclotryptamine Alkaloid Idiospermuline\u201d\nAngewandte Chemie, International Edition 2003, 42, 2525\u20132528\nL. E. Overman and E. A. Peterson\n\n266.\t\u201cTotal Synthesis of the Reputed Structure of Alcyonin and Reassignment of its Structure\u201d\nOrganic Letters 2003, 5, 1543\u20131546\nO. Corminboeuf, L. E. Overman and L. D. Pennington\n\n265.\t\u201cCatalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions\u201d\nJournal of the American Chemical Society 2003, 125, 6261\u20136271\nA. B. Dounay, K. Hatanaka, J. J. Kodanko, M. Oestreich, L. E. Overman, L. A. Pfeifer and M. M. Weiss\n\n264.\t\u201cThe Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis\u201d\nChemical Reviews 2003, 103, 2945\u20132963\nL. E. Overman and A. Dounay\n\n263.\t\u201cStereocontrolled Synthesis of Triazacyclopenta[cd]pentalenes by Intramolecular 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines\u201d\n Journal of Organic Chemistry 2002, 67, 7880\u20137883\nG. B\u00e9langer, F-T. Hong, L. E. Overman, B. N. Rogers, J. T. Tellew and W. C. Trenkle\n\n262.\t\u201cDiastereoselective Lithiation of (\uf0686-Arene)dicarbonyltriphenylphosphane Chromium(0) Oxazoline Complexes\u2014Direct Preparation of Enantiopure Complexes Having Planar Chiral Fragments of Either Configuration\u201d\nAngewandte Chemie, International Edition 2002, 41, 3884\u20133887\nL. E. Overman, C. E. Owen and G. G. Zipp\n\n261.\t\u201cNew Cationic Olefin Cyclization\u2013Pinacol Reactions. Ring-Expanding Cyclopentane Annulations that Directly Install Useful Functionality in the Cyclopentane Ring\u201d\nJournal of Organic Chemistry 2002, 67, 6421\u20136429\nL. E. Overman and J. P. Wolfe\n\n260.\t\u201cEnantioselective Total Synthesis of Quadrigemine C and Psycholeine\u201d\nJournal of the American Chemical Society 2002, 124, 9008\u20139009\nA. D. Lebsack, J. T. Link, L. E. Overman and B. A. Stearns\n\n259.\t\u201cStereoselective Synthesis of Carbocyclic Ring Systems by Pinacol-Terminated Prins Cyclizations\u201d\nTetrahedron 2002, 58, 6473\u20136483\nT. C. Gahman and L. E. Overman\n\n258.\t\u201cPreparation of \uf061-Sulfenyl Enones by Thermal Fragmentation of \uf062-Sulfenyl Enol Triflates\u201d\nOrganic Letters 2002, 4, 929\u2013931\nJ. Hynes, Jr., T. Nasser, L. E. Overman and D. A. Watson\n\n257.\t\u201cConstruction of Substituted Cyclohexanones by Reductive Cyclization of 7-Oxo-2,8-alkadienyl Esters\u201d\nOrganic Letters 2002, 4, 79\u201382\nT. M. Kamenecka, L. E. Overman and S. K. L. Sakata\n\n256.\t\u201cCatalytic Asymmetric Intramolecular Aminopalladation: Enantioselective Synthesis of Vinyl-Substituted 2-Oxazolidinones, 2-Imidazolidinones and 2-Pyrrolidinones\u201d\nJournal of the American Chemical Society 2002, 124, 12\u201313\nL. E. Overman and T. P. Remarchuk\n\n255.\t\u201cEnantioselective Total Synthesis of Batzelladine F: Structural Revision and Stereochemical Definition\u201d\nJournal of the American Chemical Society 2001, 123, 10782\u201310783\nF. Cohen and L. E. Overman\n\n254.\t\u201cEnantioselective Total Syntheses of Ditryptophenaline and ent-WIN 64821\u201d\nJournal of the American Chemical Society 2001, 123, 9465\u20139467\nL. E. Overman and D. V. Paone\n\n253.\t\u201cTotal Synthesis of Asperazine\u201d\nJournal of the American Chemical Society 2001, 123, 9468\u20139469: PMCID: PMC 1987397\nS. P. Govek and L. E. Overman\n\n252.\t\u201cA General Strategy for the Synthesis of Cladiellin Diterpenes. Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (a.k.a. Deacetoxyalcyonin Acetate), Cladiell-11-ene-3,6,7-triol, Sclerophytin A and the Initially Purported Structure of Sclerophytin A\u201d\nJournal of the American Chemical Society 2001, 123, 9033\u20139044\nD. W. C. MacMillan, L. E. Overman and L. D. Pennington\n\n251.\t\u201cEnantioselective Total Synthesis of Shahamin K\u201d\nJournal of the American Chemical Society 2001, 123, 4851\u20134852\nA. D. Lebsack, L. E. Overman and R. J. Valentegovich\n\n250.\t\u201cA New Asymmetric Synthesis of trans-Hydroisoquinolones\u201d\nOrganic Letters 2001, 3, 1229\u20131232\nA. Kamatani and L. E. Overman\n\n249.\t\u201cStereoselection in the Prins-Pinacol Synthesis of Acyltetrahydrofurans\u201d\nOrganic Letters 2001, 3, 1225\u20131228\nF. Cohen, D. W. C. MacMillan, L. E. Overman and A. Romero\n\n248.\t\u201cSynthesis of Polycyclic Guanidines by Cyclocondensation Reactions of N-Amidinyliminium Ions\u201d \nJournal of Organic Chemistry 2001, 66, 3167\u20133175\nL. E. Overman and J. P. Wolfe\n\n247.\t\u201cUse of Sequential Intramolecular Heck Cyclizations for Preparing Bicyclo[3.2.1]octane Fragments of Tetracyclic Stemodane and Stemarane Diterpenes\u201d\nSynlett 2001, 1009\u20131012\nS. J. O\u2019Connor, L. E. Overman and P. V. Rucker\n\n246.\t\u201cThwarting \u00df-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction\u201d\nAngewandte Chemie, International Edition 2001, 40, 1439\u20131442\nM. Oestreich, P. R. Dennison, J. J. Kodanko and L. E. Overman\n\n245.\t\u201cEnantioselective Synthesis of Authentic Schlerophytin A, Sclerophytin B, and Cladiell-11-ene-3,6,7-triol\u201d\nOrganic Letters 2001, 3, 135\u2013137\nF. Gallou, D. W. C. MacMillan, L. E. Overman, L. A. Paquette, L. D. Pennington and J. Yang\n244.\t\u201cCatalytic Asymmetric Synthesis of Quaternary Carbon Centers by Intramolecular Heck Reaction: Synthetic Developments and Mechanistic Studies\u201d\nJournal of Synthetic Organic Chemistry, JAPAN 2000, 58, 718\u2013727\nA. Ashimori and L. E. Overman\n\n243.\t\u201cTotal Synthesis of (\u2013)-Spirotryprostatin B and Three Stereoisomers\u201d\nAngewandte Chemie, International Edition 2000, 39, 4596\u20134599\nL. E. Overman and M. D. Rosen\n\n242.\t\u201cSynthesis of 3-Acyltetrahydrofurans from Formaldehyde Acetals of Allylic Diols\u201d\nTetrahedron Letters 2000, 41, 9431\u20139435\nC. M. Gasparski, P. M. Herrinton, L. E. Overman and J. P. Wolfe\n\n241.\t\u201cInvestigation of a Dialkylation Approach for Enantioselective Construction of Vicinal Quaternary Stereocenters\u201d\nOrganic Letters 2000, 2, 3241\u20133244\nS. B. Hoyt and L. E. Overman\n\n240.\t\u201cTotal Synthesis of the Supposed Structure of Sclerophytin A and an Improved Route to (\u2013)-7-Deacetoxyalcyonin Acetate\u201d\nOrganic Letters 2000, 2, 2683\u20132686\nL. E. Overman and L. D. Pennington\n\n239.\t\u201cA New Method for Stereocontrolled Synthesis of Substituted Tetrahydrothiophenes\u201d\nJournal of the American Chemical Society 2000, 122, 8672\u20138676\nA. M. Ponce and L. E. Overman\n\n238.\t\u201cEnantioselective Total Syntheses of 13,14,15-Isocrambescidin 800 and 13,14,15-Isocrambescidin 657\u201d\nJournal of the American Chemical Society 2000, 122, 4904\u20134914\nD. S. Coffey, L. E. Overman and F. Stappenbeck\n\n237.\t\u201cA Practical Entry to the Crambescidin Family of Guanidine Alkaloids. Enantioselective Total Syntheses of Ptilomycalin A, Crambescidin 657 and its Methyl Ester (Neofolitispate 2) and Crambescidin 800\u201d\nJournal of the American Chemical Society 2000, 122, 4893\u20134903\nD. S. Coffey, A. I. McDonald, L. E. Overman, M. H. Rabinowitz and P. A. Renhowe\n\n236.\t\u201cStereoselection in the Prins\u2013Pinacol Synthesis of 2,2-Disbustituted 4-Acyltetrahydrofurans. Enantioselective Synthesis of (\u2013)-Citreoviral\u201d \nOrganic Letters 2000, 2, 223\u2013226\nN. Hanaki, J. T. Link, D. W. C. MacMillan, L. E. Overman, W. G. Trankle and J. A. Wurster\n\n235.\t\u201cInvestigations Directed at the Total Synthesis of Ouabain. Lessons Learned from Degradation Studies\u201d\nHeterocycles 2000, 52, 1297\u20131314\nL. E. Overman and P. V. Rucker\n\n234.\t\u201cAsymmetric Total Synthesis of Batzelladine D\u201d\nOrganic Letters 1999, 1, 2169\u20132172\nF. Cohen, L. E. Overman and S. K. L. Sakata\n\n233.\t\u201cA New Strategy for Synthesis of Attached Rings\u201d\nCanadian Journal of Chemistry 2000, 78, 732\u2013738\nL. E. Overman and L. D. Pennington\n\n232.\t\u201cEnantioselective Total Synthesis of the Kinesin Motor Protein Inhibitor Adociasulfate 1\u201d\nJournal of the American Chemical Society 1999, 121, 12206\u201312207\nM. Bogenst\u00e4tter, A. Limberg, L. E. Overman and A. L. Tomasi\n\n231.\t\u201cEnantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and Meso-Chimonanthine\u201d\nAngewandte Chemie, International Edition 2000, 39, 213\u2013215\nL. E. Overman, J. F. Larrow, B. A. Stearns and J. M. Vance\n\n230.\t\u201cPreparation of (3S)-N-N-1,7-Bis-tert-butoxycarbonyl-3-hydroxyspermidine in High Enantiomeric Purity\u201d\nJournal of Organic Chemistry 1999, 64, 8741\u20138742\nD. S. Coffey, A. I. McDonald and L. E. Overman\n\n229.\t\u201cA Suzuki Coupling Method for Directly Introducing a Protected \uf062-Aminoethyl Group into Arenes and Alkenes. Convenient Synthesis of Phenethyl and Homoallylic Amines\u201d\nJournal of Organic Chemistry 1999, 64, 8743\u20138744\nA. Kamatani and L. E. Overman\n\n228.\t\u201cDirect Stereo- and Enantiocontrolled Synthesis of Vicinal Stereogenic Quaternary Carbon Centers. Total Synthesis of meso- and (\u2013)-Chimonanthine and (+)-Calycanthine\u201d\nJournal of the American Chemical Society 1999, 121, 7702\u20137703\nL. E. Overman, D. V. Paone and B. A. Stearns\n\n227.\t\u201cTotal Synthesis of (\u00b1)-Gelsemine\u201d\nAngewandte Chemie, International Edition 1999, 38, 2934\u20132936\nA. Madin, C. J. O'Donnell, T. Oh, D.W. Old, L. E. Overman and M. J. Sharp\n\n226.\t\u201cEnantioselective Total Synthesis of 13,14,15-Isocrambescidin 800\u201d\nJournal of the American Chemical Society 1999, 121, 6944\u20136945\nD. Coffey, A. I. McDonald, L. E. Overman and F. Stappenbeck\n\n225.\t\u201cEnantiodivergent Total Synthesis of (+)- and (\u2013)-Scopadulcic Acid A\u201d\nJournal of the American Chemical Society 1999, 121, 5467\u20135480\nM. E. Fox, C. Li, J. P. Marino, Jr. and L. E. Overman\n\n224.\t\u201cHigh Enantioselection in the Rearrangement of Allylic Imidates with Ferrocenyl Oxazoline Catalysts\u201d\nJournal of the American Chemical Society 1999, 121, 2933\u20132934.\nY. Donde and L. E. Overman\n\n223.\t\u201cPalladium Catalyzed Enantioselective Rearrangement of Allylic Imidates to Allylic Amides\u201d\nJournal of Organometallic Chemistry 1999, 576\/1-2, 290\u2013299\nT. K. Hollis and L. E. Overman\n\n222.\t\u201cAsymmetric Intramolecular Heck Reactions\u201d\nCatalytic Asymmetric Synthesis, Second Edition; I. Ojima, Ed., Wiley: New York; 2000, Chapter 8G, pp 675\u2013697\nY. Donde and L. E. Overman\n\n221.\t\u201cStudies Towards a Total Synthesis of Sarains A\u2013C. Stereospecific Condensation of \uf061,\uf062-Unsaturated Esters With the Phenyl Oxazoline Derivative of Threonine\u201d\nTetrahedron Letters 1999, 40, 1273\u20131276\nS. Jaroch, R. T. Matsuoka and L. E. Overman\n\n220.\t\u201cStereocontrolled Synthesis of Trisubstituted Tetrahydropyrans\u201d\nJournal of the American Chemical Society 1999, 121, 1092\u20131093\nM. J. Cloninger and L. E. Overman\n\n219.\t\u201cTuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis or trans 1-Oxo- and 1-Iminohexahydropyrrolo-[1,2-c]pyrimidines\u201d\nJournal of Organic Chemistry 1999, 64, 1520\u20131528\nA. I. McDonald and L. E. Overman\n\n218.\t\u201cApplication of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B\u201d \nJournal of Organic Chemistry 1999, 64, 1512\u20131519\nA. S. Franklin, S. K. Ly, G. H. Mackin, L. E. Overman and A. J. Shaka\n\n217.\t\u201cTotal Synthesis of (+)-Aloperine. Use of a Nitrogen-Bound Silicon Tether in an Intramolecular Diels\u2013Alder Reaction\u201d\nJournal of the American Chemical Society 1999, 121, 700\u2013709\nA. D. Brosius, L. E. Overman and L. Schwink\n\n216.\t\u201cAsymmetric Construction of the Diazatricyclic Core of the Marine Alkaloids Sarains A-C\u201d\nJournal of Organic Chemistry 1998, 63, 8096\u20138097\nR. Downham, F. W. Ng and L. E Overman\n\n215.\t\u201cPlanar-Chiral Cyclopalladated Ferrocenyl Amines and Imines as Enantioselective Catalysts for Allylic Imidate Rearrangements\u201d\nTetrahedron: Asymmetry 1998, 9, 3213\u20133222\nF. Cohen and L.E. Overman\n\n214.\t\u201cForming Cyclics with the Intramolecular Heck Reaction\u201d\nCHEMTECH 1998, 28(8), August, 19\u201326\nJ. T. Link and L. E. Overman\n\n213.\t\u201cStereoselectivities of Nucleophilic Additions to Cycloheptanones. Experimental and Theoretical Studies and General Purpose Force Field for the Prediction of Nucleophilic Addition Stereoselectivities\u201d\nJournal of Organic Chemistry 1998, 63, 3196\u20133203\nK. Ando, K. R. Condroski, K. N. Houk, Y.-D. Wu, S. K. Ly and L. E. Overman\n\n212.\t\u201cCatalytic Asymmetric Synthesis of Either Enantiomer of the Calabar Alkaloids Physostigmine and Physovenine\u201d\nJournal of the American Chemical Society 1998, 120, 6500\u20136503\nT. Matsuura, L. E. Overman and D. J. Poon\n\n211.\t\u201cCatalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of (Z)-\uf061,\uf062-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Intermediates\u201d\nJournal of the American Chemical Society 1998, 120, 6488\u20136499\nA. Ashimori, B. Bachand, M. A. Calter, S. P. Govek, L. E. Overman and D. J. Poon\n\n210.\t\u201cCatalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Investigations of Intramolecular Heck Reactions of (E)-\uf061,\uf062-Unsaturated 2-Haloanilides and Analogs to Form Enantioenriched Spirocyclic Products\u201d\nJournal of the American Chemical Society 1998, 120, 6477\u20136487\nA. Ashimori, B. Bachand, L. E. Overman and D. J. Poon\n\n209.\t\u201cIntramolecular Heck Cyclization of \uf061-Sulfenyl Enol Triflates. Asymmetric Synthesis of a Pentacyclic Cardenolide Precursor Having Functionality at C-11\u201d\nTetrahedron Letters 1998, 39, 4647\u20134650\nJ. Hynes, Jr., L. E. Overman, T. Nasser and P. V. Rucker\n\n208.\t\u201cEnantioselective Synthesis of Cardenolide Precursors Using an Intramolecular Heck Reaction\u201d\nTetrahedron Letters 1998, 39, 4643\u20134646\nL. E. Overman and P. V. Rucker\n\n207.\t\u201cEnantioselective Total Synthesis of Hispidospermidin\u201d\nJournal of the American Chemical Society 1998, 120, 4039\u20134040\nL. E. Overman and A. Tomasi\n\n206.\t\u201cSynthesis of a Phenolic Analog of Aphidicolin. Diminished Stereoselection in Intramolecular 6-Exo Heck Reactions of Substrates Having a Hydrocarbon Tether\u201d\nSynlett 1997, 1469\u20131471\nM. M. Abelman, N. Kado, L. E. Overman and A. K. Sarkar\n\n205.\t\u201cHalide-Terminated N-Acyliminium Ion\u2013Alkyne Cyclizations: A New Construction of Carbacephem Antibiotics\u201d \nJournal of Organic Chemistry 1997, 62, 9210\u20139216\nE. Metais, L. E. Overman, M. I. Rodriguez and B. A. Stearns\n\n204.\t\u201cPyridinomorphinans: Asymmetric Synthesis of Either Enantiomer and Opioid Receptor Binding Selectivity\u201d\nTetrahedron Letters 1997, 38, 8439\u20138442\nC. Y. Hong, L. E. Overman and A. Romero\n\n203.\t\u201cAn Unexpected Product Arising from Metal Alkylidene Mediated Ring-Closing Diene Metathesis\u201d\nTetrahedron Letters 1997, 38, 8635\u20138638\nD. Joe and L. E. Overman\n\n202.\t\u201cCyclopalladated Ferrocenyl Amines as Enantioselective Catalysts for the Rearrangement of Allylic Imidates to Allylic Amides\u201d\nTetrahedron Letters 1997, 38, 8837\u20138840\nT. K. Hollis and L. E. Overman\n\n201.\t\u201cTotal Synthesis of (\u00b1)-Scopadulcic Acid B\u201d\nJournal of the American Chemical Society 1997, 119, 12031\u201312040\nL. E. Overman, D. J. Ricca and V. D. Tran\n\n200.\t\u201cStereocontrolled Synthesis of the Tetracyclic Core of the Bisguanidine Alkaloids Palau'amine and Styloguanidine\u201d\nJournal of the American Chemical Society 1997, 119, 7159\u20137160\nL. E. Overman, B. Rogers, J. Tellew and W. C. Trenkle\n\n199.\t\u201cRing-Enlarging Cyclohexane Annulations\u201d\nJournal of Organic Chemistry 1997, 62, 6379\u20136387\nS. Ando, K. P. Minor and L. E. Overman\n\n198.\t\u201cPrins-Pinacol Spiroannulations\u201d\nTetrahedron 1997, 53, 8927\u20138940\nK. P. Minor and L. E. Overman\n\n197. \t\u201cControlling Stereoselection in Aza-Cope\u2013Mannich Reactions\u201d\nIsrael Journal of Chemistry 1997, 37, 23\u201330\nL. E. Overman and W. C. Trenkle\n\n196.\t\u201cTotal Synthesis of (+)-Isolaurepinnacin. Use of Acetal\u2013Alkene Cyclizations to Prepare Highly Functionalized Seven-Membered Cyclic Ethers\u201d\nJournal of the American Chemical Society 1997, 119, 2446\u20132452\nD. Berger, L. E. Overman and P. A. Renhowe\n\n195.\t\u201cAllylic Transposition of Alcohol and Amine Functionality by Thermal- or Palladium(II)- Catalyzed Rearrangements of Allylic N-Benzoylbenzimidates\u201d\nJournal of Organic Chemistry 1997, 62, 2288\u20132291\nL. E. Overman and G. G. Zipp\n\n194.\t\u201cFirst Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allyl Amides\u201d\nJournal of Organic Chemistry 1997, 62, 1449\u20131456\nM. Calter, T. K. Hollis, L. E. Overman, J. Ziller and G. G. Zipp\n\n193.\t\u201cIntramolecular Heck Reactions in Natural Products Chemistry\u201d \nMetal-catalyzed Cross-coupling Reactions, Diederich, F.; Stang, P. J., Eds.; VCH: Weinheim; 1998, Chapter 6, pp 231\u2013269\nJ. T. Link and L. E. Overman \n\n192.\t\u201cAloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration\u201d\nJournal of Organic Chemistry 1997, 62, 440\u2013441\nA. D. Brosius and L. E. Overman\n\n191.\t\u201cAsymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights\u201d\nAngewandte Chemie, International Edition in English 1997, 36, 518\u2013521\nL. E. Overman and D. J. Poon\n\n190.\t\u201cSynthesis of 2-Azatricyclo[5.2.1.0]decanes and 2,5-Diazatricyclo[5.2.1]decanes by Intramolecular Azomethine Ylide Cycloadditions\u201d\nJournal of Organic Chemistry 1996, 61, 8338\u20138340\nL. E. Overman and J. T. Tellew\n\n189.\t\u201cA Strategy for Total Synthesis of Complex Cardenolides\u201d\nJournal of Organic Chemistry 1996, 61, 6760\u20136761\nW. Deng, M. S. Jensen, L. E. Overman, P. V. Rucker and J.-P. Vionnet\n\n188.\t\u201cDesign and In Vitro Pharmacology of a Selective \uf067-Aminobutryic AcidC Receptor Antagonist\u201d\nMolecular Pharmacology 1996, 50, 1024\u20131030\nR. M. Woodward, D. Ragozzino, Y. Murata, F. Eusebi, L. E. Overman and R. Miledi\n\n187.\t\u201cThe First Selective Antagonist of the GABAc Receptor\u201d\nBioorganic &amp; Medicinal Chemistry Letters 1996, 6, 2073\u20132076\nY. Murata, R. M. Woodward, R. Miledi and L. E. Overman\n\n186.\t\u201cStereocontrolled Total Syntheses of meso-Chimonanthine and meso-Calycanthine via a Novel Samarium Mediated Reductive Dialkylation\u201d\nJournal of the American Chemical Society 1996, 118, 8166\u20138167\nJ. T. Link and L. E. Overman\n\n185.\t\u201cEnantioselective Total Synthesis of (+)-Allopumiliotoxins 267A, 323B and 339A. Application of Iodide-Promoted Iminium Ion\u2013Alkyne Cyclizations for Forming Allopumiliotoxin A Alkaloids\u201d\nJournal of the American Chemical Society 1996, 118, 9073\u20139082\n C. Caderas, R. Lett, L. E. Overman, M. H. Rabinowitz, L. A. Robinson, M. J. Sharp and J. Zablocki\n\n184.\t\u201cEfficient Total Syntheses of Pumiliotoxins A and B. Applications of Iodide-Promoted Iminium Ion\u2013Alkyne Cyclizations in Alkaloid Construction\u201d\nJournal of the American Chemical Society 1996, 118, 9062\u20139072\nN. Lin, L. E. Overman, M. H. Rabinowitz, L. A. Robinson, M. J. Sharp and J. Zablocki\n\n183.\t\u201cAprotic Chloride and Bromide-Promoted Alkyne-Iminium Ion Cyclizations\u201d\nHeterocycles 1996, 42, 549\u2013553\nY. Murata and L. E. Overman\n\n182.\t\u201cTotal Syntheses of Pumiliotoxin A and Allopumiliotoxin Alkaloids. Interplay of Pharmacologically Active Natural Products and New Synthetic Methods and Strategies\u201d\nChemical Reviews 1996, 96, 505\u2013522\nA. Franklin and L. E. Overman\n\n181.\t\u201cNew Reactions for Forming Heterocycles and Their Use in Natural Products Synthesis\u201d\nAldrichimica Acta 1995, 28, 107\u2013120\nL. E. Overman\n\n180.\t\u201cSilyl Ethers of Cycloheptene \u2013 Novel Proton Pump Inhibitors Obtained During the Total Synthesis of the Scopadulcic Acids\u201d\nBioorganic &amp; Medicinal Chemistry Letters 1995, 5, 2943\u20132946\nT. Hayashi, T. Sugimoto, N. Takewaki, N. Takeguchi, V. Tran, S. O'Connor, P. Rucker and L. E. Overman\n\n179.\t\u201cEnantioselective Total Synthesis of (\u2013)-7-Deacetoxyalcyonin Acetate. The First Synthesis of a Eunicellin Diterpene\u201d\nJournal of the American Chemical Society 1995, 117, 10391\u201310392\nD. W. C. MacMillan and L. E. Overman\n\n178.\t\u201cMannich Biscyclizations. Total Synthesis of (\u2013)-Ajmalicine\u201d\nJournal of the American Chemical Society 1995, 117, 9139\u20139150\nM. L\u00f6gers, L. E. Overman and G. Welmaker\n\n177.\t\u201cTotal Synthesis of (+)-Laurencin. Use of Acetal\u2013Vinylsulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers\u201d\nJournal of the American Chemical Society 1995, 117, 5958\u20135966\nM. Bratz, W. H. Bullock, L. E. Overman and T. Takemoto\n\n176.\t\u201cThe Enantiomer of Strychnine is a Weak Antagonist of the Inhibitory Glycine Receptor\u201d\nBioorganic &amp; Medicinal Chemistry Letters 1995, 5, 749\u2013752\nS. D. Knight, R. Miledi, Q.-T. Nguyen, L. E. Overman and G. Pairaudeau\n\n175.\t\u201cAsymmetric Total Syntheses of (\u2013)- and (+)-Strychnine and the Wieland\u2013Gumlich Aldehyde\u201d\nJournal of the American Chemical Society 1995, 117, 5776\u20135788\nS. D. Knight, L. E. Overman and G. Pairaudeau\n\n174.\t\u201cEnantioselective Total Synthesis of (\u2013)-Ptilomycalin A\u201d\nJournal of the American Chemical Society 1995, 117, 2657\u20132658\nL. E. Overman, M. H. Rabinowitz and P. A. Renhowe\n\n173.\t\u201cEnantioselective Total Synthesis of Either Enantiomer of the Antifungal Antibiotic Preussin (L-657,398) from (S)-Phenylalanine\u201d\nJournal of the American Chemical Society 1994, 116, 11241\u201311250\nW. Deng and L. E. Overman\n\n172.\t\u201cPreparation of Spirocyclic Polyethers by Intramolecular Heck Reactions\u201d\nHeterocycles 1994, 39, 497\u2013501\nS. D. Knight and L. E. Overman\n\n171.\t\u201cRegioselective Opening of Terminal Epoxides with 2-(Trialkylsilyl)allyl Organometallic Reagents\u201d\nJournal of Organic Chemistry 1994, 59, 4138\u20134142\nL. E. Overman and P. A. Renhowe\n\n170.\t\u201cAn Enantioselective Approach to the Synthesis of Manzamine A\u201d\nTetrahedron Letters 1994, 35, 4279\u20134282\nT. M. Kamenecka and L. E. Overman\n\n169.\t\u201cPreparation of Opium Alkaloids by Palladium Catalyzed Bis-Cyclizations. Formal Total Synthesis of Morphine\u201d\nTetrahedron Letters 1994, 35, 3453\u20133456\nC. Y. Hong and L. E. Overman\n\n168.\t\u201cA Convenient Method for the Preparation of 3-Substituted Glutarate Diesters\u201d\nJournal of Organic Chemistry 1994, 59, 1946\nG. Leotta, III, L. E. Overman and G. S. Welmaker\n\n167.\t\u201cApplication of Intramolecular Heck Reactions for Forming Congested Quaternary Carbon Centers in Complex Molecule Total Synthesis\u201d\nPure and Applied Chemistry 1994, 66, 1423\u20131430\nL. E. Overman\n\n166.\t\u201cApplication of Intramolecular Heck Reactions to the Preparation of Steroid and Terpene Intermediates Having cis A-B Ring Fusions. Model Studies for the Total Synthesis of Complex Cardenolides\u201d\nTetrahedron (Symposium in Print \u201cPalladium in Organic Synthesis\u201d) 1994, 50, 347\u2013358\nS. Laschat, F. Narjes and L. E. Overman\n\n165.\t\u201cAsymmetric Synthesis of Either Enantiomer of Opium Alkaloids and Morphinans. Total Synthesis of (\u2013)- and (+)-Dihydrocodeinone and (\u2013)- and (+)-Morphine\u201d\nJournal of the American Chemical Society 1993, 115, 11028\u201311029\nC. Y. Hong, N. Kado and L. E. Overman \n\n164.\t\u201cSimple Method for Controlling Stereoselection in Mannich Cyclization Reactions of Aldehydes\u201d\nJournal of Organic Chemistry 1993, 58, 6947\u20136948\nD. A. Heerding, C. Y. Hong, N. Kado, G. C. Look and L. E. Overman\n\n163.\t\u201cEnantioselective Total Synthesis of (\u2013)-Strychnine\u201d\nJournal of the American Chemical Society 1993, 115, 9293\u20139294\nS. D. Knight, L. E. Overman and G. Pairaudeau\n\n162.\t\u201cTotal Synthesis of (\u00b1)-Scopadulcic Acid A. An Illustration of the Utility of Palladium Catalyzed Polyene Cyclizations\u201d\nJournal of Organic Chemistry 1993, 58, 5304\u20135306\nD. J. Kucera, S. J. O'Connor and L. E. Overman\n\n161.\t\u201cCatalytic Asymmetric Synthesis of Either Enantiomer of Physostigmine. Formation of Quaternary Carbon Centers with High Enantioselection by Intramolecular Heck Reactions of (Z)-2-Butenanilides\u201d\nJournal of Organic Chemistry 1993, 58, 6949\u20136951\nA. Ashimori, T. Matsuura, L. E. Overman and D. J. Poon\n\n160.\t\u201cCharge as a Key Component in the Design of New Cyclization Reactions\u201d\nAbstract, 33rd National Organic Symposium 1993, 96\u2013116\nL. E. Overman\n\n159.\t\u201cEnantioselective Total Synthesis of (\u2013)-Isolaurepinnacin\u201d\nJournal of the American Chemical Society 1993, 115, 9305\u20139306\nD. Berger, L. E. Overman and P. A. Renhowe\n\n158.\t\u201cFirst Total Synthesis of Scopadulcic Acid B. An Illustration of the Utility of Palladium- Catalyzed Polyene Cyclizations\u201d\nOrganometallic Reagents in Organic Synthesis, Academic Press: New York, 1994, pp 117\u2013128\nL. E. Overman, M. M. Abelman, D. J. Ricca and V. D. Tran\n\n157.\t\u201cPreparation of Enantioenriched Tetrahydropyridines by Iminium Ion\u2013Vinylsilane Cyclizations\u201d\nTetrahedron Letters 1993, 34, 5243\u20135246\nP. Castro, L. E. Overman, X. Zhang and P. S. Mariano\n\n156.\t\u201cIntroduction of the 2-Phenylthioethyl, 2-Phenylsulfinylethyl, and 2,2-Di(phenylthio)ethyl Substituents into Cyclic Ketones\u201d\nJournal of Organic Chemistry 1993, 58, 6476\u20136479\nJ. Montgomery and L. E. Overman\n\n155.\t\u201cStudies Towards the Total Synthesis of (+)-Ptilomycalin A. Use of a Tethered Biginelli Condensation for the Preparation of an Advanced Tricyclic Intermediate\u201d\nJournal of Organic Chemistry 1993, 58, 3235\u20133237\nL. E. Overman and M. H. Rabinowitz\n\n154.\t\u201cTotal Synthesis of Amaryllidaceae Alkaloids of the 5,11-Methanomorphanthride Type. Efficient Total Syntheses of (\u2013)-Pancracine and (\u00b1)-Pancracine\u201d\nJournal of Organic Chemistry 1993, 58, 4662\u20134672\nL. E. Overman and J. Shim\n\n153.\t\u201cFirst Total Synthesis of Lycopodium Alkaloids of the Magellenane Group. Enantioselective Total Syntheses of (\u2013)-Magellanine and (+)-Magellaninone\u201d\nJournal of the American Chemical Society 1993, 115, 2992\u20132993\nG. C. Hirst, T. O. Johnson and L. E. Overman\n\n152.\t\u201cThe Aza-Cope-Mannich Approach to Strychnos Alkaloids. Short Stereocontrolled Total Syntheses of (\u00b1)-Dehydrotubifoline and (\u00b1)-Akuammicine\u201d\nJournal of the American Chemical Society 1993, 115, 3966\u20133976\nS. R. Angle, J. M. Fevig, S. D. Knight, R. M. Marquis, Jr. and L. E. Overman\n\n151.\t\u201cGeneral Approach to Halogenated Tetrahydrofuran Natural Products from Red Algae of the Genus Laurencia. The Total Synthesis of (\u00b1)-Kumausallene and (\u00b1)-epi-Kumausallene\u201d\nJournal of Organic Chemistry 1993, 58, 2468\u20132477\nT. A. Grese, K. D. Hutchinson and L. E. Overman\n\n150.\t\u201cTotal Synthesis of the Amaryllidaceae Alkaloid (\u00b1)-Epielwesine. The Importance of Vinylsilane Stereochemistry in Iminium Ion\u2013Vinylsilane Cyclizations\u201d\nHeterocycles 1993, 35, 205\u2013225\nR. M. Burk and L. E. Overman\n\n149.\t\u201cFirst Total Synthesis of Scopadulcic Acid B\u201d\nJournal of the American Chemical Society 1993, 115, 2042\u20132044\nL. E. Overman, D. J. Ricca and V. D. Tran\n\n148.\t\u201cPreparation of Unsaturated Seven and Eight Membered Nitrogen Heterocycles by Iodide-Promoted Alkyne\u2013Iminium Ion Cyclizations\u201d\nSynlett 1992, 995\u2013996\nI. M. Rodriguez-Campos and L. E. Overman\n\n147.\t\u201cPreparation of Seven-Membered Cyclic Ethers Containing Halogenated Side Chains by Acetal-Alkene Cyclizations\u201d\nSynlett 1992, 811\u2013812\nD. Berger and L. E. Overman\n\n146.\t\u201cPalladium-Catalyzed Polyene Cyclizations\u201d\nPure and Applied Chemistry 1992, 64, 1813\u20131819\nL. E. Overman, M. M. Abelman, D. J. Kucera, D. J. Ricca and V. D. Tran \n\n145.\t\u201cControlling Stereoselection in Intramolecular Heck Reactions by Tailoring the Palladium Catalyst\u201d\nTetrahedron Letters 1992, 33, 4859\u20134862\nA. Madin and L. E. Overman\n\n144.\t\u201cIodide-Promoted Aldiminium Ion\u2013Alkyne Cyclizations. A Convenient Synthesis of Substituted Tetrahydropyridines and 3-Alkyldenepiperidines\u201d\nTetrahedron Letters 1992, 33, 4103\u20134106\nL. E. Overman and A. K. Sarkar\n\n143.\t\u201cCatalytic Asymmetric Synthesis of Quaternary Carbon Centers. Palladium Catalyzed Formation of Either Enantiomer of Spirooxindoles and Related Spirocyclics Using a Single Enantiomer of a Chiral Diphosphine Ligand\u201d\nJournal of Organic Chemistry 1992, 57, 4571\u20134572\nA. Ashimori and L. E. Overman\n\n142.\t\u201cCharge as a Key Component in Reaction Design. The Invention of Cationic Cyclization Reactions of Importance in Synthesis\u201d\nAccounts of Chemical Research 1992, 25, 352\u2013359\nL. E. Overman\n\n141.\t\u201cReaction of Na2Fe(CO)4 with an Unsaturated Aziridinium Ion. Unprecedented Rearrangement of an Alkyltetracarbonylferrate Intermediate\u201d\nJournal of Organic Chemistry 1992, 57, 1035\u20131038\nL. E. Overman and M. J. Sharp\n\n140.\t\u201cSynthesis of 3-Acyl-3-Alkyloxindoles\u201d\nTetrahedron Letters 1991, 32, 6993\u20136996\nC. J. Flann, L. E. Overman and A. Sarkar\n\n139.\t\u201cFirst Total Synthesis of (+)-Allopumiliotoxin 339A. A Practical Entry to Dendrobatid Alkaloids of the Allopumiliotoxin Class\u201d\nJournal of the American Chemical Society 1992, 114, 368\u2013369\nL. E. Overman, L. A. Robinson and J. Zablocki\n\n138.\t\u201cRing-Enlarging Cyclopentene Annulations\u201d\nTetrahedron Letters 1991, 32, 7361\u20137364\nT. Johnson and L. E. Overman\n\n137.\t\u201cFirst Total Synthesis of Amaryllidaceae Alkaloids of the 5,11-Methanomorphanthridine Type. An Efficient Total Synthesis of (\u00b1)-Pancracine\u201d\nJournal of Organic Chemistry 1991, 56, 5005\u20135007\nL. E. Overman and J. Shim\n\n136.\t\u201cNew Approach to Strychnos Alkaloids. Stereocontrolled Total Synthesis of (\u00b1)-Dehydrotubifoline\u201d\nJournal of the American Chemical Society 1991, 113, 5085\u20135086\nJ. M. Fevig, R. M. Marquis, Jr. and L. E. Overman\n\n135.\t\u201cThe First Enantioselective Total Syntheses of the Allopumiliotoxin A Alkaloids 267A and 339B\u201d\nJournal of Organic Chemistry 1992, 57, 1179\u20131190\nS. W. Goldstein, L. E. Overman, and M. H. Rabinowitz\n\n134.\t\u201c3(S)-((tert-Butyldiphenylsilyl)oxy)-2-butanone (2-Butanone, (S)-3-[[1,1-dimethylethyl)diphenylsilyl]]oxy]\u201d\nOrganic Syntheses 1992, 71, 56\u201362; Collective Volume IX, p 139\u2013142\nL. E. Overman and G. M. Rishton\n\n133.\t\u201cStereocontrolled Preparation of 3-Acyltetrahydrofurans from Acid-Promoted Rearrangements of Allylic Ketals: (2S,3S)-3-Acetyl-8-carboethoxy-2,3-dimethyl-1-oxa-8-azaspiro[4.5]decane\u201d\nOrganic Syntheses 1992, 71, 63\u201371; Collective Volume IX, pp 4\u20139\nL. E. Overman and G. M. Rishton\n\n132.\t\u201cGeneral Approach to Halogenated Tetrahydrofuran Natural Products from Red Algae of the Genus Laurencia. Total Synthesis of (\u00b1)-trans-Kumausyne and Demonstration of an Asymmetric Synthesis Strategy\u201d\nJournal of the American Chemical Society 1991, 113, 5378\u20135384\nM. J. Brown, T. Harrison and L. E. Overman\n\n131.\t\u201cStereocontrolled Preparation of Tetrahydrofurans from Acid-Promoted Rearrangements of Allylic Acetals\u201d\nJournal of the American Chemical Society 1991, 113, 5354\u20135365\nM. H. Hopkins, L. E. Overman and G. M. Rishton\n\n130.\t\u201cAcid-Promoted Reaction of Cyclic Allylic Diols with Carbonyl Compounds. Stereoselective Ring-Enlarging Tetrahydrofuran Annulations\u201d\nJournal of the American Chemical Society 1991, 113, 5365\u20135378\nM. J. Brown, T. Harrison, P. M. Herrinton, M. H. Hopkins, K. D. Hutchinson, P. Mishra and L. E. Overman \n\n129.\t\u201cUse of Aza-Cope Rearrangement\u2013Mannich Cyclization Reactions to Achieve a General Entry to Melodinus and Aspidosperma Alkaloids. Stereocontrolled Total Syntheses of (\u00b1)-Deoxoapodine, (\u00b1)-Meloscine, and (\u00b1)-Epimeloscine and a Formal Synthesis of 1-Acetylaspidoalbidine\u201d\nJournal of the American Chemical Society 1991, 113, 2598\u20132610\nL. E. Overman, G. M. Robertson and A. J. Robichaud\n\n128.\t\u201cPreparation of 3-Amino-4-(hydroxymethyl)azetidin-2-ones from the Reaction of Glycine Enolates with Imines of a Glycoaldehyde\u201d\nJournal of Organic Chemistry 1991, 56, 1933\u20131936\nM. J. Brown and L. E. Overman\n\n127.\t\u201cConstruction of Quaternary Carbon Centers by Palladium-Catalyzed Intramolecular Alkene Insertions. Total Synthesis of the Amaryllidaceae Alkaloids (\uf0b1)-Tazettine and (\uf0b1)-6a-Epipretazettine\u201d\nJournal of the American Chemical Society 1990, 112, 6959\u20136964\nM. M. Abelman, L. E. Overman and V. D. Tran\n\n126.\t\u201cFormation of \uf0444-Oxocenes from Lewis Acid-Promoted Cyclization of 5-Hexenyl Acetals. Evidence for a Concerted Ene Cyclization Mechanism\u201d\nJournal of the American Chemical Society 1990, 112, 4399\u20134403\nT . A. Blumenkopf, G. C. Look and L. E. Overman\n\n125.\t\u201cPreparation of Eight-Membered Cyclic Ethers by Lewis Acid Promoted Acetal\u2013Alkene Cyclizations\u201d\nJournal of the American Chemical Society 1990, 112, 4386\u20134399\nT. A. Blumenkopf, M. Bratz, A. Casta\u00f1eda, G. C. Look, L. E. Overman, D. Rodriguez and A. S. Thompson\n\n124.\t\u201cMechanism of the Palladium Dichloride Catalyzed Cope Rearrangement of Acyclic Dienes. A Substituent Effect Study\u201d\nJournal of the American Chemical Society 1990, 112, 3945\u20133949\nL. E. Overman and A. F. Renaldo\n\n123.\t\u201cPalladium-Catalyzed Polyene Cyclizations of Trienyl Triflates\u201d\nJournal of Organic Chemistry 1989, 54, 5846\u20135848\nN. E. Carpenter, D. J. Kucera and L. E. Overman\n\n122.\t\u201cPumiliotoxin Alkaloids: A New Class of Sodium Channel Agents\u201d\nBiochemical Pharmacology 1990, 40, 315\u2013326\nJ. W. Daly, F. Gusovsky, E. T. McNeal, S. Secunda, M. Bell, C. R. Creveling, Y. Nishizawa, L. E. Overman, M. J. Sharp and D. P. Rossignol\n\n121.\t\u201cIntramolecular (N-Acyloxy)iminium Ion-Alkyne Cycloadditions. A New Route to Bicyclic \uf061-Amino Ketones\u201d\nJournal of Organic Chemistry 1990, 55, 1447\u20131459\nM. J. Fisher and L. E. Overman\n\n120.\t\u201cIntramolecular Mannich and Related Reactions\u201d\nComprehensive Organic Synthesis 1991, 2, 1007\u20131046\nL. E. Overman and D. J. Ricca\n\n119.\t\u201c(E)-1-Benzyl-3-(1-iodoethylidene)piperidine. Nucleophile-Promoted Alkyne Iminium Ion Cyclizations\u201d\nOrganic Syntheses 1991, 70, 111\u2013119; Collective Volume IX, pp 46\u201351\nH. J. Arnold, L. E. Overman, M. J. Sharp and M. C. Witschel\n\n118.\t\u201cTotal Synthesis of (\uf0b1)-Meloscine and (\uf0b1)-Epimeloscine\u201d\nJournal of Organic Chemistry 1989, 54, 1236\u20131238\nL. E. Overman, G. M. Robertson and A. J. Robichaud\n\n117.\t\u201cStereocontrolled Construction of Carbocyclic Rings by Sequential Cationic Cyclization\u2013Pinacol Rearrangements\u201d\nJournal of the American Chemical Society 1989, 111, 1514\u20131515\nG. C. Hirst, P. N. Howard and L. E. Overman\n\n116.\t\u201cCationic Cyclization Reactions Terminated by Pinacol Rearrangements\u201d\nSelectivities in Lewis Acid-Promoted Reactions, NATO ASSI Series, Kluwer Academic: Dordrecht, Netherlands, Vol. 289; D. Schinzer, Ed.; 1989, pp 1\u201320 \nL. E. Overman\n\n115.\t\u201cPreparation of Seven-Membered Ring Cyclic Ethers and 3-Alkylidene-Tetrahydropyrans from the Cyclization of Oxonium Cations Derived from Unsubstituted and Silicon-Containing 4-Alken-1-ols\u201d\nJournal of Organic Chemistry 1989, 54, 5695\u20135707\nA. Casta\u00f1eda, D. J. Kucera and L. E. Overman\n\n114.\t\u201cPreparation of Functionalized Hydroindol-3-ols via Tandem Aza-Cope Rearrangement\u2013Mannich Cyclizations. Formal Total Synthesis of (+)-6a-Epipretazettine and Related Alkaloids\u201d\nTetrahedron Letters 1989, 30, 647\u2013650\nL. E. Overman and H. Wild\n\n113.\t\u201cSynthesis of Allopumiliotoxin A Alkaloids via Iminium Ion\u2013Vinylsilane Cyclizations\"\nTetrahedron Letters 1988, 29, 6541\u20136544\nR. M. Lett, L. E. Overman and J. Zablocki\n\n112.\t\u201cComplementary Use of Iminium Ion and Acyl Iminium Ion Cyclization Initiators for Asymmetric Synthesis of Both Enantiomers of Hydroxylated Indolizidines\u201d\nJournal of Organic Chemistry 1989, 54, 2591\u20132596\nM.-P. Heitz and L. E. Overman\n\n111.\t\u201cTotal Syntheses of (+)-Geissoschizine, (\u00b1)-Geissoschizine, and (\u00b1)-(Z)-Isositsirikine. Stereocontrolled Synthesis of Exocyclic Double Bonds by Stereospecific Iminium Ion\u2013Vinylsilane Cyclizations\u201d\nJournal of the American Chemical Society 1989, 111, 300\u2013308\nL. E. Overman and A. J. Robichaud\n\n110.\t\u201cSynthesis Studies Directed Towards Gelsemine. Preparation of an Advanced Pentacyclic Intermediate\u201d\nTetrahedron Letters 1988, 29, 3785\u20133788\nW. G. Earley, T. Oh and L. E. Overman\n\n109.\t\u201cSynthesis Studies Directed Towards Gelsemine. A New Synthesis of Highly Functionalized cis-Hydroisoquinolines\u201d\nTetrahedron Letters 1988, 29, 3781\u20133784\nW. G. Earley, E. J. Jacobsen, G. P. Meier, T. Oh and L. E. Overman\n\n108.\t\u201cStudies on the Total Synthesis of Gelsemine\u201d\nProceedings of the First Princess Chulabhorn Science Congress 1987. International Congress on Natural Products 1990, 3, 381\u2013390\nW. G. Earley, E. J. Jacobsen, T. Oh and L. E. Overman\n\n107.\t\u201cSynthesis of Substituted Tetrahydropyridines by Cyclizations of Silicon-Containing Iminium Ions\u201d\nTetrahedron (Symposium in Print) 1988, 44, 3919\u20133930\nG. W. Daub, D. A. Heerding and L. E. Overman\n\n106.\t\u201cPalladium-Catalyzed Polyene Cyclizations of Dienyl Aryl Iodides\u201d\nJournal of the American Chemical Society 1988, 110, 2328\u20132329\nM. M. Abelman and L. E. Overman\n\n105.\t\u201cEnantioselective Total Synthesis of the Pumiliotoxin A Alkaloids via Reductive Iminium Ion\u2013Alkyne Cyclizations. Total Synthesis of (+)-Pumiliotoxin A\u201d\nTetrahedron Letters 1988, 29, 901\u2013904\nL. E. Overman and M. J. Sharp\n\n104.\t\u201cSynthesis and Diels-Alder Reactions of 5-Alkenyl-1,3-Oxathiole-3-Oxides. A New Class of Diheterosubstituted 1,3-Dienes\u201d\nJournal of Organic Chemistry 1988, 53, 2630\u20132634\nM. J. Fisher and L. E. Overman\n\n103.\t\u201cNucleophile-Promoted Electrophilic Cyclization Reactions of Alkynes\u201d\nJournal of the American Chemical Society 1988, 110, 612\u2013614, 5934\nL. E. Overman and M. J. Sharp\n\n102.\t\u201cTotal Synthesis of (\u2013)-Laurenyne. The Use of Acetal-Initiated Cyclizations to Prepare Functionalized Eight-Membered Cyclic Ethers\u201d\nJournal of the American Chemical Society 1988, 110, 2248\u20132256\nL. E. Overman and A. S. Thompson\n\n101.\t\u201cFace Selectivity in Diels\u2013Alder Reactions of Chiral Dienes Containing Allylic Substituents\u201d\nJournal of the American Chemical Society 1988, 110, 4625\u20134633\nM. J. Fisher, W. J. Hehre, S. D. Kahn and L. E. Overman\n\n100.\t\u201cScope and Mechanism of Tandem Cationic Aza-Cope Rearrangement\u2013Mannich Cyclization Reactions\u201d\nJournal of the American Chemical Society 1988, 110, 4329\u20134336\nE. J. Jacobsen, J. Levin and L. E. Overman\n\n99.\t\u201cEnantioselective Total Synthesis of Streptazolin. The Tandem Use Iminium Ion\u2013Vinylsilane Cyclizations and Intramolecular Acylations\u201d\nJournal of the American Chemical Society 1987, 109, 6115\u20136119\nC. J. Flann and L. E. Overman\n\n98.\t\u201cMedium Effects and the Nature of the Rate-Determining Step in Mannich-Type Cyclizations\u201d\nJournal of the American Chemical Society 1987, 109, 6107\u20136114\nS. J. McCann and L. E. Overman\n\n97.\t\u201cIntramolecular Alkene Arylations for Rapid Assembly of Polycyclic Systems Containing Quaternary Centers. A New Synthesis of Spirooxindoles and Other Fused and Bridged Ring Systems\u201d\nJournal of Organic Chemistry 1987, 52, 4130\u20134133\nM. M. Abelman, T. Oh and L. E. Overman\n\n96.\t\u201cRing-Enlarging Furan Annulations\u201d\nJournal of Organic Chemistry 1987, 52, 3711\u20133712\nP. M. Herrinton, M. H. Hopkins, P. Mishra, M. J. Brown and L. E. Overman\n\n95.\t\u201cA Naturally Occurring Erythro Diastereomer of Pumiliotoxin B\u201d\nTetrahedron 1988, 44, 6795\u20136800\nH. M. Garraffo, M. W. Edwards, T. F. Spande, J. W. Daly, L. E. Overman, C. Severini and V. Erspamer\n\n94.\t\u201cStereocontrolled Preparation of Tetrahydrofurans by Acid-Catalyzed Rearrangement of Allylic Acetals\u201d\nJournal of the American Chemical Society 1987, 109, 4748\u20134749\nM. H. Hopkins and L. E. Overman\n\n93.\t\u201cPumiliotoxin Alkaloids: Relationship of Cardiotonic Activity to Sodium Channel Activity and Phosphatidylinositol Turnover\u201d\nJournal of Medicinal Chemistry 1988, 31, 477\u2013480\nJ. W. Daly, E. McNeal, F. Gusovsky, F. Ito and L. E. Overman\n\n92.\t\u201cTransition State Geometry of [3,3]-Sigmatropic Rearrangements of Iminium Ions\u201d\nJournal of Organic Chemistry 1988, 53, 685\u2013690\nR. J. Doedens, G. P. Meier and L. E. Overman\n\n91.\t\u201cCationic Cyclization Reactions of Vinylsilanes in Heterocyclic Synthesis\u201d\nChemica Scripta 1987, 27, 543\u2013544\nL. E. Overman\n\n90.\t\u201cIminium Ion and Acyliminium Ion Initiated Cyclization Reactions of Vinylsilanes. Regiocontrolled Synthesis of Tetrahydropyridines and Related Heterocycles\u201d\nJournal of the American Chemical Society 1987, 109, 6097\u20136107\nC. Flann, T. C. Malone and L. E. Overman\n\n89.\t\u201ctert-Butyldiphenylsilylamines: Useful Protecting Groups for Primary Amines\u201d\nTetrahedron Letters 1986, 27, 4301\u20134304\nL. E. Overman, M. E. Okazaki and P. Mishra\n\n88.\t\u201cEfficient Preparations of 8- and 9-Membered Cyclic Ethers\u201d\nJournal of the American Chemical Society 1986, 108, 3516\u20133517\nL. E. Overman, T. A. Blumenkopf, A. Casta\u00f1eda and A. S. Thompson\n\n87.\t\u201cRegioselective Synthesis of Tetrahydropyridines. Synthesis of 1-(4-Methoxyphenyl)-1,2,5,6-tetrahydropyridine\u201d\nOrganic Syntheses 1989, 68, 188\u2013197; Collective Volume VIII, pp 358\u2013362\nL. E. Overman, C. J. Flann and T. C. Malone\n\n86.\t\u201cVinylsilane- and Alkynylsilane-Terminated Cyclization Reactions\u201d\nChemical Reviews 1986, 86, 857\u2013873\nT. A. Blumenkopf and L. E. Overman\n\n85.\t\u201cHeterocyclization Reactions Employing Vinylsilane Terminators\u201d\nLectures in Heterocyclic Chemistry 1985, 8, 59\u201367\nL. E. Overman\n\n84.\t\u201cAcetal-Initiated Cyclizations of Vinylsilanes. A General Synthesis of Allylically Unsaturated Oxacyclics\u201d\nJournal of the American Chemical Society 1986, 108, 1303\u20131304\nL. E. Overman, A. Casta\u00f1eda and T. A. Blumenkopf\n\n83.\t\u201cModeling Chemical Reactivity 1. Regioselectivity of Diels\u2013Alder Cycloadditions of Electron-Rich Dienes with Electron-Deficient Dienophiles\u201d\nJournal of the American Chemical Society 1986, 108, 7381\u20137396\nS. D. Kahn, C. F. Pau, L. E. Overman and W. J. Hehre\n\n82.\t\u201cEnantioselective Total Synthesis of (+)-Pumiliotoxin A\u201d\nJournal of Organic Chemistry 1985, 50, 3669\u20133670\nL. E. Overman and N.-H. Lin\n\n81.\t\u201cThe Synthesis of Indolizidines by Intramolecular Ene Cyclizations. Preparation of (E)-Alkylidene Analogs of Pumiliotoxin A\u201d\nTetrahedron Letters 1985, 26, 4167\u20134170\nL. E. Overman and D. Lesuisse\n\n80.\t\u201c(Z)-4-(Trimethylsilyl)-3-buten-1-ol\u201d\nOrganic Syntheses 1989, 68, 182\u2013187; Collective Volume VIII, pp 609\u2013612\nL. E. Overman, M. J. Brown and S. F. McCann\n\n79.\t\u201cStereocontrolled Synthesis of Substituted cis-Cyclopenta[b]pyrrolidines\u201d\nJournal of Organic Chemistry 1985, 50, 2403\u20132405\nL. E. Overman, M. Okazaki and E. J. Jacobsen\n\n78.\t\u201cSynthesis Applications of Cationic Aza-Cope Rearrangements. Stereocontrolled Synthesis of Hexahydro-1H-pyrrolo[2,3-d]carbazoles\u201d\nJournal of Organic Chemistry 1985, 50, 4021\u20134028\nL. E. Overman and S. R. Angle\n\n77.\t\u201cA Convenient Synthesis of \uf0441-Pyrrolines and \uf0441-Piperideines\u201d\nTetrahedron Letters 1984, 25, 5737\u20135738\nL. E. Overman and R. M. Burk\n\n76.\t\u201cThe Importance of Vinylsilane Stereochemistry and \uf073-\uf070 Stabilization in Iminium Ion\u2013Vinylsilane Cyclizations. A Short Total Synthesis of the Amaryllidaceae Alkaloid (\u00b1)-Epielwesine\u201d\nTetrahedron Letters 1984, 25, 5739\u20135742\nL. E. Overman and R. M. Burk\n\n75.\t\u201cA Convenient Method for Obtaining trans-2-Aminocyclohexanol and trans-2-Aminocyclopentanol in Enantiomerically Pure Form\u201d\nJournal of Organic Chemistry 1985, 50, 4154\u20134155\nL. E. Overman and S. Sugai\n\n74.\t\u201cTotal Synthesis of (\u2013)-Crinine. Use of Tandem Cationic Aza-Cope Rearrangement\/ Mannich Cyclizations for the Synthesis of Enantiomerically Pure Amaryllidaceae Alkaloid\u201d\nHelvetica Chimica Acta 1985, 68, 745\u2013749\nL. E. Overman and S. Sugai\n\n73.\t\u201cA Convenient Synthesis of 4-Unsubstituted \uf062-Lactams\u201d\nJournal of the American Chemical Society 1985, 107, 1698\u20131701\nL. E. Overman and T. Osawa\n\n72.\t\u201cEnantioselective Total Synthesis of Allopumiliotoxin A Alkaloids 267A and 339B\u201d\nJournal of the American Chemical Society 1984, 106, 5360\u20135361\nL. E. Overman and S. W. Goldstein\n\n71.\t\u201cA Convenient Synthesis of Unsymmetrical Secondary Amines. In Situ Formation of Unstable Formaldehyde Imines\u201d\nTetrahedron Letters 1984, 25, 1635\u20131638\nL. E. Overman and R. M. Burk\n\n70.\t\u201cA New Class of Cardiotonic Agents: Structure-Activity Correlations for Natural and Synthetic Analogs of the Alkaloid Pumiliotoxin B\u201d\nJournal of Medicinal Chemistry 1985, 28, 482\u2013486\nJ. W. Daly, E. T. McNeal, L. E. Overman and D. H. Ellison \n\n69.\t\u201cMercury(II) and Palladium(II)-Catalyzed [3,3]-Sigmatropic Rearrangements\u201d\nAngewandte Chemie, International Edition in English 1984, 23, 579\u2013586\nL. E. Overman\n\n68.\t\u201cNew Synthetic Route to Perhydrohistrionicotoxin Using (3Z)-4-Butyl-3-Trichloroacetamido-1,3-Butadiene\u201d\nHeterocycles 1984, 22, 485\u2013488\nT. Ibuka, H. Minakata, M. Hashimoto, L. E. Overman and R. L. Freerks\n\n67.\t\u201cRecent Advances in the Total Synthesis of Pentacyclic Aspidosperma Alkaloids\u201d\nAlkaloids: Chemical and Biological Perspectives\u201d S. W. Pelletier, Ed., Volume 3, 1985, pp 275\u2013307\nL. E. Overman and M. Sworin\n\n66.\t\u201cIminium Ion and Acyliminium Ion Initiated Cyclizations of Vinylsilanes. Regiocontrolled Construction of Unsaturated Azacyclics\u201d\nJournal of the American Chemical Society 1983, 105, 6993\u20136994\nL. E. Overman, T. C. Malone and G. P. Meier\n\n65.\t\u201cEnantioselective Total Syntheses of Pumiliotoxin B and Pumiliotoxin 251D. A General Entry to the Pumiliotoxin A Alkaloids via Stereospecific Iminium Ion-Vinylsilane Cyclizations\u201d\nJournal of the American Chemical Society 1984, 106, 4192\u20134201\nL. E. Overman, K. L. Bell and F. Ito\n\n64.\t\u201cPalladium Dichloride Catalyzed Cope Rearrangements of Functionalized Acyclic 1,5-Dienes\u201d\nTetrahedron Letters 1983, 24, 3757\u20133760\nL. E. Overman and A. F. Renaldo\n\n63.\t\u201cSynthesis Applications of Cationic Aza-Cope Rearrangements. Stereoselective Synthesis of cis- and trans-3a-Aryl-4-oxodecahydrocyclohepta[b]pyrroles\u201d\nJournal of Organic Chemistry 1983, 48, 3393\u20133400\nL. E. Overman, E. J. Jacobsen and R. J. Doedens\n\n62.\t\u201cApplications of Cationic Aza-Cope Rearrangements for Alkaloid Synthesis. Stereoselective Preparation of cis-3a-Arylhydroindoles and a New Short Route to Amaryllidaceae Alkaloids\u201d\nJournal of the American Chemical Society 1983, 105, 6629\u20136637\nL. E. Overman, L. T. Mendelson and E. J. Jacobsen\n\n61.\t\u201cCarbon\u2013Carbon Bond Formation Under Mild Conditions via Tandem Cationic Aza-Cope\u2013Mannich Reactions. A Convenient Synthesis of Polysubstituted Pyrrolidines\u201d\nJournal of the American Chemical Society 1983, 105, 6622\u20136629\nL. E. Overman, M. Kakimoto, M. Okazaki and G. P. Meier\n\n60.\t\u201cPalladium Dichloride Promoted Cyclizations of 1,5-Dienes. A New Method for Forming Cyclohexenes\u201d\nTetrahedron Letters 1983, 24, 2235\u20132238\nL. E. Overman and A. F. Renaldo\n\n59.\t\u201cImportance of Allylic Interactions and Stereoelectronic Effects in Dictating the Steric Course of the Reaction of Iminium Ions with Nucleophiles. An Efficient Total Synthesis of (+)-Gephyrotoxin\u201d\nJournal of the American Chemical Society 1983, 105, 5373\u20135379\nL. E. Overman, D. Lesuisse and M. Hashimoto\n\n58.\t\u201cPreparation and Diels-Alder Reactions of 1,3-Dienes Containing Both Sulfur and Nitrogen Substituents. Complete Orientational Control by the Acylamino Group\u201d\nJournal of the American Chemical Society 1983, 105, 6335\u20136337\nL. E. Overman, C. B. Petty, T. Ban and G. T. Huang\n\n57.\t\u201cCarbonyl Participation in the Reaction of N-Acyl-2-isopropenylpyrrolidines with Halogen Electrophiles. Stereocontrolled Preparation of Enantiomerically Pure Synthons for the Synthesis of Pumiliotoxin A Alkaloids\u201d\nTetrahedron Letters 1982, 23, 4887\u20134890\nL. E. Overman and R. J. McCready\n\n56.\t\u201cA New Approach for the Total Synthesis of Pentacyclic Aspidosperma Alkaloids. Total Synthesis of dl-16-Methoxytabersonine\u201d\nJournal of Organic Chemistry 1983, 48, 2685\u20132690\nL. E. Overman, M. Sworin and R. M. Burk \n\n55.\t\u201cHighly Stereocontrolled Reduction of \uf061'-Alkoxyenones to Give Either the Threo or Erythro Allylic 1,2-Diol. Assignment of the Threo Configuration to the C-15, C-16 Diol of Pumiliotoxin B\u201d\nTetrahedron Letters 1982, 23, 2355\u20132358\nL. E. Overman and R. J. McCready\n\n54.\t\u201cThe Cyanomethyl Group for Nitrogen Protection and Iminium Ion Generation in Ring-Enlarging Pyrrolidine Annulations. A Short Synthesis of the Amaryllidaceae Alkaloid \n            dl-Crinine\u201d\nTetrahedron Letters 1982, 23, 2741\u20132744\nL. E. Overman and E. J. Jacobsen\n\n53.\t\u201cSynthesis Applications of Aza-Cope Rearrangements. Stereocontrolled Synthesis of Cyclohepta[b]pyrroldines\u201d\nTetrahedron Letters 1982, 23, 2737\u20132740\nL. E. Overman and E. J. Jacobsen\n\n52.\t\u201cSynthesis Applications of Aza-Cope Rearrangements. Stereoselective Synthesis of trans-2-Alkyl-cis-3a-aryloctahydroindolones\u201d\nTetrahedron Letters 1982, 23, 2733\u20132736\nL. E. Overman, L. T. Mendelson and L. A. Flippin\n\n51.\t\u201cStereocontrolled Synthesis of Exocyclic Trisubstituted Double Bonds by Stereospecific Iminium Ion\u2013Vinylsilane Cyclizations. A Short Synthetic Route to Indoloquinolizidine Alkaloids\u201d\nJournal of Organic Chemistry 1982, 47, 5297\u20135300\nL. E. Overman and T. C. Malone\n\n50.\t\u201cChair Topology of the Palladium Dichloride-Catalyzed Cope Rearrangement of Acyclic 1,5-Dienes\u201d\nJournal of the American Chemical Society 1982, 104, 7225\u20137231\nL. E. Overman and E. J. Jacobsen\n\n49.\t\u201cSynthesis Applications of Aza-Cope Rearrangements. A Stereoselective Synthesis of cis-3a-Aryloctahydroindolones and a New Short Entry to Amaryllidaceae Alkaloids\u201d\nJournal of the American Chemical Society 1981, 103, 5579\u20135581\nL. E. Overman and L. T. Mendelson\n\n48.\t\u201cSynthesis Applications of Aza-Cope Rearrangements. A Stereoselective Synthesis of 9a-Arylhydrolilolidines and a New Approach to the Synthesis of Aspidosperma Alkaloids\u201d\nTetrahedron (Symposium in Print) 1981, 37, 4041\u20134045\nL. E. Overman and M. Sworin\n\n47.\t\u201cA Short Total Synthesis of (+)-Perhydrogephyrotoxin\u201d\nJournal of Organic Chemistry 1981, 46, 2833\u20132835\nL. E. Overman and R. L. Freerks\n\n46.\t\u201cEnantiospecific Total Synthesis of Dendrobatid Toxin 251D. A Short Chiral Entry to the Cardiac-Active Pumiliotoxin A Alkaloids via Stereospecific Iminium Ion\u2013Vinylsilane Cyclizations\u201d\nJournal of the American Chemical Society 1981, 103, 1851\u20131853\nL. E. Overman and K. L. Bell\n\n45.\t\u201cFacile Aminolysis of Epoxides with Diethylaluminum Amides\u201d\nTetrahedron Letters 1981, 22, 195\u2013199\nL. E. Overman and L. A. Flippin\n\n44.\t\u201cPreparation of Substituted 2-Pyridones by Thermal Rearrangement of Propargylic Pseudoureas. Improvements in the 2-Pyridone Yields by Variations of the Pseudourea NR2 Substituent\u201d\nJournal of Organic Chemistry 1981, 46, 811\u2013813\nL. E. Overman and J. P. Roos\n\n43.\t\u201cA New Method for Stereoselective Piperidine Annulation. Directing the 2-Azonia-[3,3]-Sigmatropic Rearrangement by Irreversible Hydrolysis\u201d\nJournal of Organic Chemistry 1980, 45, 5229\u20135230\nL. E. Overman and T. Yokomatsu\n\n42.\t\u201cDiels\u2013Alder Reactions of 1-N-Acylamino-1,3-dienes\u201d\nJournal of the American Chemical Society 1981, 103, 2816\u20132822\nL. E. Overman, R. L. Freerks, C. B. Petty, L. A. Clizbe, R. K. Ono, G. F. Taylor and P. J . Jessup\n\n41.\t\u201cThermal Rearrangements of Propargylic Trichloroacetimidates. Synthesis of Trichloroacetamido-1,3-and 1,2-dienes\u201d\nJournal of the American Chemical Society 1981, 103, 2807\u20132816\nL. E. Overman, L. A. Clizbe, R. L. Freerks and C. K. Marlowe\n\n40.\t\u201cPumiliotoxin-C and Synthetic Analogs: A New Class of Nicotinic Antagonists\u201d\nMolecular Pharmacology 1982, 22, 565\u2013573\nY. Nimitkitpaisan, J. W. Daly, P. J. Jessup, L. E. Overman, J. E. Warnick and E. X. Albuquerque\n\n39.\t\u201cAllylic and Propargylic Imidic Esters in Organic Synthesis\u201d\nAccounts of Chemical Research 1980, 13, 218\u2013224\nL. E. Overman\n\n38.\t\u201cStereoselective Total Synthesis of (+)-Perhydrogephyrotoxin. Synthetic Applications of Directed 2-Azonia-[3,3]-Sigmatropic Rearrangements\u201d\nJournal of the American Chemical Society 1980, 102, 1454\u20131456\nL. E. Overman and C. Fukaya\n\n37.\t\u201cPalladium(II)Chloride-Catalyzed Cope Rearrangements of Acyclic 1,5-Dienes\u201d\nJournal of the American Chemical Society 1980, 102, 865\u2013867\nL. E. Overman and F. M. Knoll\n\n36.\t\u201cDirected 2-Azonia-[3,3]-Sigmatropic Rearrangements. A Convenient Preparation of Substituted 1-Azaspiro[4,5]decanes\u201d\nTetrahedron Letters 1979, 42, 4041\u20134044\nL. E. Overman, M. Kakimoto and M. Okawara\n\n35.\t\u201cSynthetic Applications of N-Acylamino-1,3-dienes. Control of Endo Stereoselectivity by the Acyl Substituent. A Stereospecific Synthesis of the Analgesic Tilidine\u201d\nJournal of Organic Chemistry 1979, 44, 4183\u20134185\nL. E. Overman, C. B. Petty and R. J. Doedens\n\n34.\t\u201cPreparation of Substituted 2-Pyridones by Thermal Rearrangement of Propargylic Pyrrolidine Pseudoureas\u201d\nJournal of the American Chemical Society 1980, 102, 747\u2013754\nL. E. Overman, S. Tsuboi, J. P. Roos and G. F. Taylor\n\n33.\t\u201c4-Methylene-1,5-Dihydrooxazoles: Isolation, Properties and Use for the Preparation of Substituted Oxazoles\u201d\nJournal of Organic Chemistry 1979, 44, 2323\u20132325\nL. E. Overman, S. Tsuboi and S. Angle\n\n32.\t\u201cThe Preparation of Trichloroacetamido-1,2-dienes\u201d\nTetrahedron Letters 1979, 20, 599\u2013603\nL. E. Overman, C. M. Marlowe and L. A. Clizbe\n\n31.\t\u201cPalladium(II)-Catalyzed Rearrangement of Allylic Acetates\u201d\nTetrahedron Letters 1979, 20, 321\u2013324\nL. E. Overman and F. M. Knoll\n\n30.\t\u201cCarbon\u2013Carbon Bond Formation via Directed 2-Azonia-[3,3]-Sigmatropic Rearrangements. A New Pyrrolidine Synthesis\u201d\nJournal of the American Chemical Society 1979, 101, 1310\u20131313\nL. E. Overman and M. Kakimoto\n\n29.\t\u201cPreparation of Rearranged Allylic Isocyanates from the Reaction of Allylic Alkoxides with Cyanogen Chloride\u201d\nJournal of Organic Chemistry 1978, 43, 4564\u20134567\nL. E. Overman and M. Kakimoto\n\n28.\t\u201cSynthetic Applications of N-Acylamino-1,3-dienes. An Efficient Stereospecific Total Synthesis of dl-Pumiliotoxin C and a General Entry to cis-Decahydroquinoline Alkaloids\u201d\nJournal of the American Chemical Society 1978, 100, 5179\u20135185\nL. E. Overman and P. J. Jessup\n\n27.\t\u201cHow Important is Secondary Orbital Overlap in Determining the Regioselectivity of Diels\u2013Alder Reactions?\u201d\nTetrahedron Letters 1978, 19, 1313\u20131316\nI. Fleming, J. P. Michael, L. E. Overman and G. F. Taylor\n\n26.\t\u201ctrans-1-N-Acylamino-1,3-dienes: Preparation from Dienoic Acids\u201d\nJournal of Organic Chemistry 1978, 43, 2164\u20132167\nL. E. Overman, G. F. Taylor, C. B. Petty and P. J. Jessup\n\n25.\t\u201cMild Procedures for Interconverting Allylic Oxygen Functionality. Cyclization-Induced [3,3]-Sigmatropic Rearrangement of Allylic Carbamates\u201d\nJournal of the American Chemical Society 1978, 100, 4822\u20134834\nL. E. Overman, C. B. Campbell and F. M. Knoll\n\n24.\t\u201c1-N-Acylamino-1,3-dienes from 2,4-Pentadienoic Acids by the Curtius Rearrangement: Benzyl trans-1,3-Butadiene-1-carbamate\u201d\nOrganic Syntheses 1979, 59, 1\u20139; Collective Volume VI, pp 95\u2013101\nP. J. Jessup, C. B. Petty, J. Roos and L. E. Overman\n\n23.\t\u201cThe Diels\u2013Alder Reaction Between trans-1-N-Acylamino-1,3-dienes and Methyl Acrylate. A Correlation Between Diene Photoelectron Ionization Potentials and Reactivity, Stereoselectivity and Regioselectivity\u201d\nJournal of the American Chemical Society 1978, 100, 3182\u20133189\nL. E. Overman, G. F. Taylor, K. N. Houk and L. S. Domelsmith\n\n22.\t\u201cA Short Stereospecific Total Synthesis of dl-Pumiliotoxin C\u201d\nTetrahedron Letters 1977, 18, 1253\u20131256\nL. E. Overman and P. J. Jessup\n\n21.\t\u201cA New Synthesis of 2-Pyridones. Solution Thermolysis of Propargylic Pseudoureas\u201d\nJournal of the American Chemical Society 1977, 99, 2813\u20132815\nL. E. Overman and S. Tsuboi\n\n20.\t\u201cGas Phase Acidities of the 2-Butenes. Regarding the Use of Organometallics as Models for Free Carbanions\u201d\nJournal of the American Chemical Society 1977, 99, 1976\u20131977\nJ. E. Bartmess, W. J. Hehre, R. T. McIver, Jr. and L. E. Overman\n\n19.\t\u201cMercury(II)-Catalyzed 3,3-Sigmatropic Rearrangements of Allylic N,N-Dimethylcarbamates: A Mild Method for Allylic Equilibrations and Contrathermodynamic Allylic Isomer Enrichments\u201d\nJournal of Organic Chemistry 1976, 41, 3338\u20133340\nL. E. Overman and C. B. Campbell\n\n18.\t\u201cN-Acyl-1-amino-1,3-dienes: 1-Amino-1,3-diene Synthetic Equivalents for the Diels-Alder Reaction\u201d\nTetrahedron Letters 1976, 17, 3089\u20133092\nL. E. Overman, G. F. Taylor and P. J. Jessup\n\n17.\t\u201cThe Preparation of Ureas by the Thermolysis of Allylic Pseudoureas\u201d\nTetrahedron Letters 1976, 17, 1145\u20131148\nS. Tsuboi, P. Stromquist and L. E. Overman\n\n16.\t\u201cSynthesis of Trichloroacetamido-1,3-dienes. Useful Aminobutadiene Equivalents for the Diels\u2013Alder Reaction\u201d\nJournal of the American Chemical Society 1976, 98, 2352\u20132355\nL. E. Overman and L. A. Clizbe\n\n15.\t\u201cA General Method for the Synthesis of Amines by the Rearrangement of Allylic Trichloroacetimidates. 1,3-Transposition of Alcohol and Amine Functions\u201d\nJournal of the American Chemical Society 1976, 98, 2901\u20132910\nL. E. Overman\n\n14.\t\u201cNucleophilic Cleavage of the Sulfur\u2013Sulfur Bond by Phosphorus Nucleophiles. IV. Kinetic Study of the Reduction of Alkyl Disulfides with Triphenylphosphine and Water\u201d\nJournal of the American Chemical Society 1976, 98, 771\u2013775\nL. E. Overman and E. M. O\u2019Connor\n\n13.\t\u201cAllylically Transposed Amines from Allylic Alcohols: 3,7-Dimethyl-1,6-Octadien-3-Amine\u201d\nOrganic Syntheses 1978, 58, 4\u201311: Collective Volume VI, pp 507\u2013511\nL. A. Clizbe and L. E. Overman\n\n12.\t\u201cNucleophilic Cleavage of the Sulfur\u2013Sulfur Bond by Phosphorus Nucleophiles III. Kinetic Study of the Reduction of a Series of Ethyl Aryl Disulfides with Triphenylphosphine and Water\u201d\nJournal of Organic Chemistry 1975, 40, 2779\u20132781\nL. E. Overman and S. T. Petty\n\n11.\t\u201cSynthesis of 1-Azaspiro[5.5]undec-7-en-2-one\u201d\nTetrahedron Letters 1975, 16, 1149\u20131152\nL. E. Overman\n\n10.\t\u201cNucleophilic Cleavage of the Sulfur-Sulfur Bond by Phosphorous Nucleophiles. Kinetic Study of the Reduction of Aryl Disulfides with Triphenylphosphine and Water\u201d\nJournal of the American Chemical Society 1974, 96, 6081\u20136089\nL. E. Overman, D. Matzinger, E. M. O\u2019Connor and J. D. Overman\n\n9.\t\u201cHemiacetal-Mediated Reactions. Directed Synthesis of Diols and Acetals\u201d\nJournal of Organic Chemistry 1974, 39, 1474\u20131481\nL. E. Overman and C. B. Campbell\n\n8.\t\u201cThermal- and Mercuric Ion-Catalyzed [3,3]-Sigmatropic Rearrangements of Allylic Trichloroacetimidates. The 1,3-Transposition of Alcohol and Amine Functions\u201d\nJournal of the American Chemical Society 1974, 96, 597\u2013599\nL. E. Overman\n\n7.\t\u201cThe Reduction of Aryl Disulfides with Triphenylphosphine and Water\u201d\nSynthesis 1974, 59\u201360\nL. E. Overman, J. Smoot and J. D. Overman\n\n6.\t\u201cIntramolecular Delivery of a Water Equivalent in the Oxymercuration Reaction. Conversion of an Allylic Alcohol Into a cis-Vicinal Diol\u201d\nJournal of the Chemical Society, Chemical Communications 1972, 1196\u20131198\nL. E. Overman\n\n5.\t\u201cDehydrogenase Enzyme Models. Approximation of an Alcohol and a Pyridinium Ring\u201d\nJournal of Organic Chemistry 1972, 37, 4214\u20134218\nL. E. Overman\n\n4.\t\u201cSolvolytic Rearrangements Accompanied by Multiple Alkyl Shifts\u201d\nJournal of the American Chemical Society 1971, 93, 2247\u20132253\nH. W. Whitlock, Jr. and L. E. Overman\n\n3.\t\u201cAn \u2018Artificial Enzyme\u2019 Combining a Metal Catalytic Group and Hydrophobic Binding Cavity\u201d\nJournal of the American Chemical Society 1970, 91, 1075\u20131077\nR. Breslow and L. E. Overman\n\n2.\t\u201cThe Chemical Behavior of o-Bis(phenylethynyl)benzene Toward Some Electrophilic and Nucleophilic Reagents\u201d\nJournal of Organic Chemistry 1969, 34, 879\u2013886\nH. W. Whitlock, Jr., P. V. Sandvick, L. E. Overman and P. B. Reichardt\n\n1.\t\u201cAngular Methylation\u201d\nJournal of Organic Chemistry 1969, 34, 1962\u20131963\nH. W. Whitlock, Jr. and L. E. Overman\n\nPatents\n\n1.\t\u201cSynthesis of Indolizidines Related to the Cardiotonic Pumiliotoxin A Alkaloids\u201d\nU.S. Patent 4,675,325 (issued June 23, 1987) \nL. E. Overman and F. Ito\n\n2.\t\u201cGABA Receptor Antagonists Selective for GABArho Receptors\u201d\nU. S. Patent 5627169 (issued May 6, 1997)\nR. Miledi, L. E. Overman, Y. Murata and R. Woodward\n\n3.\t\"ETP Derivatives\u201d \t\t \n\tU.S. Patent 9,527,868 (issued December 27, 2016)\n\tL. Overman, M. Baumann, S. Nam, D. Horne, R. Jove\n\n4.\t\u201cETP Derivatives\u201d\n\tUS Patent 9,856,273 (issued January 2, 2018)\n\tL. E. Overman, M. Baumann, S. Nam, D. Horne, R. Jove, J. Xie, C. Kowolik \n\n\n<\/pre>\n","protected":false},"excerpt":{"rendered":"<p>402. &#8220;Constructing Saturated Guanidinum Heterocycles by Cycloaddition of N-Amidinyliminium Ions with Indoles&#8221; T. K. Allred, M. B. Shaghafi, P.-P. Chen, Q. Tran, K. N. Houk, L. E. Overman Organic Letters 2021, 23, . https:\/\/doi.org\/10.1021\/acs.orglett.1c02832 401. &#8220;Potent Anticancer Effects of Epidithiodiketopiperazine NT1721 in Cutaneous T Cell Lymphoma&#8221; M. Lin, C. M. Kowolik, J. Xie, S. Yadav, [&hellip;]<\/p>\n","protected":false},"author":58,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-2034","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/pages\/2034","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/users\/58"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/comments?post=2034"}],"version-history":[{"count":4,"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/pages\/2034\/revisions"}],"predecessor-version":[{"id":2039,"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/pages\/2034\/revisions\/2039"}],"wp:attachment":[{"href":"https:\/\/sites.ps.uci.edu\/overman\/wp-json\/wp\/v2\/media?parent=2034"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}